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1.发明申请CATALYTIC HYDROGENATION USING COMPLEXES OF BASE METALS WITH TRIDENTATE LIGANDS 有权使用三元配体的碱金属复合物进行催化氢化公开(公告)号：US20150336862A1
公开(公告)日：2015-11-26
申请号：US13587717
申请日：2012-08-16
IPC分类号： C07C29/17 , C07F15/06 , C07F5/04 , C07C67/303 , C07C51/36 , C07D211/46 , C07C41/20 , C07C41/18 , C07C29/145 , C07C41/01 , C07C17/354 , C07C45/62 , C07C209/52 , C07C5/03 , C07C5/05 , B01J31/24 , C07F15/04
CPC分类号： B01J31/2295 , B01J31/189 , B01J31/2476 , B01J2231/643 , B01J2231/645 , B01J2231/646 , B01J2531/0244 , B01J2531/845 , B01J2531/847 , C07C5/03 , C07C5/05 , C07C17/354 , C07C29/141 , C07C29/145 , C07C29/172 , C07C29/175 , C07C41/01 , C07C41/18 , C07C41/20 , C07C41/26 , C07C45/62 , C07C51/36 , C07C67/303 , C07C209/52 , C07C209/70 , C07C2531/14 , C07C2531/22 , C07C2531/28 , C07C2601/14 , C07C2601/16 , C07C2601/18 , C07C2602/08 , C07C2602/42 , C07C2603/12 , C07C2603/18 , C07D211/02 , C07D211/46 , C07F5/04 , C07F15/04 , C07F15/045 , C07F15/06 , C07F15/065 , Y02P20/52 , C07C43/23 , C07C33/20 , C07C33/22 , C07C33/24 , C07C35/38 , C07C69/24 , C07C53/126 , C07C31/125 , C07C33/46 , C07C43/04 , C07C35/32 , C07C43/205 , C07C49/403 , C07C211/27 , C07C211/48 , C07C25/13 , C07C15/073 , C07C15/02 , C07C15/085 , C07C11/02 , C07C13/26 , C07C13/64 , C07C13/20
摘要： Complexes of cobalt and nickel with tridentate ligand PNHPR are effective for hydrogenation of unsaturated compounds. Cobalt complex [(PNHPCy)Co(CH2SiMe3)]BArF4 (PNHPCy=bis[2-(dicyclohexylphosphino)ethyl]amine, BArF4=B(3,5-(CF3)2C6H3)4)) was prepared and used with hydrogen for hydrogenation of alkenes, aldehydes, ketones, and imines under mild conditions (25-60° C., 1-4 atm H2). Nickel complex [(PNHPCy)Ni(H)]BPh4 was used for hydrogenation of styrene and 1-octene under mild conditions. (PNPCy)Ni(H) was used for hydrogenating alkenes.
摘要翻译： 钴和镍与三齿配体PNHPR的配合物对于不饱和化合物的氢化是有效的。 钴配合物[（PNHPCy）Co（CH2SiMe3）] BArF4（PNHPCy =双[2-（二环己基膦基）乙基]胺，BArF 4 = B（3,5-（CF 3）2 C 6 H 3）4） 的烯烃，醛，酮和亚胺在温和条件下（25-60℃，1-4atm H 2）。 镍络合物[（PNHPCy）Ni（H）] BPh4用于在温和条件下苯乙烯和1-辛烯的氢化。 （PNPCy）Ni（H）用于氢化烯烃。
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2.发明授权Catalytic hydrogenation using complexes of base metals with tridentate ligands 有权使用贱金属配合物与三齿配体的催化氢化公开(公告)号：US09434666B2
公开(公告)日：2016-09-06
申请号：US13587717
申请日：2012-08-16
IPC分类号： C07C29/145 , C07C67/303 , C07C51/36 , C07C41/18 , C07C41/01 , C07C41/20 , C07C45/62 , C07C209/52 , C07C5/03 , C07C5/05 , C07C231/24 , C07F15/04 , C07F15/06 , C07F5/04 , C07D211/46 , C07C29/17 , C07C17/354 , C07C29/141 , C07C41/26 , C07D211/02 , B01J31/18
CPC分类号： B01J31/2295 , B01J31/189 , B01J31/2476 , B01J2231/643 , B01J2231/645 , B01J2231/646 , B01J2531/0244 , B01J2531/845 , B01J2531/847 , C07C5/03 , C07C5/05 , C07C17/354 , C07C29/141 , C07C29/145 , C07C29/172 , C07C29/175 , C07C41/01 , C07C41/18 , C07C41/20 , C07C41/26 , C07C45/62 , C07C51/36 , C07C67/303 , C07C209/52 , C07C209/70 , C07C2531/14 , C07C2531/22 , C07C2531/28 , C07C2601/14 , C07C2601/16 , C07C2601/18 , C07C2602/08 , C07C2602/42 , C07C2603/12 , C07C2603/18 , C07D211/02 , C07D211/46 , C07F5/04 , C07F15/04 , C07F15/045 , C07F15/06 , C07F15/065 , Y02P20/52 , C07C43/23 , C07C33/20 , C07C33/22 , C07C33/24 , C07C35/38 , C07C69/24 , C07C53/126 , C07C31/125 , C07C33/46 , C07C43/04 , C07C35/32 , C07C43/205 , C07C49/403 , C07C211/27 , C07C211/48 , C07C25/13 , C07C15/073 , C07C15/02 , C07C15/085 , C07C11/02 , C07C13/26 , C07C13/64 , C07C13/20
摘要： Complexes of cobalt and nickel with tridentate ligand PNHPR are effective for hydrogenation of unsaturated compounds. Cobalt complex [(PNHPCy)Co(CH2SiMe3)]BArF4 (PNHPCy=bis[2-(dicyclohexylphosphino)ethyl]amine, BArF4=B(3,5-(CF3)2C6H3)4)) was prepared and used with hydrogen for hydrogenation of alkenes, aldehydes, ketones, and imines under mild conditions (25-60° C., 1-4 atm H2). Nickel complex [(PNHPCy)Ni(H)]BPh4 was used for hydrogenation of styrene and 1-octene under mild conditions. (PNPCy)Ni(H) was used for hydrogenating alkenes.
摘要翻译： 钴和镍与三齿配体PNHPR的配合物对于不饱和化合物的氢化是有效的。 钴配合物[（PNHPCy）Co（CH2SiMe3）] BArF4（PNHPCy =双[2-（二环己基膦基）乙基]胺，BArF 4 = B（3,5-（CF 3）2 C 6 H 3）4） 的烯烃，醛，酮和亚胺在温和条件下（25-60℃，1-4atm H 2）。 镍络合物[（PNHPCy）Ni（H）] BPh4用于在温和条件下苯乙烯和1-辛烯的氢化。 （PNPCy）Ni（H）用于氢化烯烃。
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公开(公告)号：US20120238733A1
公开(公告)日：2012-09-20
申请号：US13420159
申请日：2012-03-14
申请人： Kalyan V. Vasudevan , Nickolaus A. Smith , John C. Gordon , Edward A. McKigney , Ross E. Muenchausen
发明人： Kalyan V. Vasudevan , Nickolaus A. Smith , John C. Gordon , Edward A. McKigney , Ross E. Muenchausen
IPC分类号： C07F5/00
CPC分类号： C07F5/003 , Y02P20/542
摘要： Crystals of a solvated cerium(III) halide solvate complex resulted from a process of forming a paste of a cerium(III) halide in an ionic liquid, adding a solvent to the paste, removing any undissolved solid, and then cooling the liquid phase. Diffusing a solvent vapor into the liquid phase also resulted in crystals of a solvated cerium(III) halide complex.
摘要翻译： 溶剂化的卤化铈（III）溶剂化物络合物的结晶是由离子液体中形成卤化铈（III）的糊料的过程产生的，向浆料中加入溶剂，除去任何未溶解的固体，然后冷却液相。 将溶剂蒸气扩散到液相中也导致溶剂化的卤化铈（III）络合物的晶体。
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公开(公告)号：US08501484B2
公开(公告)日：2013-08-06
申请号：US13420159
申请日：2012-03-14
申请人： Kalyan V. Vasudevan , Nickolaus A. Smith , John C. Gordon , Edward A. McKigney , Ross E. Muenchausen
发明人： Kalyan V. Vasudevan , Nickolaus A. Smith , John C. Gordon , Edward A. McKigney , Ross E. Muenchausen
IPC分类号： G01N33/20
CPC分类号： C07F5/003 , Y02P20/542
摘要： Crystals of a solvated cerium(III) halide solvate complex resulted from a process of forming a paste of a cerium(III) halide in an ionic liquid, adding a solvent to the paste, removing any undissolved solid, and then cooling the liquid phase. Diffusing a solvent vapor into the liquid phase also resulted in crystals of a solvated cerium(III) halide complex.
摘要翻译： 溶剂化的卤化铈（III）溶剂化物络合物的结晶是由离子液体中形成卤化铈（III）的糊料的过程产生的，向浆料中加入溶剂，除去任何未溶解的固体，然后冷却液相。 将溶剂蒸气扩散到液相中也导致溶剂化的卤化铈（III）络合物的晶体。
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