摘要:
Provided is a polymer electrolyte containing a block copolymer comprising one or more blocks having sulfonic acid groups and one or more blocks having substantially no sulfonic acid group, and at least one block among all blocks is a block having aromatic rings in the main chain thereof, and a method for producing the same. The polymer electrolyte is suitable for a proton conductive film of a fuel cell due to excellent water resistance and heat resistance, and high proton conductivity.
摘要:
The present invention provide a copolymer which exhibit high electricity generation characteristics when being used as a polyelectrolyte for fuel cell, and also provide a copolymer comprising an aromatic unit substantially free from an ion-exchange group, and an aliphatic unit having an ion-exchange group and a main chain consisting of an aliphatic repeating unit.
摘要:
The present invention relates to a laminated membrane comprising a membrane (I) which comprises aromatic polymer electrolyte containing a super strong acid group and a membrane (II) which comprises one compound selected from the group consisting of electrolytes of perfluoroalkylsulfonic acid polymer and non-super strong acid polymer, and a laminated membrane comprising a membrane (III) which comprises a perfluoroalkylsulfonic acid polymer electrolyte and a membrane (IV) which comprises a non-super strong acid polymer electrolyte. The laminated membrane of the present invention is an electrolyte membrane excellent in generation performance and excellent also in the respect of mechanical strength.
摘要:
The present invention relates to a laminated membrane comprising a membrane (I) which comprises aromatic polymer electrolyte containing a super strong acid group and a membrane (II) which comprises one compound selected from the group consisting of electrolytes of perfluoroalkylsulfonic acid polymer and non-super strong acid polymer, and a laminated membrane comprising a membrane (III) which comprises a perfluoroalkylsulfonic acid polymer electrolyte and a membrane (IV) which comprises a non-super strong acid polymer electrolyte. The laminated membrane of the present invention is an electrolyte membrane excellent in generation performance and excellent also in the respect of mechanical strength.
摘要:
Provided is a polymer electrolyte containing a block copolymer comprising one or more blocks having sulfonic acid groups and one or more blocks having substantially no sulfonic acid group, and at least one block among all blocks is a block having aromatic rings in the main chain thereof, and a method for producing the same. The polymer electrolyte is suitable for a proton conductive film of a fuel cell due to excellent water resistance and heat resistance, and high proton conductivity.
摘要:
A polymer electrolyte comprising a sulfonated polyethersulfone having an ion-exchange group equivalent weight of 870 to 5000 g/mol, which is obtainable by sulfonating a polyethersulfone having the structural unit represented by the following structural formula, ##STR1## The polymer electrolyte is cheap, easily mold-processable by virtue of soluble property in organic solvent and thermoplastic property, easily film-processable, highly water-resistant, and suitable for a fuel cell.
摘要:
A process for producing an aromatic polyamide film comprising forming a thin layer of an optically isotropic dope in which an aromatic polyamide is dissolved in a polar amide, immersing the thin layer dope in a polar solvent kept at a temperature not higher than -20.degree. C. to coagulate the dope to form a film and drying the film in the presence of an isocyanate compound. Said process can produce directly a transparent film from an aromatic polyamide dope without requiring the step of dissolving the aromatic polyamide in conc. sulfuric acid, does not require any acid resistant equipment and is inexpensive.
摘要:
A polymer electrolyte membrane having outstanding water resistance and high thermal resistance, moreover having practical strength required for use as a polymer electrolyte membrane of a solid polymer electrolyte type fuel cell at low price, and a method for producing the polymer electrolyte membrane are provided. A polymer electrolyte comprising a block copolymer comprising one or more of blocks in which sulfonic acid groups are introduced and one or more blocks in which sulfonic acid groups are not substantially introduced wherein at least one block in the block copolymer is a block having aromatic rings in polymer chain, and a porous membrane, and a fuel cell using the membrane are provided.And moreover the present invention provides a method for producing a polymer electrolyte membrane comprising the steps of, (i) impregnating some of pores of a porous membrane with a solution (1) of a polymer electrolyte having a contact angle of less than 90° to said porous membrane, (ii) impregnating a remaining part in the pores of the porous membrane with a solution (2) of a polymer electrolyte having a larger contact angle than that of the solution (1) to said porous membrane, and (iii) removing a solvent.
摘要:
A fuel cell containing a polymer electrolyte membrane, wherein the polymer electrolyte membrane contains a polymer electrolyte composition that contains a polymer electrolyte and at least one antioxidant selected from the group consisting of an antioxidant containing tri-valent phosphorous and an antioxidant containing sulfur.
摘要:
The present invention relates to a laminated membrane comprising a membrane (I) which comprises aromatic polymer electrolyte containing a super strong acid group and a membrane (II) which comprises one compound selected from the group consisting of electrolytes of perfluoroalkylsulfonic acid polymer and non-super strong acid polymer, and a laminated membrane comprising a membrane (III) which comprises a perfluoroalkylsulfonic acid polymer electrolyte and a membrane (IV) which comprises a non-super strong acid polymer electrolyte. The laminated membrane of the present invention is an electrolyte membrane excellent in generation performance and excellent also in the respect of mechanical strength.