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公开(公告)号：US07396608B2
公开(公告)日：2008-07-08
申请号：US10853287
申请日：2004-05-26
CPC分类号： H01M8/1067 , C08F8/36 , C08G65/24 , C08G65/48 , C08G65/485 , C08J5/2256 , C08J2371/12 , H01B1/122 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1072 , H01M8/1088 , H01M2300/0082 , Y02P70/56
摘要： Provided is a polymer electrolyte containing a block copolymer comprising one or more blocks having sulfonic acid groups and one or more blocks having substantially no sulfonic acid group, and at least one block among all blocks is a block having aromatic rings in the main chain thereof, and a method for producing the same. The polymer electrolyte is suitable for a proton conductive film of a fuel cell due to excellent water resistance and heat resistance, and high proton conductivity.
摘要翻译： 本发明提供一种包含含有一个或多个具有磺酸基的嵌段和一个或多个基本上不含磺酸基的嵌段的嵌段共聚物的聚合物电解质，所有嵌段中的至少一个嵌段是其主链中具有芳环的嵌段， 及其制造方法。 由于优异的耐水性和耐热性以及高的质子传导性，聚合物电解质适用于燃料电池的质子传导膜。
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公开(公告)号：US06761989B2
公开(公告)日：2004-07-13
申请号：US09742115
申请日：2000-12-22
IPC分类号： H01M810
CPC分类号： H01M8/1067 , C08F8/36 , C08G65/24 , C08G65/48 , C08G65/485 , C08J5/2256 , C08J2371/12 , H01B1/122 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1072 , H01M8/1088 , H01M2300/0082 , Y02P70/56
摘要： Provided is a polymer electrolyte containing a block copolymer comprising one or more blocks having sulfonic acid groups and one or more blocks having substantially no sulfonic acid group, and at least one block among all blocks is a block having aromatic rings in the main chain thereof, and a method for producing the same. The polymer electrolyte is suitable for a proton conductive film of a fuel cell due to excellent water resistance and heat resistance, and high proton conductivity.
摘要翻译： 本发明提供一种包含含有一个或多个具有磺酸基的嵌段和一个或多个基本上不含磺酸基的嵌段的嵌段共聚物的聚合物电解质，所有嵌段中的至少一个嵌段是其主链中具有芳环的嵌段， 及其制造方法。 由于优异的耐水性和耐热性以及高的质子传导性，聚合物电解质适用于燃料电池的质子传导膜。
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公开(公告)号：US5849434A
公开(公告)日：1998-12-15
申请号：US685562
申请日：1996-07-24
摘要： A non-aqueous electrolyte lithium secondary battery, comprising a cathode containing, as active material, a material that can be doped/undoped with lithium ions, an anode containing, as active material, a carbonaceous material that can be doped/undoped with lithium ions, a separator interposed between the cathode and anode and an electrolyte prepared by dissolving lithium salt in an organic solvent, wherein the anode contains a polymer having carbonate groups represented by the structural formula �I!: ##STR1## said polymer having a number average molecular weight of not less than 300 and not more than 200,000. The lithium secondary battery has cycle life and high-rate capacity which are improved without reducing low-temperature capacity.
摘要翻译： 一种非水电解质锂二次电池，其包含含有作为活性材料的能够掺杂/未掺杂锂离子的材料的阴极，含有可掺杂/未掺杂锂离子的碳质材料作为活性材料的阳极 插入在阴极和阳极之间的隔膜和通过将锂盐溶解在有机溶剂中而制备的电解质，其中阳极含有具有由结构式[I]表示的碳酸酯基团的聚合物：所述聚合物具有 数均分子量不小于300，不大于20万。 锂二次电池具有循环寿命和高速率容量，在不降低低温容量的情况下得到改进。
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公开(公告)号：US6087031A
公开(公告)日：2000-07-11
申请号：US997547
申请日：1997-12-23
CPC分类号： H01M8/1072 , C08J5/20 , H01M8/1027 , H01M8/1032 , H01M8/1067 , Y02P70/56
摘要： A polymer electrolyte comprising a sulfonated polyethersulfone having an ion-exchange group equivalent weight of 870 to 5000 g/mol, which is obtainable by sulfonating a polyethersulfone having the structural unit represented by the following structural formula, ##STR1## The polymer electrolyte is cheap, easily mold-processable by virtue of soluble property in organic solvent and thermoplastic property, easily film-processable, highly water-resistant, and suitable for a fuel cell.
摘要翻译： 包含具有870〜5000g / mol的离子交换基当量的磺化聚醚砜的聚合物电解质，其可通过磺化具有由下列结构式表示的结构单元的聚醚砜获得。该聚合物电解质便宜， 由于在有机溶剂中的可溶性和热塑性能可加工，易于加工膜，高度防水，并且适用于燃料电池。
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公开(公告)号：US06939646B2
公开(公告)日：2005-09-06
申请号：US10108441
申请日：2002-03-29
IPC分类号： C08G75/20 , C07C311/48 , C08G65/40 , C08J5/20 , C08J5/22 , C08L71/00 , H01B1/06 , H01B1/12 , H01B13/00 , H01M6/18 , H01M8/02 , H01M8/10 , H01M10/05 , H01M10/0565
CPC分类号： H01M8/106 , C07C311/48 , C08J5/20 , C08J5/2275 , C08J2365/02 , H01B1/122 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M10/052 , H01M10/0565 , H01M2300/0082 , H01M2300/0088 , Y02P70/56
摘要： A polymer electrolyte having, in a main chain, a structural unit represented by the following formula (1): —[Ar1—(SO2—N−(X+)—SO2—Ar2)m—SO2—N−(X+)—SO2—Ar1—O]— (1) wherein Ar1 and Ar2 independently represent a divalent aromatic groups, m represents an integer of 0 to 3, and X+ represents an ion selected from hydrogen ion, an alkali metal ion and ammonium ion, which is excellent in proton conductivity, thermal resistance and strength. The polymer electrolyte is soluble in solvents and has excellent film forming property and recycling efficiency.
摘要翻译： 在主链中具有由下式（1）表示的结构单元的聚合物电解质：<？in-line-formula description =“In-line formula”end =“lead”→> - [Ar < （SO 2 -N） - （SO 2 - ） - SO 2 - （SO 2 - ） - SO 2 - （X + O） - SO 2 - （SO 2 - ） - SO 2 - 其中Ar
-O] - （1）<？in-line-formula description =“In-line Formulas”end =“tail” > 1 和Ar 2独立地表示二价芳族基团，m表示0〜3的整数，X +是表示选自氢离子， 碱金属离子和铵离子，其质子传导性，耐热性和强度优异。 聚合物电解质溶于溶剂中，具有优异的成膜性能和循环利用效率。 -
公开(公告)号：US5985477A
公开(公告)日：1999-11-16
申请号：US997564
申请日：1997-12-23
CPC分类号： H01M8/1083 , H01M8/0289 , H01M8/1027 , H01M8/1032 , H01M8/1067 , H01M8/1072 , H01M8/1081 , Y02P70/56
摘要： Provided is a polymer electrolyte which is cheap and easily synthesized, and has a high water resistance and high output performance.The polymer electrolyte comprising a sulfonated polymer having an ion-exchange group equivalent weight of 500 to 2500 g/mol, which is obtainable by sulfonating a structural unit represented by the structural formula (II) of a copolymer having 95 to 40 mol % of a structural unit represented by the following structural formula (I) and 5 to 60 mol % of a structural unit represented by the following structural formula (II), ##STR1##
摘要翻译： 提供一种廉价且易于合成的高分子电解质，具有高耐水性和高输出性能。 该聚合物电解质包含离子交换基团当量为500〜2500g / mol的磺化聚合物，其可通过将具有95〜40mol％的结构式（II）的结构式（II）表示的结构单元磺化， 由下述结构式（I）表示的结构单元和5〜60摩尔％的由下述结构式（II）表示的结构单元，
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7.发明授权Polymer composite material, optical material including the same, and thermoplastic aromatic polymer 有权聚合物复合材料，包括其的光学材料和热塑性芳族聚合物公开(公告)号：US08367757B2
公开(公告)日：2013-02-05
申请号：US12812841
申请日：2008-11-25
申请人： Yusuke Imai , Atsushi Terahara
发明人： Yusuke Imai , Atsushi Terahara
IPC分类号： C08K3/10
CPC分类号： C08G63/672 , C08K3/22 , C08L67/03 , G02B1/10
摘要： The present invention develops a new thermoplastic aromatic polymer in which metal oxide particles can be uniformly dispersed even without any special functional group in the polymer, and provides a high-performance polymer composite material including the thermoplastic aromatic polymer. A polymer composite material of the present invention includes: a polymer matrix including a thermoplastic aromatic polymer having both an ester bond and an ether bond; and metal oxide particles dispersed in the polymer matrix.
摘要翻译： 本发明开发出一种新的热塑性芳族聚合物，其中金属氧化物颗粒在聚合物中即使没有任何特殊的官能团也能均匀分散，并且提供了包括热塑性芳族聚合物的高性能聚合物复合材料。 本发明的聚合物复合材料包括：包含具有酯键和醚键的热塑性芳族聚合物的聚合物基体; 和分散在聚合物基质中的金属氧化物颗粒。
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公开(公告)号：US20060182678A1
公开(公告)日：2006-08-17
申请号：US10531265
申请日：2003-10-14
申请人： Hiroshi Shinoda , Atsushi Terahara
发明人： Hiroshi Shinoda , Atsushi Terahara
IPC分类号： C01B31/00
CPC分类号： C08L53/00 , C08G65/00 , C08G65/007 , C08G65/40 , C08J5/2256 , C08J2371/12 , C08J2387/00 , H01B1/122 , H01M4/86 , H01M8/1004 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1039 , H01M2300/0082 , C08L2666/02
摘要： The present invention relates to a block copolymer having at least one block having an acid group and at least one block having substantially no acid group, wherein one end group of a repeating unit in at least one block of all blocks is oxygen and/or sulfur, and at least one repeating unit of a block having substantially no acid group contains a halogen atom. The block copolymer of the present invention gives a polymer electrolyte membrane which is excellent not only in heat resistance and proton conductivity but also in water resistance and chemical stability, and is useful as an electrolyte for a proton conducting membrane etc. of a fuel cell.
摘要翻译： 本发明涉及具有至少一个具有酸基的嵌段和至少一个基本上没有酸基的嵌段的嵌段共聚物，其中所有嵌段的至少一个嵌段中的重复单元的一个端基是氧和/或硫 ，并且基本上不含酸基的嵌段的至少一个重复单元含有卤素原子。 本发明的嵌段共聚物得到不仅在耐热性和质子传导性以及耐水性和化学稳定性方面优异的高分子电解质膜，而且可用作燃料电池的质子传导膜等的电解质。
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公开(公告)号：US07910686B2
公开(公告)日：2011-03-22
申请号：US10531265
申请日：2003-10-14
申请人： Hiroshi Shinoda , Atsushi Terahara
发明人： Hiroshi Shinoda , Atsushi Terahara
IPC分类号： C08G73/24
CPC分类号： C08L53/00 , C08G65/00 , C08G65/007 , C08G65/40 , C08J5/2256 , C08J2371/12 , C08J2387/00 , H01B1/122 , H01M4/86 , H01M8/1004 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1039 , H01M2300/0082 , C08L2666/02
摘要： The present invention relates to a block copolymer having at least one block having an acid group and at least one block having substantially no acid group, wherein one end group of a repeating unit in at least one block of all blocks is oxygen and/or sulfur, and at least one repeating unit of a block having substantially no acid group contains a halogen atom. The block copolymer of the present invention gives a polymer electrolyte membrane which is excellent not only in heat resistance and proton conductivity but also in water resistance and chemical stability, and is useful as an electrolyte for a proton conducting membrane etc. of a fuel cell.
摘要翻译： 本发明涉及具有至少一个具有酸基的嵌段和至少一个基本上没有酸基的嵌段的嵌段共聚物，其中所有嵌段的至少一个嵌段中的重复单元的一个端基是氧和/或硫 ，并且基本上不含酸基的嵌段的至少一个重复单元含有卤素原子。 本发明的嵌段共聚物得到不仅在耐热性和质子传导性以及耐水性和化学稳定性方面优异的高分子电解质膜，而且可用作燃料电池的质子传导膜等的电解质。
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10.发明申请POLYMER COMPOSITE MATERIAL, OPTICAL MATERIAL INCLUDING THE SAME, AND THERMOPLASTIC AROMATIC POLYMER 有权聚合物复合材料，包括其的光学材料和热塑性芳族聚合物公开(公告)号：US20110046285A1
公开(公告)日：2011-02-24
申请号：US12812841
申请日：2008-11-25
申请人： Yusuke Imai , Atsushi Terahara
发明人： Yusuke Imai , Atsushi Terahara
IPC分类号： C08K3/22
CPC分类号： C08G63/672 , C08K3/22 , C08L67/03 , G02B1/10
摘要： The present invention develops a new thermoplastic aromatic polymer in which metal oxide particles can be uniformly dispersed even without any special functional group in the polymer, and provides a high-performance polymer composite material including the thermoplastic aromatic polymer. A polymer composite material of the present invention includes: a polymer matrix including a thermoplastic aromatic polymer having both an ester bond and an ether bond; and metal oxide particles dispersed in the polymer matrix.
摘要翻译： 本发明开发出一种新的热塑性芳族聚合物，其中金属氧化物颗粒在聚合物中即使没有任何特殊的官能团也能均匀分散，并且提供了包括热塑性芳族聚合物的高性能聚合物复合材料。 本发明的聚合物复合材料包括：包含具有酯键和醚键的热塑性芳族聚合物的聚合物基体; 和分散在聚合物基质中的金属氧化物颗粒。
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