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    Process for the ortho-alkylation of phenolic compounds
    3.
    发明授权
    Process for the ortho-alkylation of phenolic compounds 失效
    酚类化合物的邻烷基化方法

    公开(公告)号：US4388478A

    公开(公告)日：1983-06-14

    申请号：US316800

    申请日：1981-10-30

    申请人： Akihide Kudoh ,  Motoo Kawamata ,  Kazushi Ohshima ,  Makoto Kotani ,  Takeshi Tsuda ,  Fukuichi Aoki

    发明人： Akihide Kudoh ,  Motoo Kawamata ,  Kazushi Ohshima ,  Makoto Kotani ,  Takeshi Tsuda ,  Fukuichi Aoki

    IPC分类号： B01J23/00 ,  B01J23/32 ,  B01J23/34 ,  C07B61/00 ,  C07C27/00 ,  C07C37/16 ,  C07C39/06 ,  C07C67/00

    CPC分类号： B01J23/32 ,  C07C37/16

    摘要： This invention relates to a process for the selective ortho-alkylation of a phenolic compound having at least one ortho-positioned hydrogen atom by catalytically reacting the phenolic compound with an alcohol in the vapor phase. In this process, the reaction of the phenolic compound with the alcohol is carried out at a temperature of from 300.degree. to 550.degree. C. in the presence of a catalyst containing manganese oxide and one or more additives selected from group (A) consisting of germanium oxide, tin oxide and lead oxide, or a catalyst containing manganese oxide, one or more additives selected from the aforesaid group (A), and one or more additives selected from group (B) consisting of alkali metal oxides and alkaline earth metal oxides. The catalyst used in this invention exhibits not only excellent catalytic activity in the selective ortho-alkylation of phenols, continuous stability of the activity, good shapeability and good mechanical strength but also effective utilization of alcohols.

    摘要翻译： 本发明涉及一种通过使酚类化合物与气相中的醇催化反应，使具有至少一个邻位氢原子的酚类化合物选择性正烷基化的方法。 在该方法中，酚类化合物与醇的反应在含有氧化锰和一种或多种选自（A）组成的催化剂的催化剂存在下，在300〜550℃的温度下进行。 或者含有氧化锰的催化剂，选自上述组（A）的一种或多种添加剂和选自由碱金属氧化物和碱土金属氧化物组成的组（B）的一种或多种添加剂 。 用于本发明的催化剂不仅在酚的选择性邻烷基化中表现出优异的催化活性，活性的连续稳定性，良好的成型性和良好的机械强度，而且有效地利用醇。

    Process for the ortho-alkylation of phenolic compounds
    6.
    发明授权
    Process for the ortho-alkylation of phenolic compounds 失效
    酚类化合物的邻烷基化方法

    公开(公告)号：US4390737A

    公开(公告)日：1983-06-28

    申请号：US316781

    申请日：1981-10-30

    申请人： Akihide Kudoh ,  Motoo Kawamata ,  Kazushi Ohshima ,  Makoto Kotani ,  Takeshi Tsuda ,  Satoshi Morita

    发明人： Akihide Kudoh ,  Motoo Kawamata ,  Kazushi Ohshima ,  Makoto Kotani ,  Takeshi Tsuda ,  Satoshi Morita

    IPC分类号： B01J23/00 ,  B01J23/32 ,  C07B61/00 ,  C07C27/00 ,  C07C37/16 ,  C07C39/06 ,  C07C67/00

    CPC分类号： B01J23/32 ,  C07C37/16

    摘要： This invention relates to a process for the selective ortho-alkylation of a phenolic compound having at least one ortho-positioned hydrogen atom by catalytically reacting the phenolic compound with an alcohol in the vapor phase. In this process, the reaction of the phenolic compound with the alcohol is carried out at a temperature of from 300.degree. to 550.degree. C. in the presence of a catalyst containing manganese oxide, silicon oxide and one or more additives selected from group (A) consisting of germanium oxide, tin oxide and lead oxide, or a catalyst containing manganese oxide, silicon oxide, one or more additives selected from the aforesaid group (A), and one or more additives selected from group (B) consisting of alkali metal oxides and alkaline earth metal oxides. The catalyst used in this invention exhibits not only excellent catalytic activity in the selective ortho-alkylation of phenols, continuous stability of the activity, good shapability, and good mechanical strength but also effective utilization of alcohols.

    摘要翻译： 本发明涉及一种通过使酚类化合物与气相中的醇催化反应，使具有至少一个邻位氢原子的酚类化合物选择性正烷基化的方法。 在该方法中，酚类化合物与醇的反应在含有氧化锰，氧化硅和选自组（A）的一种或多种添加剂的催化剂存在下，在300-550℃的温度下进行。 ），或者含有氧化锰，氧化硅，选自上述组（A）的一种或多种添加剂的一种或多种添加剂和选自由碱金属（B）组成的组分（B））的一种或多种添加剂组成的催化剂，由氧化锗，氧化锡和氧化铅组成的催化剂， 氧化物和碱土金属氧化物。 用于本发明的催化剂不仅在酚的选择性邻烷基化中具有优异的催化活性，活性的连续稳定性，良好的成型性和良好的机械强度，而且还有效地利用醇。

    Process for the selective ortho-alkylation of phenolic compounds
    8.
    发明授权
    Process for the selective ortho-alkylation of phenolic compounds 失效
    酚类化合物的选择性邻烷基化方法

    公开(公告)号：US4227023A

    公开(公告)日：1980-10-07

    申请号：US966356

    申请日：1978-12-04

    申请人： Motoo Kawamata ,  Tadamitsu Kiyoura ,  Kazushi Ohshima ,  Yasuo Kogure ,  Akihide Kudoh ,  Makoto Kotani

    发明人： Motoo Kawamata ,  Tadamitsu Kiyoura ,  Kazushi Ohshima ,  Yasuo Kogure ,  Akihide Kudoh ,  Makoto Kotani

    IPC分类号： B01J21/00 ,  B01J23/00 ,  B01J23/34 ,  C07B61/00 ,  C07C27/00 ,  C07C37/16 ,  C07C39/06 ,  C07C67/00 ,  C07C37/14

    CPC分类号： B01J23/34 ,  C07C37/16

    摘要： This invention relates to a process for the selective ortho-alkylation of a phenolic compound having at least one ortho-positioned a hydrogen atom by catalytically reacting the phenolic compound with an alcohol in the vapor phase. In this process, the reaction of the phenolic compound with the alcohol is carried out at a temperature of from 300.degree. to 550.degree. C. in the presence of a mixed oxide catalyst of manganese, silicon, and one or more additives selected from the group consisting of magnesium oxide, calcium oxide, strontium oxide, and barium oxide. The catalyst used in this invention exhibits not only excellent catalytic activity in the selective ortho-alkylation of phenols but also continuous stability of the activity, good shapability, and good mechanical strength.

    摘要翻译： 本发明涉及一种通过使酚类化合物与气相中的醇催化反应，使具有至少一个邻位氢原子的酚类化合物进行选择性邻位烷基化的方法。 在该方法中，酚类化合物与醇的反应在300℃至550℃的温度下，在锰，硅和一种或多种选自以下的添加剂的混合氧化物催化剂存在下进行： 由氧化镁，氧化钙，氧化锶和氧化钡组成。 用于本发明的催化剂不仅在酚的选择性邻烷基化中具有优异的催化活性，而且具有活性的连续稳定性，良好的成型性和良好的机械强度。