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    METHOD FOR MANUFACTURING OLEFIN
    2.
    发明申请
    METHOD FOR MANUFACTURING OLEFIN 审中-公开
    制备烯烃的方法

    公开(公告)号：US20120016172A1

    公开(公告)日：2012-01-19

    申请号：US13259268

    申请日：2010-03-31

    申请人： Satoru Miyazoe ,  Hirokazu Ikenaga ,  Makoto Kotani

    发明人： Satoru Miyazoe ,  Hirokazu Ikenaga ,  Makoto Kotani

    IPC分类号： C07C5/23 ,  C01F17/00 ,  B01J21/02 ,  C07C5/27

    CPC分类号： B01J23/10 ,  B01J23/002 ,  B01J23/007 ,  B01J23/02 ,  B01J23/24 ,  B01J23/30 ,  B01J23/36 ,  B01J35/0006 ,  B01J35/1014 ,  B01J37/0009 ,  B01J2523/00 ,  C07C5/2512 ,  C07C6/04 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/10 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/36 ,  Y02P20/52 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/36 ,  C07C11/06 ,  C07C11/08

    摘要： A method for manufacturing an olefin through reaction between the same type of or different types of raw material olefins to obtain an olefin having a structure different from the structure of the raw material olefins, the method including using a catalyst containing at least one type of metal element selected from the group consisting of tungsten, molybdenum, and rhenium together with other specific catalysts. In the method, side reactions of a metathesis reaction can be suppressed and the selectivity of a desired product can be increased by facilitating double bond isomerization of raw material olefins. Furthermore, the desired product can be obtained efficiently at a high productivity by maintaining the activity of a metathesis catalyst for a long term and suppressing deterioration of performance of a catalyst (isomerization catalyst) for facilitating double bond isomerization of the raw material olefins.

    摘要翻译： 一种通过相同类型或不同类型的原料烯烃之间的反应制备烯烃的方法，以获得具有不同于原料烯烃结构的结构的烯烃，该方法包括使用含有至少一种类型的金属的催化剂 元素选自钨，钼和铼以及其他特定的催化剂。 在该方法中，可以抑制复分解反应的副反应，并且通过促进原料烯烃的双键异构化可以提高所需产物的选择性。 此外，为了促进原料烯烃的双键异构化，可以通过长时间保持复分解催化剂的活性并抑制催化剂（异构化催化剂）的性能劣化，从而以高生产率有效地获得所需的产物。

    OLEFIN PRODUCTION PROCESS
    3.
    发明申请
    OLEFIN PRODUCTION PROCESS 失效
    OLEFIN生产过程

    公开(公告)号：US20110152595A1

    公开(公告)日：2011-06-23

    申请号：US13060578

    申请日：2009-08-27

    申请人： Toshihiro Takai ,  Hirokazu Ikenaga ,  Makoto Kotani ,  Satoru Miyazoe

    发明人： Toshihiro Takai ,  Hirokazu Ikenaga ,  Makoto Kotani ,  Satoru Miyazoe

    IPC分类号： C07C2/88 ,  C07C1/20

    CPC分类号： C07C6/04 ,  C07C5/2775 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/16 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/36 ,  C07C2527/232 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/08

    摘要： A process is provided which is capable of producing olefins stably and efficiently by a metathesis reaction of identical or different olefins while preventing the lowering in metathesis catalyst activity due to trace impurities such as heteroatom-containing compounds that are contained in a starting olefin.The olefin production process includes supplying a starting olefin containing more than 0 ppm by weight to not more than 10 ppm by weight of one or more kinds of heteroatom-containing compounds to a reactor that contains a metathesis catalyst and an isomerization catalyst, the metathesis catalyst including at least one metal element selected from the group consisting of tungsten, molybdenum and rhenium, the isomerization catalyst including calcined hydrotalcite or yttrium oxide, and performing a metathesis reaction of identical or different olefins.

    摘要翻译： 提供了能够通过相同或不同烯烃的复分解反应稳定有效地生产烯烃的方法，同时防止由于起始烯烃中所含的含杂原子的化合物的微量杂质引起的复分解催化剂活性的降低。 烯烃生产方法包括向含有复分解催化剂和异构化催化剂的反应器中提供含有大于0ppm重量至不超过10ppm重量的一种或多种含杂原子的化合物的起始烯烃，复分解催化剂 包括选自钨，钼和铼的至少一种金属元素，所述异构化催化剂包括煅烧水滑石或氧化钇，并进行相同或不同烯烃的复分解反应。

    Process for the ortho-alkylation of phenolic compounds
    5.
    发明授权
    Process for the ortho-alkylation of phenolic compounds 失效
    酚类化合物的邻烷基化方法

    公开(公告)号：US4390737A

    公开(公告)日：1983-06-28

    申请号：US316781

    申请日：1981-10-30

    申请人： Akihide Kudoh ,  Motoo Kawamata ,  Kazushi Ohshima ,  Makoto Kotani ,  Takeshi Tsuda ,  Satoshi Morita

    发明人： Akihide Kudoh ,  Motoo Kawamata ,  Kazushi Ohshima ,  Makoto Kotani ,  Takeshi Tsuda ,  Satoshi Morita

    IPC分类号： B01J23/00 ,  B01J23/32 ,  C07B61/00 ,  C07C27/00 ,  C07C37/16 ,  C07C39/06 ,  C07C67/00

    CPC分类号： B01J23/32 ,  C07C37/16

    摘要： This invention relates to a process for the selective ortho-alkylation of a phenolic compound having at least one ortho-positioned hydrogen atom by catalytically reacting the phenolic compound with an alcohol in the vapor phase. In this process, the reaction of the phenolic compound with the alcohol is carried out at a temperature of from 300.degree. to 550.degree. C. in the presence of a catalyst containing manganese oxide, silicon oxide and one or more additives selected from group (A) consisting of germanium oxide, tin oxide and lead oxide, or a catalyst containing manganese oxide, silicon oxide, one or more additives selected from the aforesaid group (A), and one or more additives selected from group (B) consisting of alkali metal oxides and alkaline earth metal oxides. The catalyst used in this invention exhibits not only excellent catalytic activity in the selective ortho-alkylation of phenols, continuous stability of the activity, good shapability, and good mechanical strength but also effective utilization of alcohols.

    摘要翻译： 本发明涉及一种通过使酚类化合物与气相中的醇催化反应，使具有至少一个邻位氢原子的酚类化合物选择性正烷基化的方法。 在该方法中，酚类化合物与醇的反应在含有氧化锰，氧化硅和选自组（A）的一种或多种添加剂的催化剂存在下，在300-550℃的温度下进行。 ），或者含有氧化锰，氧化硅，选自上述组（A）的一种或多种添加剂的一种或多种添加剂和选自由碱金属（B）组成的组分（B））的一种或多种添加剂组成的催化剂，由氧化锗，氧化锡和氧化铅组成的催化剂， 氧化物和碱土金属氧化物。 用于本发明的催化剂不仅在酚的选择性邻烷基化中具有优异的催化活性，活性的连续稳定性，良好的成型性和良好的机械强度，而且还有效地利用醇。

    Olefin production process
    8.
    发明授权
    Olefin production process 失效
    烯烃生产过程

    公开(公告)号：US08299313B2

    公开(公告)日：2012-10-30

    申请号：US13060578

    申请日：2009-08-27

    申请人： Toshihiro Takai ,  Hirokazu Ikenaga ,  Makoto Kotani ,  Satoru Miyazoe

    发明人： Toshihiro Takai ,  Hirokazu Ikenaga ,  Makoto Kotani ,  Satoru Miyazoe

    IPC分类号： C07C2/88

    CPC分类号： C07C6/04 ,  C07C5/2775 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/16 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/36 ,  C07C2527/232 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/08

    摘要： A process is provided which is capable of producing olefins stably and efficiently by a metathesis reaction of identical or different olefins while preventing the lowering in metathesis catalyst activity due to trace impurities such as heteroatom-containing compounds that are contained in a starting olefin.The olefin production process includes supplying a starting olefin containing more than 0 ppm by weight to not more than 10 ppm by weight of one or more kinds of heteroatom-containing compounds to a reactor that contains a metathesis catalyst and an isomerization catalyst, the metathesis catalyst including at least one metal element selected from the group consisting of tungsten, molybdenum and rhenium, the isomerization catalyst including calcined hydrotalcite or yttrium oxide, and performing a metathesis reaction of identical or different olefins.

    摘要翻译： 提供了能够通过相同或不同烯烃的复分解反应稳定有效地生产烯烃的方法，同时防止由于起始烯烃中所含的含杂原子的化合物的微量杂质引起的复分解催化剂活性的降低。 烯烃生产方法包括向含有复分解催化剂和异构化催化剂的反应器中提供含有大于0ppm重量至不超过10ppm重量的一种或多种含杂原子的化合物的起始烯烃，复分解催化剂 包括选自钨，钼和铼的至少一种金属元素，所述异构化催化剂包括煅烧水滑石或氧化钇，并进行相同或不同烯烃的复分解反应。

    Electronic apparatus having radio transmitter
    9.
    发明授权
    Electronic apparatus having radio transmitter 失效
    具有无线电发射机的电子设备

    公开(公告)号：US07003270B2

    公开(公告)日：2006-02-21

    申请号：US10062476

    申请日：2002-02-05

    申请人： Nobuhide Maruo ,  Makoto Saotome ,  Makoto Kotani

    发明人： Nobuhide Maruo ,  Makoto Saotome ,  Makoto Kotani

    IPC分类号： H04B1/04

    CPC分类号： H04B15/005 ,  H04B2215/069

    摘要： An electronic apparatus comprising a radio transmitter is disclosed. In a computer system (1) having a radio transmission circuit (3) of a phase modulation type supplied with power from a power supply (4) of a switching type, the switching frequency of the power supply (4) is determined based on the comparison frequency for the sampling operation of a PLL circuit (10) of the radio transmitter, thereby removing the power noises generated from the switching regulator of the radio transmitter of a phase modulation type.

    摘要翻译： 公开了一种包括无线电发射机的电子设备。 在具有从切换式电源（4）供给电力的相位调制型无线发送电路（3）的计算机系统（1）中，根据电源（4）的开关频率， 用于无线电发射机的PLL电路（10）的采样操作的比较频率，从而消除从相位调制类型的无线电发射机的开关调节器产生的电力噪声。

    Process for the selective ortho-alkylation of phenolic compounds
    10.
    发明授权
    Process for the selective ortho-alkylation of phenolic compounds 失效
    酚类化合物的选择性邻烷基化方法

    公开(公告)号：US4227023A

    公开(公告)日：1980-10-07

    申请号：US966356

    申请日：1978-12-04

    申请人： Motoo Kawamata ,  Tadamitsu Kiyoura ,  Kazushi Ohshima ,  Yasuo Kogure ,  Akihide Kudoh ,  Makoto Kotani

    发明人： Motoo Kawamata ,  Tadamitsu Kiyoura ,  Kazushi Ohshima ,  Yasuo Kogure ,  Akihide Kudoh ,  Makoto Kotani

    IPC分类号： B01J21/00 ,  B01J23/00 ,  B01J23/34 ,  C07B61/00 ,  C07C27/00 ,  C07C37/16 ,  C07C39/06 ,  C07C67/00 ,  C07C37/14

    CPC分类号： B01J23/34 ,  C07C37/16

    摘要： This invention relates to a process for the selective ortho-alkylation of a phenolic compound having at least one ortho-positioned a hydrogen atom by catalytically reacting the phenolic compound with an alcohol in the vapor phase. In this process, the reaction of the phenolic compound with the alcohol is carried out at a temperature of from 300.degree. to 550.degree. C. in the presence of a mixed oxide catalyst of manganese, silicon, and one or more additives selected from the group consisting of magnesium oxide, calcium oxide, strontium oxide, and barium oxide. The catalyst used in this invention exhibits not only excellent catalytic activity in the selective ortho-alkylation of phenols but also continuous stability of the activity, good shapability, and good mechanical strength.

    摘要翻译： 本发明涉及一种通过使酚类化合物与气相中的醇催化反应，使具有至少一个邻位氢原子的酚类化合物进行选择性邻位烷基化的方法。 在该方法中，酚类化合物与醇的反应在300℃至550℃的温度下，在锰，硅和一种或多种选自以下的添加剂的混合氧化物催化剂存在下进行： 由氧化镁，氧化钙，氧化锶和氧化钡组成。 用于本发明的催化剂不仅在酚的选择性邻烷基化中具有优异的催化活性，而且具有活性的连续稳定性，良好的成型性和良好的机械强度。