公开(公告)号：US5387635A

公开(公告)日：1995-02-07

申请号：US924032

申请日：1992-08-27

申请人： Michael E. Rowland ,  Kenneth E. Springs

发明人： Michael E. Rowland ,  Kenneth E. Springs

IPC分类号： C08F8/42 ,  C08F8/44 ,  C08J3/05 ,  C08J5/18 ,  C08L23/00 ,  C08L23/26 ,  C08L33/02 ,  C09D123/26 ,  C09D133/02 ,  C09J133/02 ,  C08K5/00

CPC分类号： C08F8/44

摘要： Aqueous dispersions of ethylene/.alpha.,.beta.-unsaturated carboxylic acid interpolymers (e.g., random ethylene/acrylic acid interpolymers) are formed using a mixture of bases at a concentration of at least 0.2 equivalents of base per mole of .alpha.,.beta.-unsaturated carboxylic acid. The dispersions have at least 10 weight percent dispersed solids and not more than 1 weight percent of the initial polymer in non-dispersed form. Preferred bases for use in forming the dispersions are ammonium hydroxide and/or alkali metal hydroxides. A mixture of ammonium hydroxide and potassium hydroxide is especially preferred for forming the dispersions with ethylene/acrylic acid interpolymers at an ammonium hydroxide:acrylic acid molar ratio of 1:1 and a potassium hydroxide:acrylic acid molar ratio in the range of 0.6-0.8:1. The dispersions are particularly useful in forming thin coatings of adhesive on substrates, such as paper and metal foil, using conventional techniques.

摘要翻译： PCT No.PCT / US92 / 00622 Sec。 371日期：1992年8月27日 102（e）日期1992年8月27日PCT提交1992年1月24日PCT公布。 第WO92 / 13012号公报 日期为1992年8月6日。乙烯/α，β-不饱和羧酸互聚物（例如，无规乙烯/丙烯酸互聚物）的水分散体使用碱的混合物形成，碱的浓度为每摩尔 α，β-不饱和羧酸。 分散体具有非分散形式的至少10重量％的分散固体和不超过1重量％的初始聚合物。 用于形成分散体的优选碱是氢氧化铵和/或碱金属氢氧化物。 氢氧化铵和氢氧化钾的混合物特别优选用氢氧化铵：丙烯酸摩尔比为1:1和氢氧化钾：丙烯酸摩尔比为0.6-0.8的乙烯/丙烯酸互聚物形成分散体 ：1。 分散体特别可用于使用常规技术在基材上形成薄的粘合剂涂层，例如纸和金属箔。

公开(公告)号：US5206279A

公开(公告)日：1993-04-27

申请号：US646134

申请日：1991-01-25

申请人： Michael E. Rowland ,  Kenneth E. Springs

发明人： Michael E. Rowland ,  Kenneth E. Springs

IPC分类号： C08F8/42 ,  C08F8/44 ,  C08J3/05 ,  C08J5/18 ,  C08L23/00 ,  C08L23/26 ,  C08L33/02 ,  C09D123/26 ,  C09D133/02 ,  C09J133/02

CPC分类号： C08F8/44

摘要： Aqueous dispersions of ethylene/.alpha.,.beta.-unsaturated carboxylic acid interpolymers (e.g., random ethylene/acrylic acid interpolymers) are formed using a mixture of bases at a concentration of at least about 0.2 equivalents of base per mole of .alpha.,.beta.-unsaturated carboxylic acid. The dispersions have at least about 10 weight percent dispersed solids and not more than about 1 weight percent of the initial polymer in non-dispersed form. Preferred bases for use in forming the dispersions are ammonium hydroxide and/or alkali metal hydroxides. A mixture of ammonium hydroxide and potassium hydroxide is especially preferred for forming the dispersions with ethylene/acrylic acid interpolymers at an ammonium hydroxide:acrylic acid molar ratio of about 1:1 and a potassium hydroxide:acrylic acid molar ratio in the range of about 0.6-0.8:1. The dispersions are particularly useful in forming thin coatings of adhesive on substrates, such as paper and metal foil, using conventional techniques.

摘要翻译： 乙烯/α，β-不饱和羧酸互聚物（例如，无规乙烯/丙烯酸互聚物）的水分散体使用碱的混合物形成，碱的浓度为每摩尔α，β-不饱和羧酸的至少约0.2当量碱 酸。 分散体具有非分散形式的至少约10重量％的分散固体和不超过约1重量％的初始聚合物。 用于形成分散体的优选碱是氢氧化铵和/或碱金属氢氧化物。 氢氧化铵和氢氧化钾的混合物特别优选用氢氧化铵：丙烯酸摩尔比为约1:1和氢氧化钾：丙烯酸摩尔比在约0.6范围内与乙烯/丙烯酸互聚物形成分散体 -0.8：1。 分散体特别可用于使用常规技术在基材上形成薄的粘合剂涂层，例如纸和金属箔。

公开(公告)号：US06482886B1

公开(公告)日：2002-11-19

申请号：US09077793

申请日：1998-09-03

申请人： Malcolm F. Finlayson ,  Kenneth E. Springs ,  John J. Gathers ,  James L. Cooper ,  Walter L. Vaughn ,  Brian H. Schumann ,  Stephen M. Oliver

发明人： Malcolm F. Finlayson ,  Kenneth E. Springs ,  John J. Gathers ,  James L. Cooper ,  Walter L. Vaughn ,  Brian H. Schumann ,  Stephen M. Oliver

IPC分类号： C08L302

CPC分类号： D06M15/11 ,  D06M15/227 ,  D06M15/263 ,  D21H17/28 ,  D21H17/29 ,  D21H17/37 ,  D21H17/43 ,  D21H21/16 ,  D21H23/32

摘要： Fibrous product is externally sized by applying to the material a basic aqueous dispersion of an interpolymer of an ethylenically unsaturated monomer and an ethylenically unsaturated carboxylic acid comonomer. The preferred dispersions which have lower initial viscosities provide dispersion/starch dilute solutions with higher viscosities and improved external sizing effectiveness. Resulting fibrous products are adequately sized and exhibit excellent printability and strength properties.

摘要翻译： 通过向材料施加烯属不饱和单体和烯键式不饱和羧酸共聚单体的互聚物的碱性水性分散体，纤维制品的外部尺寸。 具有较低初始粘度的优选分散体提供具有较高粘度和改进的外部施胶效果的分散体/淀粉稀释溶液。 所得的纤维制品具有适当的尺寸并且具有优异的可印刷性和强度性能。

公开(公告)号：US5993604A

公开(公告)日：1999-11-30

申请号：US687797

申请日：1996-07-19

申请人： Malcolm F. Finlayson ,  Kenneth E. Springs ,  John J. Gathers ,  James L. Cooper ,  Stephen M. Oliver

发明人： Malcolm F. Finlayson ,  Kenneth E. Springs ,  John J. Gathers ,  James L. Cooper ,  Stephen M. Oliver

IPC分类号： D21H17/43 ,  D21H17/07 ,  D21H17/28 ,  D21H17/29 ,  D21H17/37 ,  D21H17/45 ,  D21H17/56 ,  D21H17/66 ,  D21H21/10 ,  D21H21/16 ,  D21H23/76

CPC分类号： D21H21/10 ,  D21H21/16 ,  D21H23/765 ,  D21H17/07 ,  D21H17/28 ,  D21H17/29 ,  D21H17/37 ,  D21H17/375 ,  D21H17/43 ,  D21H17/455 ,  D21H17/56 ,  D21H17/66

摘要： The present pertains to an improved method of internally sizing a cellulosic article and an improved internally sized cellulosic article where a water-dispersible, water- and alkali-insoluble internal sizing agent from an interpolymer of an ethylenically unsaturated hydrocarbon monomer and an ethylenically unsaturated carboxylic acid comonomer is applied to fiber stock or pulp slurry some amount of time subsequent to the instance of application of a retention aid. The invention also includes a novel internal sizing composition where the interpolymer is rendered water-dispersible by reaction with an inorganic neutralizing cationic compound. The improved method is particularly well suited for paper making wherein substantially improved sizing performance is obtainable. Internal sizing agents based on inorganic neutralizing cationic compounds such as, for example, potassium hydroxide, provide the surprising advantage of hard water resistance.

摘要翻译： 本发明涉及一种改进的纤维素制品内部施胶方法和改进的内部尺寸纤维素制品，其中水分散性，水和碱不溶性内部施胶剂来自烯属不饱和烃单体和烯属不饱和羧酸的互聚物 共聚单体在施用助留剂之后的一段时间内施加到纤维原料或纸浆中。 本发明还包括一种新颖的内部施胶组合物，其中互聚物通过与无机中和阳离子化合物的反应而水分散。 改进的方法特别适用于纸张制造，其中可以获得大大改善的施胶性能。 基于无机中和阳离子化合物例如氢氧化钾的内部施胶剂提供了耐水硬性的惊人优点。