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    Method of preparing aqueous dispersions of ethylene/.alpha.,.beta.-unsaturated carboxylic acid interpolymers
    3.
    发明授权
    Method of preparing aqueous dispersions of ethylene/.alpha.,.beta.-unsaturated carboxylic acid interpolymers 失效
    制备乙烯/（ALPHA），（BETA） - 饱和羧酸类嵌段共聚物的水性分散体的方法

    公开(公告)号：US5206279A

    公开(公告)日：1993-04-27

    申请号：US646134

    申请日：1991-01-25

    申请人： Michael E. Rowland ,  Kenneth E. Springs

    发明人： Michael E. Rowland ,  Kenneth E. Springs

    IPC分类号： C08F8/42 ,  C08F8/44 ,  C08J3/05 ,  C08J5/18 ,  C08L23/00 ,  C08L23/26 ,  C08L33/02 ,  C09D123/26 ,  C09D133/02 ,  C09J133/02

    CPC分类号： C08F8/44

    摘要： Aqueous dispersions of ethylene/.alpha.,.beta.-unsaturated carboxylic acid interpolymers (e.g., random ethylene/acrylic acid interpolymers) are formed using a mixture of bases at a concentration of at least about 0.2 equivalents of base per mole of .alpha.,.beta.-unsaturated carboxylic acid. The dispersions have at least about 10 weight percent dispersed solids and not more than about 1 weight percent of the initial polymer in non-dispersed form. Preferred bases for use in forming the dispersions are ammonium hydroxide and/or alkali metal hydroxides. A mixture of ammonium hydroxide and potassium hydroxide is especially preferred for forming the dispersions with ethylene/acrylic acid interpolymers at an ammonium hydroxide:acrylic acid molar ratio of about 1:1 and a potassium hydroxide:acrylic acid molar ratio in the range of about 0.6-0.8:1. The dispersions are particularly useful in forming thin coatings of adhesive on substrates, such as paper and metal foil, using conventional techniques.

    摘要翻译： 乙烯/α，β-不饱和羧酸互聚物（例如，无规乙烯/丙烯酸互聚物）的水分散体使用碱的混合物形成，碱的浓度为每摩尔α，β-不饱和羧酸的至少约0.2当量碱 酸。 分散体具有非分散形式的至少约10重量％的分散固体和不超过约1重量％的初始聚合物。 用于形成分散体的优选碱是氢氧化铵和/或碱金属氢氧化物。 氢氧化铵和氢氧化钾的混合物特别优选用氢氧化铵：丙烯酸摩尔比为约1:1和氢氧化钾：丙烯酸摩尔比在约0.6范围内与乙烯/丙烯酸互聚物形成分散体 -0.8：1。 分散体特别可用于使用常规技术在基材上形成薄的粘合剂涂层，例如纸和金属箔。

    Process of rheology modification of polymers
    5.
    发明授权
    Process of rheology modification of polymers 有权
    聚合物流变改性工艺

    公开(公告)号：US06552129B2

    公开(公告)日：2003-04-22

    申请号：US10013152

    申请日：2001-12-10

    申请人： David A. Babb ,  Che-I Kao ,  Wendy D. Hoenig ,  Michael E. Rowland ,  Clark H. Cummins ,  H. Craig Silvis ,  Michael J. Mullins ,  Thoi H. Ho

    发明人： David A. Babb ,  Che-I Kao ,  Wendy D. Hoenig ,  Michael E. Rowland ,  Clark H. Cummins ,  H. Craig Silvis ,  Michael J. Mullins ,  Thoi H. Ho

    IPC分类号： C08F800

    CPC分类号： C08L23/02 ,  C08G81/02 ,  C08K5/43 ,  C08L23/04 ,  C08L23/06 ,  C08L23/08 ,  C08L23/0815 ,  C08L23/0838 ,  C08L23/0853 ,  C08L23/16 ,  C08L2205/22 ,  C08L2312/00 ,  C08L2314/06 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/1386 ,  Y10T428/139 ,  Y10T428/31913 ,  Y10T428/31917 ,  C08L2666/04

    摘要： The invention includes a process of reacting a poly(sulfonyl azide) with a polymer comprising steps (a) forming a first admixture of a first amount of a first polymer or in a liquid which does not require removal from the polymer and a poly(sulfonyl azide); (b) then forming a second admixture of the first admixture with a second amount of at least one second polymer; and (c) heating the second admixture at least to the decomposition temperature of the coupling agent for a time sufficient to result in coupling of polymer chains. The invention further includes all compositions obtainable by processes of the invention as well as blends of those compositions with one or more polymers of compositions different from the first or second polymer or the product of a process of the invention. Additionally the invention includes articles made from compositions of the invention, and shaping those articles particularly by processes which comprise shaping the compositions in a melted state into an article, more preferably when the process comprises thermoforming, injection molding, extrusion, casting, blow molding, foaming or blowing as well as the use of the compositions in those processes.

    摘要翻译： 本发明包括使聚（磺酰基叠氮化物）与聚合物反应的方法，包括步骤（a）形成第一量的第一聚合物的第一混合物或不需要从聚合物中除去的液体和聚（磺酰基 叠氮化物）; （b）然后形成第一混合物与第二量的至少一种第二聚合物的第二混合物; 和（c）至少加热第二混合物至偶联剂的分解温度足以导致聚合物链偶联的时间。 本发明还包括可通过本发明的方法获得的所有组合物以及这些组合物与一种或多种不同于第一或第二聚合物或本发明方法的产物的组合物的一种或多种聚合物的共混物。 另外，本发明包括由本发明的组合物制成的制品，特别是通过包括将熔融状态的组合物成型成制品的方法成型，更优选当该方法包括热成型，注射成型，挤出，铸造，吹塑成型， 发泡或吹塑以及在这些方法中使用组合物。

    Aqueous dispersions of ethylene/.alpha.,.beta.-unsaturated carboxylic acid interpolymers
    7.
    发明授权
    Aqueous dispersions of ethylene/.alpha.,.beta.-unsaturated carboxylic acid interpolymers 失效
    乙烯/α，β-不饱和羧酸互聚物的水分散体

    公开(公告)号：US5387635A

    公开(公告)日：1995-02-07

    申请号：US924032

    申请日：1992-08-27

    申请人： Michael E. Rowland ,  Kenneth E. Springs

    发明人： Michael E. Rowland ,  Kenneth E. Springs

    IPC分类号： C08F8/42 ,  C08F8/44 ,  C08J3/05 ,  C08J5/18 ,  C08L23/00 ,  C08L23/26 ,  C08L33/02 ,  C09D123/26 ,  C09D133/02 ,  C09J133/02 ,  C08K5/00

    CPC分类号： C08F8/44

    摘要： Aqueous dispersions of ethylene/.alpha.,.beta.-unsaturated carboxylic acid interpolymers (e.g., random ethylene/acrylic acid interpolymers) are formed using a mixture of bases at a concentration of at least 0.2 equivalents of base per mole of .alpha.,.beta.-unsaturated carboxylic acid. The dispersions have at least 10 weight percent dispersed solids and not more than 1 weight percent of the initial polymer in non-dispersed form. Preferred bases for use in forming the dispersions are ammonium hydroxide and/or alkali metal hydroxides. A mixture of ammonium hydroxide and potassium hydroxide is especially preferred for forming the dispersions with ethylene/acrylic acid interpolymers at an ammonium hydroxide:acrylic acid molar ratio of 1:1 and a potassium hydroxide:acrylic acid molar ratio in the range of 0.6-0.8:1. The dispersions are particularly useful in forming thin coatings of adhesive on substrates, such as paper and metal foil, using conventional techniques.

    摘要翻译： PCT No.PCT / US92 / 00622 Sec。 371日期：1992年8月27日 102（e）日期1992年8月27日PCT提交1992年1月24日PCT公布。 第WO92 / 13012号公报 日期为1992年8月6日。乙烯/α，β-不饱和羧酸互聚物（例如，无规乙烯/丙烯酸互聚物）的水分散体使用碱的混合物形成，碱的浓度为每摩尔 α，β-不饱和羧酸。 分散体具有非分散形式的至少10重量％的分散固体和不超过1重量％的初始聚合物。 用于形成分散体的优选碱是氢氧化铵和/或碱金属氢氧化物。 氢氧化铵和氢氧化钾的混合物特别优选用氢氧化铵：丙烯酸摩尔比为1:1和氢氧化钾：丙烯酸摩尔比为0.6-0.8的乙烯/丙烯酸互聚物形成分散体 ：1。 分散体特别可用于使用常规技术在基材上形成薄的粘合剂涂层，例如纸和金属箔。

    Process of rheology modification of polymers
    9.
    发明授权
    Process of rheology modification of polymers 有权
    聚合物流变改性工艺

    公开(公告)号：US06359073B1

    公开(公告)日：2002-03-19

    申请号：US09694649

    申请日：2000-10-23

    申请人： David A. Babb ,  Che-I Kao ,  Wendy D. Hoenig ,  Michael E. Rowland ,  Clark H. Cummins ,  H. Craig Silvis ,  Michael J. Mullins ,  Thoi H. Ho

    发明人： David A. Babb ,  Che-I Kao ,  Wendy D. Hoenig ,  Michael E. Rowland ,  Clark H. Cummins ,  H. Craig Silvis ,  Michael J. Mullins ,  Thoi H. Ho

    IPC分类号： C08F800

    CPC分类号： C08L23/02 ,  C08G81/02 ,  C08K5/43 ,  C08L23/04 ,  C08L23/06 ,  C08L23/08 ,  C08L23/0815 ,  C08L23/0838 ,  C08L23/0853 ,  C08L23/16 ,  C08L2205/22 ,  C08L2312/00 ,  C08L2314/06 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/1386 ,  Y10T428/139 ,  Y10T428/31913 ,  Y10T428/31917 ,  C08L2666/04

    摘要： The invention includes a process of reacting a poly(sulfonyl azide) with a polymer comprising steps (a) forming a first admixture of a first amount of a first polymer or in a liquid which does not require removal from the polymer and a poly(sulfonyl azide); (b) then forming a second admixture of the first admixture with a second amount of at least one second polymer; and (c) heating the second admixture at lest to the decomposition temperature of the coupling agent for a time sufficient to result in coupling of polymer chains. The invention further includes all compositions obtainable by processes of the invention as well as blends of those compositions with one or more polymers of compositions different from the first or second polymer or the product of a process of the invention. Additionally the invention includes articles made from compositions of the invention, and shaping those articles particularly by processes which comprise shaping the compositions in a melted state into an article, more preferably when the process comprises thermoforming, injection molding, extrusion, casting, blow molding, foaming or blowing as well as the use of the compositions in those processes.

    摘要翻译： 本发明包括使聚（磺酰基叠氮化物）与聚合物反应的方法，包括步骤（a）形成第一量的第一聚合物的第一混合物或不需要从聚合物中除去的液体和聚（磺酰基 叠氮化物）; （b）然后形成第一混合物与第二量的至少一种第二聚合物的第二混合物; 和（c）加热第二混合物至少达到偶联剂的分解温度足以导致聚合物链偶联的时间。 本发明还包括可通过本发明的方法获得的所有组合物以及这些组合物与一种或多种不同于第一或第二聚合物或本发明方法的产物的组合物的一种或多种聚合物的共混物。 另外，本发明包括由本发明的组合物制成的制品，并且特别通过包括将熔融状态的组合物成型成制品的方法成型那些制品，更优选当该方法包括热成型，注射成型，挤出，浇铸，吹塑成型， 发泡或吹塑以及在这些方法中使用组合物。

    Elastomers with improved processability
    10.
    发明授权
    Elastomers with improved processability 有权
    具有改善加工性能的弹性体

    公开(公告)号：US06232410B1

    公开(公告)日：2001-05-15

    申请号：US09140575

    申请日：1998-08-26

    申请人： Michael E. Rowland ,  Che I. Kao

    发明人： Michael E. Rowland ,  Che I. Kao

    IPC分类号： C08F800

    CPC分类号： C08J3/244 ,  C08F8/00 ,  C08F2800/20 ,  C08F2810/20 ,  C08J2323/16 ,  C08K5/14 ,  C08F210/18 ,  C08L23/16

    摘要： A process for improving the green strength of ethylene/&agr;-olefin/diene polymers is described comprising (A) selecting an ethylene/&agr;-olefin/diene polymer having a Mooney viscosity at 125 C up to about 80 and a percent gel (% gel) up to about 30 percent and (B) partially crosslinking the ethylene/&agr;-olefin/diene polymer selected in step (A) to make a modified ethylene/&agr;-olefin/diene polymer satisfying the equations MV≦100 and W ≤ ( MS 2 - MS 1 MS 1 ) wherein MV is the Mooney viscosity of the modified polymer, MS1 is the melt strength in centiNewtons of the polymer selected in step (A) at 110 C, when formulated according to ASTM D3568#2, MS2 is the melt strength in centiNewtons of the modified polymer produced by step (B) measured under the same conditions, and W is 0.3. Modified ethylene/&agr;-olefin/diene polymers obtainable according to the above process or satisfying the equation: MS 2 ≥ ( MV X + % ⁢   ⁢ gel Y ) ⁢ Z is also described in which MS2, MV and % gel of the modified polymer are defined as defined above, X is 50, Y is 20, and Z is 40. Further described is a process for making an article comprising an ethylene/&agr;-olefin/diene polymer and intermediates for making the modified ethylene/&agr;-olefin/diene polymers.

    摘要翻译： 描述了一种用于改善乙烯/α-烯烃/二烯聚合物的生坯强度的方法，其包括（A）选择在125℃至约80的门尼粘度和凝胶百分比（％凝胶）的乙烯/α-烯烃/二烯聚合物 ）至多约30％，和（B）部分交联在步骤（A）中选择的乙烯/α-烯烃/二烯聚合物，以制备满足式MV = 100的改性乙烯/α-烯烃/二烯聚合物，其中MV为 改性聚合物的门尼粘度MS1是在步骤（A）中在110℃选择的聚合物的熔体强度，以110℃的摩尔数计，当根据ASTM D3568＃2配制时，MS2是以步骤1制备的改性聚合物的熔体强度， （B）在相同条件下测量，W为0.3。 还描述了根据上述方法获得的或满足以下等式可获得的改性乙烯/α-烯烃/二烯聚合物：其中改性聚合物的MS2，MV和％凝胶如上定义，X​​为50，Y为20，和 Z是40.进一步描述了制备包含乙烯/α-烯烃/二烯聚合物的制品和制备改性乙烯/α-烯烃/二烯聚合物的中间体的方法。