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公开(公告)号：US20140011963A1
公开(公告)日：2014-01-09
申请号：US13825703
申请日：2011-09-15
申请人： Kevin M. McCauley , Steven Luo
发明人： Kevin M. McCauley , Steven Luo
IPC分类号： C08F136/06 , C08C19/22
CPC分类号： C08F136/06 , B01F17/0035 , C08C19/22 , C08F4/04 , C08F4/12 , C08F36/04 , C08F4/545
摘要： A method for producing a polydiene, the method comprising the steps of: (i) forming an active catalyst by combining a lanthanide-containing compound, an alkylating agent, and a halogen source in the substantial absence of an amine; and (ii) polymerizing conjugated diene monomer in the presence of the active catalyst and an amine.
摘要翻译： 一种制备聚二烯的方法，该方法包括以下步骤：（i）通过在基本不存在胺的情况下将含镧系元素的化合物，烷基化剂和卤素源组合形成活性催化剂; 和（ii）在活性催化剂和胺的存在下聚合共轭二烯单体。
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公开(公告)号：US08623975B2
公开(公告)日：2014-01-07
申请号：US13380938
申请日：2010-06-24
申请人： Steven Luo , Kevin M. McCauley , Jason T. Poulton
发明人： Steven Luo , Kevin M. McCauley , Jason T. Poulton
摘要： A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing takes place within a polymerization mixture that includes less than 20% by weight of organic solvent based on the total weight of the polymerization mixture, and where said step of polymerizing employs a lanthanide-based catalyst system that includes the combination of or reaction product of ingredients including (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a bromine-containing compound selected from the group consisting of elemental bromine, bromine-containing mixed halogens, and organic bromides.
摘要翻译： 一种制备聚二烯的方法，该方法包括在二烃基醚存在下聚合共轭二烯单体的步骤，其中所述聚合步骤在聚合混合物内进行，所述聚合混合物包含基于所述二烯烃醚的少于20重量％的有机溶剂 聚合混合物的总重量，并且在所述聚合步骤中使用镧系元素的催化剂体系，其包括（a）镧系元素化合物，（b）铝氧烷，（c）有机铝化合物 除了铝氧烷外，还有（d）选自元素溴，含溴混合卤素和有机溴化物的含溴化合物。
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公开(公告)号：US20120172553A1
公开(公告)日：2012-07-05
申请号：US13380938
申请日：2010-06-24
申请人： Steven Luo , Kevin M. McCauley , Jason T. Poulton
发明人： Steven Luo , Kevin M. McCauley , Jason T. Poulton
IPC分类号： C08F2/06
摘要： A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing takes place within a polymerization mixture that includes less than 20% by weight of organic solvent based on the total weight of the polymerization mixture, and where said step of polymerizing employs a lanthanide-based catalyst system that includes the combination of or reaction product of ingredients including (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a bromine-containing compound selected from the group consisting of elemental bromine, bromine-containing mixed halogens, and organic bromides.
摘要翻译： 一种制备聚二烯的方法，该方法包括在二烃基醚存在下聚合共轭二烯单体的步骤，其中所述聚合步骤在聚合混合物内进行，所述聚合混合物包含基于所述二烯烃醚的少于20重量％的有机溶剂 聚合混合物的总重量，并且在所述聚合步骤中使用镧系元素的催化剂体系，其包括（a）镧系元素化合物，（b）铝氧烷，（c）有机铝化合物 除了铝氧烷外，还有（d）选自元素溴，含溴混合卤素和有机溴化物的含溴化合物。
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公开(公告)号：US20100273963A1
公开(公告)日：2010-10-28
申请号：US12815841
申请日：2010-06-15
申请人： Steven Luo , Kevin M. McCauley , Jason T. Poulton
发明人： Steven Luo , Kevin M. McCauley , Jason T. Poulton
IPC分类号： C08F4/44
CPC分类号： C08L9/00 , C08F36/04 , Y10S526/902 , C08F4/545
摘要： A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing employs a lanthanide-based catalyst system.
摘要翻译： 一种制备聚二烯的方法，该方法包括在二烃基醚存在下聚合共轭二烯单体的步骤，其中所述聚合步骤使用镧系元素基催化剂体系。
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公开(公告)号：US20090299019A1
公开(公告)日：2009-12-03
申请号：US12490457
申请日：2009-06-24
申请人： Steven Luo , Kevin M. McCauley , Jason T. Poulton
发明人： Steven Luo , Kevin M. McCauley , Jason T. Poulton
IPC分类号： C08F4/06 , C08F136/06
CPC分类号： C08F36/04 , C08L9/00 , Y10S526/902 , C08F4/545
摘要： A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer in the presence of a dihydrocarbyl ether, where said step of polymerizing takes place within a polymerization mixture that includes less than 20% by weight of organic solvent based on the total weight of the polymerization mixture, and where said step of polymerizing employs a lanthanide-based catalyst system that includes the combination of or reaction product of ingredients including (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a bromine-containing compound selected from the group consisting of elemental bromine, bromine-containing mixed halogens, and organic bromides.
摘要翻译： 一种制备聚二烯的方法，该方法包括在二烃基醚存在下聚合共轭二烯单体的步骤，其中所述聚合步骤在聚合混合物内进行，所述聚合混合物包含基于所述二烯烃醚的少于20重量％的有机溶剂 聚合混合物的总重量，并且在所述聚合步骤中使用镧系元素的催化剂体系，其包括（a）镧系元素化合物，（b）铝氧烷，（c）有机铝化合物 除了铝氧烷外，还有（d）选自元素溴，含溴混合卤素和有机溴化物的含溴化合物。
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公开(公告)号：US20080275199A1
公开(公告)日：2008-11-06
申请号：US12113375
申请日：2008-05-01
IPC分类号： C08F4/44
CPC分类号： C08F36/08 , Y10S526/919 , C08F4/52 , C08F4/545
摘要： There is disclosed a process for producing a conjugated diene-containing polymer wherein a stream comprising conjugated diene monomer and a specified catalyst, that includes a lanthanide compound and an aluminoxane, is passed through an orifice into the reaction zone of a polymerization vessel, maintained under specific pressure conditions to form a cement having a viscosity that allows the cement to be conveyed through a devolatilization zone, where desired.
摘要翻译： 公开了一种制备含共轭二烯的聚合物的方法，其中将包含共轭二烯单体和特定催化剂的物流（包括镧系元素化合物和铝氧烷）通过孔进入聚合容器的反应区，保持在 特定压力条件，以形成具有允许粘合剂在需要时通过脱挥发分区域输送的粘度的水泥。
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公开(公告)号：US10221297B2
公开(公告)日：2019-03-05
申请号：US15518984
申请日：2015-10-15
发明人： Amy M. Randall , Yuan-Yong Yan , Kevin M. McCauley
摘要： The present disclosure is directed to rubber compositions containing a chemical additive capable of generating or enhancing strain-induced crystallization into the compositions, and tires containing the rubber compositions in one or more components such as sidewalls or treads. The chemical additive is at least one fatty acid amide compound of formula (I). As well, certain embodiments relate to methods for achieving reduced wear or improved durability in a tire tread or tire sidewall by using the chemical additives.
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8.发明授权公开(公告)号：US09546227B2
公开(公告)日：2017-01-17
申请号：US13976315
申请日：2011-12-30
申请人： Kevin M. McCauley , Steven Luo
发明人： Kevin M. McCauley , Steven Luo
CPC分类号： C08F4/52 , C08F2/02 , C08F4/70 , C08F36/04 , C08F4/7098
摘要： A process for preparing a polydiene, the process comprising the steps of (i) providing conjugated diene monomer; (ii) charging a nickel-based catalyst system to the conjugated diene monomer; and (iii) charging a modulating Lewis base to the conjugated diene monomer, to thereby polymerize the conjugated diene monomer in the presence of the modulating Lewis base, where said step of charging a modulating Lewis base is separate from said step of charging a nickel-based catalyst, and where said steps of providing conjugated diene monomer, charging a nickel-based catalyst system and charging a Lewis base form a polymerization mixture that includes less than 20% by weight of organic solvent based on the total weight of the polymerization mixture.
摘要翻译： 一种制备聚二烯的方法，该方法包括以下步骤：（i）提供共轭二烯单体; （ii）将镍基催化剂体系装入共轭二烯单体; 和（iii）将调节的路易斯碱装入共轭二烯单体，从而在调节路易斯碱的存在下使共轭二烯单体聚合，其中所述调节路易斯碱的装入步骤与将镍 - 并且其中所述提供共轭二烯单体的步骤，加入镍基催化剂体系和加入路易斯碱形成聚合混合物，其包含基于聚合混合物的总重量小于20重量％的有机溶剂。
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公开(公告)号：US09249244B2
公开(公告)日：2016-02-02
申请号：US13825703
申请日：2011-09-15
申请人： Kevin M. McCauley , Steven Luo
发明人： Kevin M. McCauley , Steven Luo
CPC分类号： C08F136/06 , B01F17/0035 , C08C19/22 , C08F4/04 , C08F4/12 , C08F36/04 , C08F4/545
摘要： A method for producing a polydiene, the method comprising the steps of: (i) forming an active catalyst by combining a lanthanide-containing compound, an alkylating agent, and a halogen source in the substantial absence of an amine; and (ii) polymerizing conjugated diene monomer in the presence of the active catalyst and an amine.
摘要翻译： 一种制备聚二烯的方法，该方法包括以下步骤：（i）通过在基本上不存在胺的情况下将含镧系元素的化合物，烷基化剂和卤素源组合形成活性催化剂; 和（ii）在活性催化剂和胺的存在下聚合共轭二烯单体。
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10.发明授权公开(公告)号：US08987395B2
公开(公告)日：2015-03-24
申请号：US13976284
申请日：2011-12-30
申请人： Kevin M. McCauley , Steven Luo
发明人： Kevin M. McCauley , Steven Luo
CPC分类号： C08F136/06 , C08F36/04 , Y10S526/902 , C08F4/7098
摘要： A process for preparing a polydiene, the process comprising the step of polymerizing conjugated diene monomer with a nickel-based catalyst system, where said step of polymerizing takes place within a polymerization mixture that includes less than 20% by weight of organic solvent based on the total weight of the polymerization mixture, where the temperature of the polymerization mixture is maintained below 34° C. during said step of polymerizing, and where the conversion of the conjugated diene monomer is maintained below 30%.
摘要翻译： 一种制备聚二烯的方法，该方法包括将共轭二烯单体与镍基催化剂体系聚合的步骤，其中所述聚合步骤在聚合混合物内进行，所述聚合混合物包含基于 聚合混合物的总重量，其中聚合混合物的温度在聚合步骤期间保持在34℃以下，共轭二烯单体的转化率保持在30％以下。
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