公开(公告)号：US20120103900A1

公开(公告)日：2012-05-03

申请号：US13284174

申请日：2011-10-28

申请人： Ramesh R. Bhave ,  Melanie M. DeBusk ,  Guillermo D. DelCul ,  Laetitia H. Delmau ,  Chaitanya K. Narula

发明人： Ramesh R. Bhave ,  Melanie M. DeBusk ,  Guillermo D. DelCul ,  Laetitia H. Delmau ,  Chaitanya K. Narula

IPC分类号： B01D17/00

CPC分类号： G21F9/125

摘要： A system and method for the extraction of americium from radioactive waste solutions. The method includes the transfer of highly oxidized americium from an acidic aqueous feed solution through an immobilized liquid membrane to an organic receiving solvent, for example tributyl phosphate. The immobilized liquid membrane includes porous support and separating layers loaded with tributyl phosphate. The extracted solution is subsequently stripped of americium and recycled at the immobilized liquid membrane as neat tributyl phosphate for the continuous extraction of americium. The sequestered americium can be used as a nuclear fuel, a nuclear fuel component or a radiation source, and the remaining constituent elements in the aqueous feed solution can be stored in glassified waste forms substantially free of americium.

摘要翻译： 一种从放射性废物溶液中提取。的系统和方法。 该方法包括将高度氧化的ium从酸性含水原料溶液通过固定的液膜转移到有机接收溶剂，例如磷酸三丁酯。 固定液膜包括多孔载体和负载磷酸三丁酯的分离层。 随后将提取的溶液从subsequently subsequently中剥离，并在固定化的液膜上循环使用，作为纯磷酸三丁酯，用于连续提取。。。 隔离ium可用作核燃料，核燃料组分或辐射源，并且进料水溶液中的其余构成元素可以以基本上不含amer的玻璃化废物形式储存。

公开(公告)号：US08999168B2

公开(公告)日：2015-04-07

申请号：US13284174

申请日：2011-10-28

申请人： Ramesh R. Bhave ,  Melanie M. DeBusk ,  Guillermo D. DelCul ,  Laetitia H. Delmau ,  Chaitanya K. Narula

发明人： Ramesh R. Bhave ,  Melanie M. DeBusk ,  Guillermo D. DelCul ,  Laetitia H. Delmau ,  Chaitanya K. Narula

IPC分类号： B01D39/00 ,  B01D39/14 ,  B01D63/00 ,  G21F9/12

CPC分类号： G21F9/125

摘要： A system and method for the extraction of americium from radioactive waste solutions. The method includes the transfer of highly oxidized americium from an acidic aqueous feed solution through an immobilized liquid membrane to an organic receiving solvent, for example tributyl phosphate. The immobilized liquid membrane includes porous support and separating layers loaded with tributyl phosphate. The extracted solution is subsequently stripped of americium and recycled at the immobilized liquid membrane as neat tributyl phosphate for the continuous extraction of americium. The sequestered americium can be used as a nuclear fuel, a nuclear fuel component or a radiation source, and the remaining constituent elements in the aqueous feed solution can be stored in glassified waste forms substantially free of americium.

摘要翻译： 一种从放射性废物溶液中提取。的系统和方法。 该方法包括将高度氧化的ium从酸性含水原料溶液通过固定的液膜转移到有机接收溶剂，例如磷酸三丁酯。 固定液膜包括多孔载体和负载磷酸三丁酯的分离层。 随后将提取的溶液从subsequently subsequently中剥离，并在固定化的液膜上循环使用，作为纯磷酸三丁酯，用于连续提取。。。 隔离ium可用作核燃料，核燃料组分或辐射源，并且进料水溶液中的其余构成元素可以以基本上不含amer的玻璃化废物形式储存。

公开(公告)号：US08158088B2

公开(公告)日：2012-04-17

申请号：US12268189

申请日：2008-11-10

申请人： Dean R. Peterman ,  David H. Meikrantz ,  Jack D. Law ,  Catherine L. Riddle ,  Terry A. Todd ,  Mitchell R. Greenhalgh ,  Richard D. Tillotson ,  Richard A. Bartsch ,  Bruce A. Moyer ,  Laetitia H. Delmau ,  Peter V. Bonnesen

发明人： Dean R. Peterman ,  David H. Meikrantz ,  Jack D. Law ,  Catherine L. Riddle ,  Terry A. Todd ,  Mitchell R. Greenhalgh ,  Richard D. Tillotson ,  Richard A. Bartsch ,  Bruce A. Moyer ,  Laetitia H. Delmau ,  Peter V. Bonnesen

IPC分类号： B01D11/00

CPC分类号： C07D323/00 ,  C07C43/23

摘要： A mixed extractant solvent that includes at least one dialkyloxycalix[4]arenebenzocrown-6 compound, 4′,4′,(5′)-di-(t-butyldicyclohexano)-18-crown-6, at least one modifier, and, optionally, a diluent. The dialkyloxycalix[4]arenebenzocrown-6 compound is 1,3-alternate-25,27-di(octyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(decyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(dodecyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(2-ethylhexyl-1-oxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(3,7-dimethyloctyl-1-oxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(4-butyloctyl-1-oxy)calix[4]arenebenzocrown-6, or combinations thereof. The modifier is a primary alcohol. A method of separating cesium and strontium from an aqueous feed is also disclosed, as are dialkyloxycalix[4]arenebenzocrown-6 compounds and an alcohol modifier.

摘要翻译： 包含至少一种二烷氧基钙[4]芳基苯并呋喃-6化合物，4'，4'，（5'） - 二 - （叔丁基二环己基）-18-冠-6的混合萃取剂溶剂，至少一种改性剂， 任选地，稀释剂。 二烷氧基钙[4]芳烃基苯并呋喃-6化合物是1,3-交替的25,27-二（辛氧基）杯[4]芳烃基苯并噻唑-6，1,3-交替的25,27-二（癸氧基）杯[4] 芳族苯并茂-6，1,3-交替的25,27-二（十二烷氧基）杯[4]芳烃基苯并茂-6，1,3-交替的25,27-二（2-乙基己基-1-氧）杯[4] （3,7-二甲基辛基-1-氧基）杯[4]芳烃基苯并呋喃-6,1,3交替的25,27-二（4-丁基辛基 - 1-氧基）杯[4]芳烃基苯并呋喃-6或其组合。 改性剂是伯醇。 还公开了一种从含水原料中分离铯和锶的方法，二烷基氧基钙[4]芳烃基苯并呋喃-6化合物和醇改性剂也是如此。

公开(公告)号：US20100116749A1

公开(公告)日：2010-05-13

申请号：US12268189

申请日：2008-11-10

申请人： DEAN R. PETERMAN ,  DAVID H. MEIKRANTZ ,  JACK D. LAW ,  CATHERINE L. RIDDLE ,  TERRY A. TODD ,  MITCHELL R. GREENHALGH ,  RICHARD D. TILLOTSON ,  RICHARD A. BARTSCH ,  BRUCE A. MOYER ,  LAETITIA H. DELMAU ,  PETER V. BONNESEN

发明人： DEAN R. PETERMAN ,  DAVID H. MEIKRANTZ ,  JACK D. LAW ,  CATHERINE L. RIDDLE ,  TERRY A. TODD ,  MITCHELL R. GREENHALGH ,  RICHARD D. TILLOTSON ,  RICHARD A. BARTSCH ,  BRUCE A. MOYER ,  LAETITIA H. DELMAU ,  PETER V. BONNESEN

IPC分类号： C07D323/00 ,  C09K3/00 ,  B01D17/00 ,  C07C43/205

CPC分类号： C07D323/00 ,  C07C43/23

摘要： A mixed extractant solvent that includes at least one dialkyloxycalix[4]arenebenzocrown-6 compound, 4′,4′,(5′)-di-(t-butyldicyclohexano)-18-crown-6, at least one modifier, and, optionally, a diluent. The dialkyloxycalix[4]arenebenzocrown-6 compound is 1,3-alternate-25,27-di(octyloxy)calix[4] arenebenzocrown-6, 1,3-alternate-25,27-di(decyloxy)calix[4]arene-benzocrown-6, 1,3-alternate-25,27-di(dodecyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(2-ethylhexyl-1-oxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(3,7-dimethyloctyl-1-oxy)calix[4] arenebenzocrown-6, 1,3-alternate-25,27-di(4-butyloctyl-1-oxy)calix[4]arenebenzocrown-6, or combinations thereof. The modifier is a primary alcohol. A method of separating cesium and strontium from an aqueous feed is also disclosed, as are dialkyloxycalix[4]arenebenzocrown-6 compounds and an alcohol modifier.

摘要翻译： 包含至少一种二烷氧基钙[4]芳基苯并呋喃-6化合物，4'，4'，（5'） - 二 - （叔丁基二环己基）-18-冠-6，至少一种改性剂的混合萃取剂溶剂， 任选地，稀释剂。 二烷氧基钙[4]芳烃基苯并呋喃-6化合物是1,3-交替的25,27-二（辛氧基）杯[4]芳烃基苯并噻唑-6，1,3-交替的25,27-二（癸氧基）杯[4] 芳基 - 苯并环己基-6,1,3-交替的25,27-二（十二烷氧基）杯[4]芳烃基苯并卡那-6，1,3-交替的25,27-二（2-乙基己基-1-氧）杯[ 4]芳基苯并卡隆-6,1,3-交替的25,27-二（3,7-二甲基辛基-1-氧基）杯[4]芳烃基苯并卡那-6，1,3-交替的25,27-二（4- 丁基辛-1-氧）杯[4]芳烃基苯甲酰基-6或其组合。 改性剂是伯醇。 还公开了一种从含水原料中分离铯和锶的方法，二烷基氧基钙[4]芳烃基苯并呋喃-6化合物和醇改性剂也是如此。