摘要:
A method for converting an alcohol to a hydrocarbon, the method comprising contacting said alcohol with a metal-loaded zeolite catalyst at a temperature of at least 100° C. and up to 550° C., wherein said alcohol can be produced by a fermentation process, said metal is a positively-charged metal ion, and said metal-loaded zeolite catalyst is catalytically active for converting said alcohol to said hydrocarbon.
摘要:
Aluminum oxynitride is prepared by the pyrolysis of an organosiloxydihaloalane such as trimethylsiloxydichloroalane in the presence of a nitrogen-containing atmosphere. The organosiloxydihaloalane may conveniently be prepared by reacting together an aluminum halide and at least one disiloxane.
摘要:
A catalyst composition includes a heterobimetallic zeolite characterized by a chabazite structure loaded with copper ions and at least one trivalent metal ion other than Al3+. The catalyst composition decreases NOx emissions in diesel exhaust and is suitable for operation in a catalytic converter.
摘要:
A system and method for the extraction of americium from radioactive waste solutions. The method includes the transfer of highly oxidized americium from an acidic aqueous feed solution through an immobilized liquid membrane to an organic receiving solvent, for example tributyl phosphate. The immobilized liquid membrane includes porous support and separating layers loaded with tributyl phosphate. The extracted solution is subsequently stripped of americium and recycled at the immobilized liquid membrane as neat tributyl phosphate for the continuous extraction of americium. The sequestered americium can be used as a nuclear fuel, a nuclear fuel component or a radiation source, and the remaining constituent elements in the aqueous feed solution can be stored in glassified waste forms substantially free of americium.
摘要:
This invention is directed to a method for making metal-aluminum-oxide materials according to sol-gel techniques from particularly defined heterobimetallic alkoxides comprising bis[bis(2-propanolato)aluminum)-tetrakis(.mu.-(2-propanolato)]alkaline-earths and, optionally, tris [(bis(2-propanolato)aluminum)hexakis(.mu.-(2-propanolato))]-lanthanides, and the materials so made. The materials may be in varied forms like sols, gels, xerogels, and calcined materials.
摘要:
A titanium tetrahalide is reacted with a disilazane to prepare a titanium containing organometallic precursor, which is thereafter mixed with a refractory material powder and pyrolyzed to form a titanium nitride-containing refractory material composite containing crystalline titanium nitride.
摘要:
A catalyst having high temperature (800.degree.-1050.degree. C.) stability and improved three-way automotive exhaust gas catalyst activity at high temperatures, comprising an outer catalytic coating of binary La-Pd oxide (La.sub.2 Pd.sub.2 O.sub.5 or La.sub.4 PdO.sub.7) calcined and supported on a catalyst-supporting substrate, the oxide being present in an amount to provide 15-150 g of Pd per cubic foot of the substrateA method of making binary La-Pd oxides useful as an automotive exhaust catalyst operative at high temperatures, comprising heating in an oxidizing atmosphere a mixture containing La compounds and Pd compounds in a La:Pd ratio of 1:1 or 4:1, the heating being staged to first heat slowly from about 50.degree. C. to start decomposition of the compounds and thereafter retaining the residue at an elevated temperature to stimulate growth of crystalline binary La-Pd oxides and to calcine the crystalline oxides.A method of making an automotive catalyst by suspending binary La-Pd oxides in a sol (preferably alumina sol) and depositing and fixing such sol suspension on a substrate coated with conventional washcoats.
摘要:
The disclosure is directed to polymeric B-aminoborazene compounds suitable for pyrolytic conversion to boron nitride. The B-aminoborazene compounds are preferably mixed with an organic solvent and a cross-linking agent to form a polymeric gel. The polymeric gel is then pyrolized to form boron nitride. The polymeric gel is useful to coat various forms and materials.
摘要:
A system and method for the extraction of americium from radioactive waste solutions. The method includes the transfer of highly oxidized americium from an acidic aqueous feed solution through an immobilized liquid membrane to an organic receiving solvent, for example tributyl phosphate. The immobilized liquid membrane includes porous support and separating layers loaded with tributyl phosphate. The extracted solution is subsequently stripped of americium and recycled at the immobilized liquid membrane as neat tributyl phosphate for the continuous extraction of americium. The sequestered americium can be used as a nuclear fuel, a nuclear fuel component or a radiation source, and the remaining constituent elements in the aqueous feed solution can be stored in glassified waste forms substantially free of americium.
摘要:
A catalyst comprising a zeolite loaded with copper ions and at least one trivalent metal ion other than Al+3, wherein the catalyst decreases NOx emissions in diesel exhaust. The trivalent metal ions are selected from, for example, trivalent transition metal ions, trivalent main group metal ions, and/or trivalent lanthanide metal ions. In particular embodiments, the catalysts are selected from Cu—Fe-ZSM5, Cu—La-ZSM-5, Fe—Cu—La-ZSM5, Cu—Sc-ZSM-5, and Cu—In-ZSM5. The catalysts are placed on refractory support materials and incorporated into catalytic converters.