SUPPORTED LIQUID INORGANIC MEMBRANES FOR NUCLEAR WASTE SEPARATION
    4.
    发明申请
    SUPPORTED LIQUID INORGANIC MEMBRANES FOR NUCLEAR WASTE SEPARATION 有权
    支持液态无机膜用于核废料分离

    公开(公告)号:US20120103900A1

    公开(公告)日:2012-05-03

    申请号:US13284174

    申请日:2011-10-28

    IPC分类号: B01D17/00

    CPC分类号: G21F9/125

    摘要: A system and method for the extraction of americium from radioactive waste solutions. The method includes the transfer of highly oxidized americium from an acidic aqueous feed solution through an immobilized liquid membrane to an organic receiving solvent, for example tributyl phosphate. The immobilized liquid membrane includes porous support and separating layers loaded with tributyl phosphate. The extracted solution is subsequently stripped of americium and recycled at the immobilized liquid membrane as neat tributyl phosphate for the continuous extraction of americium. The sequestered americium can be used as a nuclear fuel, a nuclear fuel component or a radiation source, and the remaining constituent elements in the aqueous feed solution can be stored in glassified waste forms substantially free of americium.

    摘要翻译: 一种从放射性废物溶液中提取。的系统和方法。 该方法包括将高度氧化的ium从酸性含水原料溶液通过固定的液膜转移到有机接收溶剂,例如磷酸三丁酯。 固定液膜包括多孔载体和负载磷酸三丁酯的分离层。 随后将提取的溶液从subsequently subsequently中剥离,并在固定化的液膜上循环使用,作为纯磷酸三丁酯,用于连续提取。。。 隔离ium可用作核燃料,核燃料组分或辐射源,并且进料水溶液中的其余构成元素可以以基本上不含amer的玻璃化废物形式储存。

    Single phase metal-alumina sol-gel process and material
    5.
    发明授权
    Single phase metal-alumina sol-gel process and material 失效
    单相金属 - 氧化铝溶胶 - 凝胶工艺和材料

    公开(公告)号:US5403807A

    公开(公告)日:1995-04-04

    申请号:US986412

    申请日:1993-02-08

    摘要: This invention is directed to a method for making metal-aluminum-oxide materials according to sol-gel techniques from particularly defined heterobimetallic alkoxides comprising bis[bis(2-propanolato)aluminum)-tetrakis(.mu.-(2-propanolato)]alkaline-earths and, optionally, tris [(bis(2-propanolato)aluminum)hexakis(.mu.-(2-propanolato))]-lanthanides, and the materials so made. The materials may be in varied forms like sols, gels, xerogels, and calcined materials.

    摘要翻译: 本发明涉及根据溶胶 - 凝胶技术制备金属 - 氧化铝材料的方法,其特别定义的异双金属醇盐包括双[双(2-(2-丙醇))铝) - 四((2-丙醇)) - 地球和任选的三[(双(2-丙醇)铝)六((2-丙醇))] - 镧系元素和如此制得的材料,材料可以是各种形式,如溶胶,凝胶,干凝胶, 和煅烧材料。

    Binary LA-PA oxide catalyst and method of making the catalyst
    7.
    发明授权
    Binary LA-PA oxide catalyst and method of making the catalyst 失效
    二元LA-PA氧化物催化剂及其制备方法

    公开(公告)号:US5234881A

    公开(公告)日:1993-08-10

    申请号:US894703

    申请日:1992-06-05

    CPC分类号: B01J23/63 B01J37/024

    摘要: A catalyst having high temperature (800.degree.-1050.degree. C.) stability and improved three-way automotive exhaust gas catalyst activity at high temperatures, comprising an outer catalytic coating of binary La-Pd oxide (La.sub.2 Pd.sub.2 O.sub.5 or La.sub.4 PdO.sub.7) calcined and supported on a catalyst-supporting substrate, the oxide being present in an amount to provide 15-150 g of Pd per cubic foot of the substrateA method of making binary La-Pd oxides useful as an automotive exhaust catalyst operative at high temperatures, comprising heating in an oxidizing atmosphere a mixture containing La compounds and Pd compounds in a La:Pd ratio of 1:1 or 4:1, the heating being staged to first heat slowly from about 50.degree. C. to start decomposition of the compounds and thereafter retaining the residue at an elevated temperature to stimulate growth of crystalline binary La-Pd oxides and to calcine the crystalline oxides.A method of making an automotive catalyst by suspending binary La-Pd oxides in a sol (preferably alumina sol) and depositing and fixing such sol suspension on a substrate coated with conventional washcoats.

    摘要翻译: 在高温下具有高温(800-105℃)稳定性和改进的三元汽车尾气催化剂活性的催化剂,其包含在二氧化碳上煅烧和负载的二元La-Pd氧化物(La2Pd2O5或La4PdO7)的外部催化涂层 催化剂负载底物,氧化物的存在量为每立方英尺底物提供15-150g Pd。制备用作在高温下操作的汽车尾气催化剂的二元La-Pd氧化物的方法,包括在 氧化气氛中含有La化合物和Pd化合物的La:Pd比为1:1或4:1的混合物,分级加热,首先从约50℃缓慢加热,开始分解化合物,然后保留残余物 在升高的温度下刺激结晶二元La-Pd氧化物的生长并煅烧结晶氧化物。 通过将二元La-Pd氧化物悬浮在溶胶(优选氧化铝溶胶)中并将这种溶胶悬浮液沉积并固定在涂有常规洗面涂层的基材上来制备汽车催化剂的方法。

    Supported liquid inorganic membranes for nuclear waste separation
    9.
    发明授权
    Supported liquid inorganic membranes for nuclear waste separation 有权
    用于核废料分离的支撑液体无机膜

    公开(公告)号:US08999168B2

    公开(公告)日:2015-04-07

    申请号:US13284174

    申请日:2011-10-28

    CPC分类号: G21F9/125

    摘要: A system and method for the extraction of americium from radioactive waste solutions. The method includes the transfer of highly oxidized americium from an acidic aqueous feed solution through an immobilized liquid membrane to an organic receiving solvent, for example tributyl phosphate. The immobilized liquid membrane includes porous support and separating layers loaded with tributyl phosphate. The extracted solution is subsequently stripped of americium and recycled at the immobilized liquid membrane as neat tributyl phosphate for the continuous extraction of americium. The sequestered americium can be used as a nuclear fuel, a nuclear fuel component or a radiation source, and the remaining constituent elements in the aqueous feed solution can be stored in glassified waste forms substantially free of americium.

    摘要翻译: 一种从放射性废物溶液中提取。的系统和方法。 该方法包括将高度氧化的ium从酸性含水原料溶液通过固定的液膜转移到有机接收溶剂,例如磷酸三丁酯。 固定液膜包括多孔载体和负载磷酸三丁酯的分离层。 随后将提取的溶液从subsequently subsequently中剥离,并在固定化的液膜上循环使用,作为纯磷酸三丁酯,用于连续提取。。。 隔离ium可用作核燃料,核燃料组分或辐射源,并且进料水溶液中的其余构成元素可以以基本上不含amer的玻璃化废物形式储存。