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    N-sulphenylated 2-amino-4-chloro-thiazole-sulphonamides, their use, process for their preparation, and the intermediates 2,4-dichlorothiazole-sulphonyl chloride and 2-amino-4-chloro-thiazole-sulphonamides
    5.
    发明授权
    N-sulphenylated 2-amino-4-chloro-thiazole-sulphonamides, their use, process for their preparation, and the intermediates 2,4-dichlorothiazole-sulphonyl chloride and 2-amino-4-chloro-thiazole-sulphonamides 失效
    N-磺基化的2-氨基-4-氯 - 噻唑磺酰胺，它们的用途及其制备方法，和中间体2,4-二氯噻唑 - 磺酰氯和2-氨基-4-氯 - 噻唑 - 磺酰胺

    公开(公告)号：US4906650A

    公开(公告)日：1990-03-06

    申请号：US308180

    申请日：1989-02-08

    申请人： Gunther Beck ,  Bernd Baasner ,  Michael Schwamborn ,  Wilhelm Brandes

    发明人： Gunther Beck ,  Bernd Baasner ,  Michael Schwamborn ,  Wilhelm Brandes

    IPC分类号： C07D277/20 ,  A01N47/04 ,  C07D277/36 ,  C07D277/42 ,  C07D277/52 ,  C07D277/54 ,  C07D417/12

    CPC分类号： C07D417/12 ,  A01N47/04 ,  C07D277/36 ,  C07D277/42 ,  C07D277/52

    摘要： The fungicidally active N-sulphenylated 2-amino-4-chloro-thiazole-sulphonamides of the formula ##STR1## wherein R.sup.1 and R.sup.2 independently of one another denote hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl, aryl, aralkyl or an aromatic or a non-aromatic heterocyclic radical andR.sup.3 and R.sup.4 independently of one another stand for hydrogen, alkyl, cycloalkyl, aryl or aralkyl or for the dichlorohalogenomethyl-sulphenyl radical --S--CCl.sub.2 X, in which X denotes fluorine, chlorine or bromine, and where furthermore one of the pairs of substituents R.sup.1 and R.sup.3 or R.sup.2 andR.sup.4 together with the nitrogen atom which they substitute can denote morpholino or thiomorpholino, with at least one of the radicals R.sup.3 and R.sup.4 standing for the radical --S--CCl.sub.2 X,can be prepared in a process in which, in a first step, 2,4-dichloro-thiazole is reacted with chlorosulphonic acid to give 2,4-dichloro-thiazole-sulphonyl chloride, in which, in a second step, the 2,4-dichloro-thiazole-sulphonyl chloride is reacted with primary amines or with a primary and a secondary amine to give 2-amino-4-chloro-thiazole-sulphonamides, and in which, in a third step, the sulphonamides mentioned are reacted with dichlorohalogenomethylsulphenyl chlorides to give the substances of the formula (I).

    摘要翻译： 式（I）的杀真菌活性N-磺基化2-氨基-4-氯 - 噻唑 - 磺酰胺其中R 1和R 2彼此独立地表示氢，烷基，烯基，炔基，环烷基，芳基，芳烷基或 芳族或非芳香族杂环基，R 3和R 4彼此独立地代表氢，烷基，环烷基，芳基或芳烷基或二氯卤代甲基 - 磺酰基-S-CCl 2 X，其中X表示氟，氯或溴，以及 此外，取代基R 1和R 3或R 2和R 4中的一个与它们所取代的氮原子一起可以表示吗啉代或硫代吗啉基，其中R3和R4中至少一个代表基团-S-CCl 2，可以是 其中在第一步中将2,4-二氯 - 噻唑与氯磺酸反应，得到2,4-二氯 - 噻唑 - 磺酰氯，其中在第二步中，2,4-二氯 - 二氯 - 噻唑 - 磺酰氯与伯胺反应 胺或与伯胺和仲胺反应，得到2-氨基-4-氯 - 噻唑 - 磺酰胺，其中在第三步中，所述磺酰胺与二氯卤代甲基亚磺酰氯反应，得到式（I）的物质， 。

    Sulphonylaminocarbonyltriazolinones
    10.
    发明授权
    Sulphonylaminocarbonyltriazolinones 失效
    磺酰氨基羰基三唑啉酮

    公开(公告)号：US5532378A

    公开(公告)日：1996-07-02

    申请号：US356933

    申请日：1994-12-15

    申请人： Werner Daum ,  Klaus-Helmut Muller ,  Michael Schwamborn ,  Peter Babczinski ,  Hans-Joachim Santel ,  Robert R. Schmidt ,  Harry Strang

    发明人： Werner Daum ,  Klaus-Helmut Muller ,  Michael Schwamborn ,  Peter Babczinski ,  Hans-Joachim Santel ,  Robert R. Schmidt ,  Harry Strang

    IPC分类号： A01N47/38 ,  A01N51/00 ,  C07D249/12 ,  C07D249/14 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D471/04 ,  C07D487/04

    CPC分类号： C07D401/12 ,  A01N47/38 ,  A01N51/00 ,  C07D249/12 ,  C07D249/14 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D471/04 ,  C07D487/04

    摘要： Herbicidal sulphonylaminocarbonyltriazolinones of the formula ##STR1## in which R.sup.1 represents hydrogen, hydroxyl or amino, or represents an optionally substituted radical from the series comprising alkyl, alkenyl, alkinyl, cycloalkyl aralkyl, aryl, alkoxy, alkenyloxy, alkylamino and dialkylamino,R.sup.2 represents hydrogen, hydroxyl, mercapto or amino, or represents an optionally substituted radical from the series comprising alkyl, cycloalkyl, cycloalkenyl, aralkyl, aryl, alkoxy, alkylamino and dialkylamino, and R.sup.3 represents an optionally substituted radical from the series comprising alkyl, aralkyl, aryl and heteroaryl,and salts thereof. Intermediates of the formula ##STR2## in which A.sup.1 represents in each case optionally substituted alkyl , alkenyl, cycloalkyl, alkoxy or dialkylamino andA.sup.2 represents hydrogen, or represents in each case optionally substituted alkyl, cycloalkyl, aralkyl, aryl or alkoxy,provided that both A.sup.1 and A.sup.2 do not simultaneously represent alkyl, are also new.

    摘要翻译： 式（I）的除草磺酰基氨基羰基三唑啉酮，其中R 1表示氢，羟基或氨基，或代表包含烷基，烯基，炔基，环烷基芳烷基，芳基，烷氧基，烯氧基，烷基氨基和二烷基氨基的任选取代的基团， R 2代表氢，羟基，巯基或氨基，或代表包含烷基，环烷基，环烯基，芳烷基，芳基，烷氧基，烷基氨基和二烷基氨基的系列中任意取代的基团，R 3表示任选被取代的基团， ，芳基和杂芳基，及其盐。 式（IIa）的中间体，其中A1表示在每种情况下为任选取代的烷基，烯基，环烷基，烷氧基或二烷基氨基，A 2表示氢，或在各种情况下表示任选取代的烷基，环烷基，芳烷基，芳基或烷氧基， 只要A1和A2不同时代表烷基，也是新的。