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公开(公告)号：US07319179B2
公开(公告)日：2008-01-15
申请号：US10909276
申请日：2004-07-30
申请人： José Manuel López Nieto , Pablo Botella Asunción , Maria Isabel Vazquez Navarro , Ana Dejoz García
发明人： José Manuel López Nieto , Pablo Botella Asunción , Maria Isabel Vazquez Navarro , Ana Dejoz García
CPC分类号： C07C51/215 , B01J23/002 , B01J23/20 , B01J23/28 , B01J23/31 , B01J23/8877 , B01J23/8885 , B01J27/0576 , B01J35/002 , B01J37/10 , B01J2523/00 , C07C5/48 , C07C51/25 , C07C253/24 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/02 , C07C2523/04 , C07C2523/10 , C07C2523/14 , C07C2523/18 , C07C2523/20 , C07C2523/22 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/31 , C07C2523/32 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/885 , C07C2523/887 , C07C2527/057 , Y02P20/52 , C07C11/04 , C07C53/08 , B01J2523/17 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , C07C255/03
摘要： The invention relates to a method for the oxidative dehydrogenation of ethane. The inventive method is characterized in that it consists of bringing the ethane into contact with the catalyst containing Mo, Te, V, Nb and at least a fifth element A which is selected from Cu, Ta, Sn, Se, W, Ti, Fe, Co, Ni, Cr, Zr, Sb, Bi, an alkali metal, an alkaline-earth metal and a rare earth, in which at least Mo, Te, V and Nb are present in the form of at least one oxide, said catalyst presenting, in calcined form, an X-ray diffractogram with more than ten intense diffraction lines, typically, the most intense lines corresponding to diffraction angles 2Θ of 7.7°±0.4, 8.9°±0.4, 22.1°+0.4, 26.6°±0.4, 26.9°±0.4, 27.1°±0.4, 28.1°±0.4, 31.2°±0.4, 35.0°±0.4 and 45.06°±0.
摘要翻译： 本发明涉及乙烷的氧化脱氢方法。 本发明的方法的特征在于使乙烷与含有Mo，Te，V，Nb的催化剂和至少一种选自Cu，Ta，Sn，Se，W，Ti，Fe ，Co，Ni，Cr，Zr，Sb，Bi，碱金属，碱土金属和稀土，其中至少Mo，Te，V和Nb以至少一种氧化物的形式存在，所述 催化剂以煅烧形式呈现具有超过十条强衍射线的X射线衍射图，典型地，对应于衍射角2θ的最强烈线，其中7.7°±0.4°，8.9°±0.4°，22.1°±0.4°，26.6°± 0.4,26.9°±0.4,27.1°±0.4,28.1°±0.4,31.2°±0.4,35.0°±0.4和45.06°±0。
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