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公开(公告)号：US07507863B2
公开(公告)日：2009-03-24
申请号：US11614428
申请日：2006-12-21
IPC分类号： C07C209/16 , B01J21/00
CPC分类号： C07C209/16 , C07C211/07
摘要： The present invention relates to a process for producing an aliphatic amine, including the step of contacting a linear or branched, or cyclic aliphatic alcohol with ammonia and hydrogen in the presence of a catalyst containing (A) nickel, copper and zirconium components, and (B) at least one metal component selected from the group consisting of elements belonging to Group 1 of the Periodic Table. According to the process of the present invention, an aliphatic primary amine can be produced from the aliphatic alcohol with a good yield and a high productivity.
摘要翻译： 本发明涉及一种生产脂肪族胺的方法，包括在含有（A）镍，铜和锆组分的催化剂和（A）镍，铜和锆组分的催化剂存在下，使直链或支链或环状脂族醇与氨和氢接触的步骤和（ B）选自元素周期表第1族元素中的至少一种金属成分。 根据本发明的方法，脂肪族伯胺可以从脂肪醇以良好的收率和高生产率制备。
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公开(公告)号：US20070149817A1
公开(公告)日：2007-06-28
申请号：US11614404
申请日：2006-12-21
IPC分类号： C07C209/16
CPC分类号： C07C209/16 , C07C211/07
摘要： The present invention relates to a process for producing an aliphatic amine, including the step of contacting a linear or branched, or cyclic aliphatic alcohol with ammonia and hydrogen in the presence of a catalyst containing (A) nickel, copper and zirconium components, and (B) at least one metal component selected from the group consisting of elements belonging to Group 3 of the Periodic Table, elements belonging to Group 5 of the Periodic Table and platinum group elements. According to the process of the present invention, an aliphatic primary amine can be produced from an aliphatic alcohol with a high selectivity.
摘要翻译： 本发明涉及一种生产脂肪族胺的方法，包括在含有（A）镍，铜和锆组分的催化剂和（A）镍，铜和锆组分的催化剂存在下，使直链或支链或环状脂族醇与氨和氢接触的步骤和（ B）选自元素周期表第3族元素，元素周期表第5族元素和铂族元素中的至少一种金属成分。 根据本发明的方法，脂肪族伯胺可以以高选择性由脂族醇生产。
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公开(公告)号：US20110207964A1
公开(公告)日：2011-08-25
申请号：US12672327
申请日：2008-08-07
IPC分类号： C07C291/04 , C07C209/50
CPC分类号： C07C209/50 , C07C209/02 , C07C211/08 , C07C291/04
摘要： The present invention relates to a process for producing a tertiary amine in the presence of a catalyst containing copper and at least one element selected from the group consisting of elements belonging to Groups 2, 3, 7 and 12 of the Periodic Table (long form of the periodic table), said process including the steps of (a) reducing an amide compound in a hydrogen atmosphere; and (b) introducing a dialkyl amine containing a linear or branched alkyl group having 1 to 6 carbon atoms into a reaction product obtained in the step (a), and treating the reaction product with the dialkyl amine. The present invention provides a process for producing high-purity aliphatic tertiary amines containing a less amount of by-products by reducing aliphatic acid amides under moderate conditions using a chromium-free catalyst, as well as a process for producing amine derivatives such as amine oxide by using the aliphatic tertiary amines, with a good productivity in an economical manner.
摘要翻译： 本发明涉及在含有铜的催化剂和选自元素周期表第2,3,7和12族元素中的至少一种元素的存在下制备叔胺的方法（长形式 所述方法包括以下步骤：（a）在氢气氛中还原酰胺化合物; 和（b）将含有具有1至6个碳原子的直链或支链烷基的二烷基胺引入步骤（a）中获得的反应产物中，并用二烷基胺处理反应产物。 本发明提供了一种通过使用无铬催化剂在中等条件下还原脂肪酸酰胺以及生产胺衍生物如氧化胺的方法来生产含有少量副产物的高纯度脂族叔胺的方法 通过使用脂肪族叔胺，以经济的方式具有良好的生产率。
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公开(公告)号：US20100274056A1
公开(公告)日：2010-10-28
申请号：US12159526
申请日：2006-12-21
IPC分类号： C07C209/14 , B01J23/46 , B01J23/30 , B01J23/10
CPC分类号： B01J23/462 , B01J23/6527 , B01J23/892 , B01J29/068 , B01J37/033 , B01J37/035 , C07C209/16
摘要： The present invention relates to a process for producing an aliphatic amine, comprising the step of contacting a linear or branched, or cyclic aliphatic alcohol having 6 to 22 carbon atoms with ammonia and hydrogen in the presence of a catalyst formed by supporting at least (A) a ruthenium component produced by hydrolysis of a ruthenium compound on a carrier, or by further supporting, in addition to the component (A), a specific second metal component or a specific third metal component on the carrier. According to the process of the present invention, an aliphatic primary amine can be produced from an aliphatic alcohol with a high catalytic activity and a high selectivity.
摘要翻译： 本发明涉及脂肪族胺的制造方法，其特征在于，在使至少含有（A）成分的催化剂存在下，使具有6〜22个碳原子的直链或支链或环状脂肪醇与氨和氢接触的工序 ）通过在载体上水解钌化合物而制备的钌组分，或者除了组分（A）之外还可以在载体上具有特定的第二金属组分或特定的第三金属组分。 根据本发明的方法，脂肪族伯胺可以由具有高催化活性和高选择性的脂族醇生产。
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公开(公告)号：US07514585B2
公开(公告)日：2009-04-07
申请号：US11614404
申请日：2006-12-21
IPC分类号： C07C209/16 , B01J21/00
CPC分类号： C07C209/16 , C07C211/07
摘要： The present invention relates to a process for producing an aliphatic amine, including the step of contacting a linear or branched, or cyclic aliphatic alcohol with ammonia and hydrogen in the presence of a catalyst containing (A) nickel, copper and zirconium components, and (B) at least one metal component selected from the group consisting of elements belonging to Group 3 of the Periodic Table, elements belonging to Group 5 of the Periodic Table and platinum group elements. According to the process of the present invention, an aliphatic primary amine can be produced from an aliphatic alcohol with a high selectivity.
摘要翻译： 本发明涉及一种生产脂肪族胺的方法，包括在含有（A）镍，铜和锆组分的催化剂和（A）镍，铜和锆组分的催化剂存在下，使直链或支链或环状脂族醇与氨和氢接触的步骤和（ B）选自元素周期表第3族元素，元素周期表第5族元素和铂族元素中的至少一种金属成分。 根据本发明的方法，脂肪族伯胺可以以高选择性由脂族醇生产。
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公开(公告)号：US20070149818A1
公开(公告)日：2007-06-28
申请号：US11614428
申请日：2006-12-21
IPC分类号： C07C209/16
CPC分类号： C07C209/16 , C07C211/07
摘要： The present invention relates to a process for producing an aliphatic amine, including the step of contacting a linear or branched, or cyclic aliphatic alcohol with ammonia and hydrogen in the presence of a catalyst containing (A) nickel, copper and zirconium components, and (B) at least one metal component selected from the group consisting of elements belonging to Group 1 of the Periodic Table. According to the process of the present invention, an aliphatic primary amine can be produced from the aliphatic alcohol with a good yield and a high productivity.
摘要翻译： 本发明涉及一种生产脂肪族胺的方法，包括在含有（A）镍，铜和锆组分的催化剂和（A）镍，铜和锆组分的催化剂存在下，使直链或支链或环状脂族醇与氨和氢接触的步骤和（ B）选自元素周期表第1族元素中的至少一种金属成分。 根据本发明的方法，脂肪族伯胺可以从脂肪醇以良好的收率和高生产率制备。
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公开(公告)号：US08278488B2
公开(公告)日：2012-10-02
申请号：US12672327
申请日：2008-08-07
IPC分类号： C07C209/00 , C07C291/04
CPC分类号： C07C209/50 , C07C209/02 , C07C211/08 , C07C291/04
摘要： The present invention relates to a process for producing a tertiary amine in the presence of a catalyst containing copper and at least one element selected from the group consisting of elements belonging to Groups 2, 3, 7 and 12 of the Periodic Table (long form of the periodic table), said process including the steps of (a) reducing an amide compound in a hydrogen atmosphere; and (b) introducing a dialkyl amine containing a linear or branched alkyl group having 1 to 6 carbon atoms into a reaction product obtained in the step (a), and treating the reaction product with the dialkyl amine. The present invention provides a process for producing high-purity aliphatic tertiary amines containing a less amount of by-products by reducing aliphatic acid amides under moderate conditions using a chromium-free catalyst, as well as a process for producing amine derivatives such as amine oxide by using the aliphatic tertiary amines, with a good productivity in an economical manner.
摘要翻译： 本发明涉及在含有铜的催化剂和选自元素周期表第2,3,7和12族元素中的至少一种元素的存在下制备叔胺的方法（长形式 所述方法包括以下步骤：（a）在氢气氛中还原酰胺化合物; 和（b）将含有具有1至6个碳原子的直链或支链烷基的二烷基胺引入步骤（a）中获得的反应产物中，并用二烷基胺处理反应产物。 本发明提供了一种通过使用无铬催化剂在中等条件下还原脂肪酸酰胺以及生产胺衍生物如氧化胺的方法来生产含有少量副产物的高纯度脂族叔胺的方法 通过使用脂肪族叔胺，以经济的方式具有良好的生产率。
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公开(公告)号：US20050027141A1
公开(公告)日：2005-02-03
申请号：US10897008
申请日：2004-07-23
申请人： Tetsuaki Furushima , Masaharu Jono
发明人： Tetsuaki Furushima , Masaharu Jono
IPC分类号： C07C213/02 , C07C217/08 , C07C217/42 , C08G65/325 , C07
CPC分类号： C07C213/02 , C07C217/08 , C07C217/42
摘要： The present invention is a process for producing polyoxyalkylene triamine by bringing polyoxyalkylene triol having at its terminal a hydroxyl group into contact with ammonia and hydrogen in the presence of a catalyst comprising ruthenium metal at an amount of 0.5 to 20% by weight of the total of the catalyst, the ruthenium metal being carried on at least one carrier selected from alumina, silica, silica-alumina, titanium dioxide, and titanium dioxide-silica.
摘要翻译： 本发明是一种通过在其包含钌金属的催化剂存在下使其末端具有羟基的聚氧化烯三醇与氨和氢接触而制备聚氧化烯三胺的方法，其量为总重量的0.5〜20重量％ 催化剂，钌金属承载在选自氧化铝，二氧化硅，二氧化硅 - 氧化铝，二氧化钛和二氧化钛 - 二氧化硅中的至少一种载体上。
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公开(公告)号：US08247611B2
公开(公告)日：2012-08-21
申请号：US12159526
申请日：2006-12-21
IPC分类号： C07C209/14 , C07C209/16
CPC分类号： B01J23/462 , B01J23/6527 , B01J23/892 , B01J29/068 , B01J37/033 , B01J37/035 , C07C209/16
摘要： The present invention relates to a process for producing an aliphatic amine, comprising the step of contacting a linear or branched, or cyclic aliphatic alcohol having 6 to 22 carbon atoms with ammonia and hydrogen in the presence of a catalyst formed by supporting at least (A) a ruthenium component produced by hydrolysis of a ruthenium compound on a carrier, or by further supporting, in addition to the component (A), a specific second metal component or a specific third metal component on the carrier. According to the process of the present invention, an aliphatic primary amine can be produced from an aliphatic alcohol with a high catalytic activity and a high selectivity.
摘要翻译： 本发明涉及脂肪族胺的制造方法，其特征在于，在使至少含有（A）成分的催化剂存在下，使具有6〜22个碳原子的直链或支链或环状脂肪醇与氨和氢接触的工序 ）通过在载体上水解钌化合物而制备的钌组分，或者除了组分（A）之外还可以在载体上具有特定的第二金属组分或特定的第三金属组分。 根据本发明的方法，脂肪族伯胺可以由具有高催化活性和高选择性的脂族醇生产。
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公开(公告)号：US07754923B2
公开(公告)日：2010-07-13
申请号：US12224607
申请日：2007-03-08
IPC分类号： C07C209/78 , C07C291/04
CPC分类号： C07C209/50 , B01J23/78 , B01J29/072 , B01J29/076 , B01J29/76 , B01J29/78 , B01J37/031 , B01J2229/18 , C07C211/08
摘要： The present invention provides a process for producing high-purity aliphatic tertiary amines containing a less amount of by-products by subjecting aliphatic acid amides to hydrogenation reduction under moderate conditions, as well as a process for producing amine derivatives from the aliphatic tertiary amines, with a good productivity in an economically advantageous manner. The present invention relates to a process for producing an aliphatic tertiary amine by subjecting a specific aliphatic amide to hydrogenation reduction in the presence of a catalyst containing copper and at least one element selected from the group consisting of elements belonging to Groups 2, 3 and 7 of the Periodic Table; the catalyst; and a process for producing amine oxide by reacting the tertiary amide obtained by the above production process with hydrogen peroxide.
摘要翻译： 本发明提供一种生产含有少量副产物的高纯度脂肪族叔胺的方法，该方法是在中等条件下使脂肪族酰胺进行氢化还原，以及由脂族叔胺制备胺衍生物的方法， 在经济上有利的方式具有良好的生产率。 本发明涉及通过在含有铜的催化剂和选自属于第2,3和7族的元素的至少一种元素的存在下使特定的脂族酰胺进行氢化还原来制备脂肪族叔胺的方法 的周期表; 催化剂; 以及通过使通过上述制备方法获得的叔酰胺与过氧化氢反应来制备氧化胺的方法。
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