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    Ruthenium complex useful as sensitizer, dye-sensitized oxide semiconductor electrode and solar cell using same
    3.
    发明授权
    Ruthenium complex useful as sensitizer, dye-sensitized oxide semiconductor electrode and solar cell using same 失效
    用作敏化剂的钌络合物，染料敏化氧化物半导体电极和使用其的太阳能电池

    公开(公告)号：US06639073B2

    公开(公告)日：2003-10-28

    申请号：US10087218

    申请日：2002-03-04

    申请人： Ashraful Islam ,  Hideki Sugihara ,  Kohjiro Hara ,  Masatoshi Yanagida ,  Hironori Arakawa

    发明人： Ashraful Islam ,  Hideki Sugihara ,  Kohjiro Hara ,  Masatoshi Yanagida ,  Hironori Arakawa

    IPC分类号： C07F1500

    CPC分类号： H01L51/0086 ,  C07F15/0053 ,  C09B57/10 ,  H01G9/2031 ,  H01G9/2059 ,  Y02E10/542 ,  Y02E10/549

    摘要： A ruthenium complex represented by the following formula: RuL1L2X wherein L1 represents a 2,2′;6′,2″-terpyridine compound having at least one group selected from a carboxyl group, a salt of a carboxyl group, a sulfonic acid group, a salt of a sulfonic acid group, a phosphoric acid group and a salt of a phosphoric acid group, L2 represents a diketonate ligand represented by the following formula: wherein R1 and R2 are independently selected from alkyl, alkoxyalkyl, aminoalkyl, perfluoroalkyl and aryl, R3 represents a hydrogen atom, alkyl, alkoxyalkyl, aminoalkyl, perfluoroalkyl and aryl and X represents a monodentate ligand selected from a halide, a cyano group, a thiocyano group and a thiolate. A dye-sensitized oxide semiconductor electrode includes an electrically conductive body, an oxide semiconductor film provided on a surface of the electrically conductive body, and the above metal complex. A solar cell may be constructed from the above dye-sensitized oxide semiconductor electrode, a counter electrode, and a redox electrolyte contacting with both electrodes.

    摘要翻译： 由下式表示的钌络合物：其中L 1表示具有至少一个选自羧基，羧基盐，磺酸基的2,2'; 6'，2“ - 三联吡啶化合物 酸基，磺酸基的盐，磷酸基和磷酸基的盐，L 2表示由下式表示的二酮配体：其中R 1和R 2独立地选自烷基，烷氧基烷基， 氨基烷基，全氟烷基和芳基，R 3表示氢原子，烷基，烷氧基烷基，氨基烷基，全氟烷基和芳基，X表示选自卤素，氰基，硫氰基和硫醇盐的单齿配体。 染料敏化氧化物半导体电极包括导电体，设置在导电体的表面上的氧化物半导体膜和上述金属络合物。 可以由上述染料敏化氧化物半导体电极，对电极和与两电极接触的氧化还原电解质构成太阳能电池。