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1.发明申请SELECTIVE OLEFIN DIMERIZATION WITH SUPPORTED METAL COMPLEXES ACTIVATED BY ALKYLALUMINUM COMPOUNDS OR IONIC LIQUIDS 有权具有支持的金属络合物的选择性烯化二烯化合物由ALKYLALUMINUM化合物或离子液体公开(公告)号：US20110004039A1
公开(公告)日：2011-01-06
申请号：US12828797
申请日：2010-07-01
Applicant: Matthias DÖTTERL , Roland SCHMIDT , Tanja ENGLMANN , Christine DENNER , Helmut G. ALT
Inventor： Matthias DÖTTERL , Roland SCHMIDT , Tanja ENGLMANN , Christine DENNER , Helmut G. ALT
IPC: C07C2/32
CPC classification number: C07C2/34 , B01J21/08 , B01J31/0231 , B01J31/0272 , B01J31/0275 , B01J31/0295 , B01J37/0207 , B01J37/0209 , B01J2231/20 , B01J2531/842 , C07C2/32 , C07C2521/08 , C07C2531/14 , C07C2531/22
Abstract: Methods for dimerizing alpha-olefins utilizing immobilized buffered catalysts wherein the catalytic component is of the form: where X is a halogen, n=2 or 3, M=Ti, V, Cr, Mn, Fe, Co and Ni and R1, R2, R3 and R4 are selected from the group consisting of hydrogen, alkyl, aryl, alkenyl, alkinyl, alkyloxy, substituted aryl, and X are provided. A method for dimerizing alpha-olefins utilizing the immobilized buffered catalysts and a co-catalyst is also provided.
Abstract translation: 使用固定化缓冲催化剂二聚α-烯烃的方法，其中催化组分的形式为：其中X是卤素，n = 2或3，M = Ti，V，Cr，Mn，Fe，Co和Ni以及R1，R2 ，R3和R4选自氢，烷基，芳基，烯基，炔基，烷氧基，取代的芳基和X。 还提供了利用固定化缓冲催化剂和助催化剂二聚α-烯烃的方法。
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2.发明授权Selective olefin dimerization with supported metal complexes activated by alkylaluminum compounds or ionic liquids 有权选择性烯烃二聚与由烷基铝化合物或离子液体活化的负载金属配合物公开(公告)号：US08487153B2
公开(公告)日：2013-07-16
申请号：US12828797
申请日：2010-07-01
Applicant: Matthias Dötterl , Roland Schmidt , Tanja Englmann , Christine Denner , Helmut G. Alt
Inventor： Matthias Dötterl , Roland Schmidt , Tanja Englmann , Christine Denner , Helmut G. Alt
IPC: C07C2/22
CPC classification number: C07C2/34 , B01J21/08 , B01J31/0231 , B01J31/0272 , B01J31/0275 , B01J31/0295 , B01J37/0207 , B01J37/0209 , B01J2231/20 , B01J2531/842 , C07C2/32 , C07C2521/08 , C07C2531/14 , C07C2531/22
Abstract: Methods for dimerizing alpha-olefins utilizing immobilized buffered catalysts wherein a buffered ionic liquid is mixed with an organometallic complex of the formula: where X is a halogen, n=2 or 3, M=Ti, V, Cr, Mn, Fe, Co and Ni and R1, R2, R3 and R4 are selected from the group consisting of hydrogen, alkyl, aryl, alkenyl, alkynyl, alkyloxy, substituted aryl, and X are provided. A method for dimerizing alpha-olefins utilizing the immobilized buffered catalysts and a co-catalyst is also provided.
Abstract translation: 使用固定化缓冲催化剂二聚α-烯烃的方法，其中将缓冲的离子液体与下式的有机金属络合物混合：其中X是卤素，n = 2或3，M = Ti，V，Cr，Mn，Fe，Co 并且提供Ni和R 1，R 2，R 3和R 4选自氢，烷基，芳基，烯基，炔基，烷氧基，取代的芳基和X。 还提供了利用固定化缓冲催化剂和助催化剂二聚α-烯烃的方法。
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Patent Agency Ranking
公开(公告)号：US20120136189A1
公开(公告)日：2012-05-31
申请号：US13025935
申请日：2011-02-11
Applicant: Matthias Dötterl , Helmut G. Alt , Roland Schmidt
Inventor： Matthias Dötterl , Helmut G. Alt , Roland Schmidt
IPC: C07C2/24
CPC classification number: C07C2/32 , B01J31/0278 , B01J31/0282 , B01J31/0284 , B01J31/1815 , B01J2231/20 , B01J2531/0241 , B01J2531/847 , C07C2531/02 , C07C2531/14 , C07C2531/22 , C07C11/02
Abstract: The present invention relates generally to buffered ionic liquids that are very useful for dimerization of olefins, such as isopropene, wherein the buffer is a phosphine or a bismuthine or an arsine or an amine.
Abstract translation: 本发明一般涉及对烯烃二聚，如异丙烯非常有用的缓冲离子液体，其中缓冲液是膦或铋或胂或胺。
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公开(公告)号：US09115226B2
公开(公告)日：2015-08-25
申请号：US13150700
申请日：2011-06-01
Applicant: Matthias Dötterl , Helmut Alt , Roland Schmidt
Inventor： Matthias Dötterl , Helmut Alt , Roland Schmidt
IPC: C07C2/24 , C08F136/06 , C08F8/42 , C08F10/00 , B01J31/06 , B01J31/24 , C07C2/36 , C10G29/20 , B01J31/14 , B01J31/16
CPC classification number: C08F136/06 , B01J31/06 , B01J31/143 , B01J31/1683 , B01J31/2409 , B01J37/0203 , B01J37/0209 , B01J37/0213 , B01J2231/20 , B01J2531/847 , C07C2/36 , C07C2531/14 , C07C2531/24 , C08F10/00 , C10G29/205 , C08F4/027 , C08F4/7016 , C07C11/02 , C07C11/107
Abstract: A method of making a heterogenously supported catalyst useful in dimerization, oligomerization or polymerization is provided in which a catalyst precursor containing a metal and an aromatic group are alkylated onto an oligomeric support having at least one terminal unsaturated group by Friedel Crafts alkylation.
Abstract translation: 提供一种制备用于二聚，低聚或聚合的异质载体的催化剂的方法，其中通过Friedel Crafts烷基化将含有金属和芳族基团的催化剂前体烷基化到具有至少一个末端不饱和基团的低聚载体上。
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公开(公告)号：US20120010452A1
公开(公告)日：2012-01-12
申请号：US13150700
申请日：2011-06-01
Applicant: Matthias Dötterl , Helmut Alt , Roland Schmidt
Inventor： Matthias Dötterl , Helmut Alt , Roland Schmidt
IPC: C07C2/24 , C08F136/06 , C08F8/42
CPC classification number: C08F136/06 , B01J31/06 , B01J31/143 , B01J31/1683 , B01J31/2409 , B01J37/0203 , B01J37/0209 , B01J37/0213 , B01J2231/20 , B01J2531/847 , C07C2/36 , C07C2531/14 , C07C2531/24 , C08F10/00 , C10G29/205 , C08F4/027 , C08F4/7016 , C07C11/02 , C07C11/107
Abstract: A method of making a heterogenously supported catalyst useful in dimerization, oligomerization or polymerization is provided in which a catalyst precursor containing a metal and an aromatic group are alkylated onto an oligomeric support having at least one terminal unsaturated group by Friedel Crafts alkylation.
Abstract translation: 提供一种制备用于二聚，低聚或聚合的异质载体的催化剂的方法，其中通过Friedel Crafts烷基化将含有金属和芳族基团的催化剂前体烷基化到具有至少一个末端不饱和基团的低聚载体上。
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6.发明授权Organometallic complexes as catalyst precursors for selective olefin dimerization and processes therefor 有权有机金属络合物作为选择性烯烃二聚化的催化剂前体及其工艺公开(公告)号：US08816146B2
公开(公告)日：2014-08-26
申请号：US12829075
申请日：2010-07-01
Applicant: Tanja Englmann , Christine Denner , Helmut G. Alt , Roland Schmidt , Matthias Dötterl
Inventor： Tanja Englmann , Christine Denner , Helmut G. Alt , Roland Schmidt , Matthias Dötterl
IPC: C07C2/22
CPC classification number: C07C2/32 , B01J21/08 , B01J31/0284 , B01J31/0288 , B01J31/0289 , B01J31/143 , B01J31/2217 , B01J37/0207 , B01J37/0209 , B01J2231/20 , B01J2531/847 , C07C2531/14 , C07C2531/22
Abstract: Methods for dimerizing alpha-olefins utilizing immobilized buffered catalysts wherein a buffered ionic liquid is mixed with an organometallic complex of the formula: where M is selected from the group of Ti, Zr, Hg, Ni, and V and R and R′ are selected from the group consisting of hydrogen, alkyl, aryl, alkenyl, alkynyl, alkyloxy, substituted aryl, and halogens, are provided.
Abstract translation: 使用固定化缓冲催化剂二聚α-烯烃的方法，其中将缓冲的离子液体与下式的有机金属络合物混合：其中M选自Ti，Zr，Hg，Ni和V组，R和R'被选择 提供了由氢，烷基，芳基，烯基，炔基，烷氧基，取代的芳基和卤素组成的组。
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7.发明申请ORGANOMETALLIC COMPLEXES AS CATALYST PRECURSORS FOR SELECTIVE OLEFIN DIMERIZATION AND PROCESSES THEREFOR 有权有机金属络合物作为催化剂前体，用于选择性烯烃二元化及其工艺公开(公告)号：US20110004040A1
公开(公告)日：2011-01-06
申请号：US12829075
申请日：2010-07-01
Applicant: Tanja Englmann , Christine Denner , Helmut G. Alt , Roland Schmidt , Matthias Dötterl
Inventor： Tanja Englmann , Christine Denner , Helmut G. Alt , Roland Schmidt , Matthias Dötterl
IPC: C07C2/32
CPC classification number: C07C2/32 , B01J21/08 , B01J31/0284 , B01J31/0288 , B01J31/0289 , B01J31/143 , B01J31/2217 , B01J37/0207 , B01J37/0209 , B01J2231/20 , B01J2531/847 , C07C2531/14 , C07C2531/22
Abstract: Methods for dimerizing alpha-olefins utilizing immobilized buffered catalysts, wherein the catalytic component is of the formula: where M is selected from the group of Ti, Zr, Hg, Ni, and V and R and R′ are selected from the group consisting of hydrogen, alkyl, aryl, alkenyl, alkinyl, alkyloxy, substituted aryl, and halogens, are provided.
Abstract translation: 使用固定化缓冲催化剂二聚α-烯烃的方法，其中催化组分具有下式：其中M选自Ti，Zr，Hg，Ni和V组，R和R'选自 氢，烷基，芳基，烯基，炔基，烷氧基，取代的芳基和卤素。
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