公开(公告)号：US20110061529A1

公开(公告)日：2011-03-17

申请号：US12736046

申请日：2009-02-17

申请人： Thilo Von Trotha ,  Vincent Liu ,  Michael Wyschofsky

发明人： Thilo Von Trotha ,  Vincent Liu ,  Michael Wyschofsky

IPC分类号： B01D53/047

CPC分类号： B01D53/0476 ,  B01D2256/16 ,  B01D2257/504 ,  C01B3/34 ,  C01B3/56 ,  C01B2203/0233 ,  C01B2203/043 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/0495 ,  C01B2203/0838 ,  C01B2203/0883 ,  C01B2203/148 ,  C01B2203/84 ,  Y02C10/08 ,  Y02P20/152 ,  Y02P30/30

摘要： A process is described for purifying synthesis gas by means of a pressure swing adsorption unit which is desorbed by a vacuum produced by a so-called ejector, which is driven by steam generated by a heat exchanger which uses the heat in the flue gas duct or in the useful-gas duct for the generation of steam. The pressure swing adsorption unit is operated advantageously in cyclic turns of adsorption under excess pressure, depressurization desorption and vacuum desorption and the gas desorbed by the ejector being cooled in a cooler so that the contained steam can be condensed and discharged or is advantageously returned to the feed gas for the synthesis gas production. The foreign gas desorbed by the pressure swing adsorption unit, which contains at least partly not yet consumed fuel gas, is recycled to the fuel gas. In an advantageous embodiment, the vacuum from the ejector is stored in an intermediate tank and applied to the pressure swing adsorption unit according to the vacuum desorption cycle. Also disclosed is a device for running this process.

摘要翻译： 描述了一种通过变压吸附单元来净化合成气的方法，所述变压吸附装置由所谓的喷射器产生的真空解吸，所述真空由利用烟气管道中的热量的热交换器产生的蒸汽驱动， 在用于产生蒸汽的有用气体管道中。 变压吸附单元有利地在过压下循环吸附循环转动，减压解吸和真空解吸，并且通过喷射器解吸的气体在冷却器中冷却，使得所含蒸汽可以冷凝和排出，或者有利地返回到 用于合成气生产的原料气。 由至少部分尚未消耗的燃料气体的变压吸附单元解吸的外来气体被再循环到燃料气体中。 在有利的实施例中，来自喷射器的真空存储在中间罐中，并根据真空解吸循环施加到变压吸附单元。 还公开了用于运行该过程的装置。

公开(公告)号：US06277345B1

公开(公告)日：2001-08-21

申请号：US09448104

申请日：1999-11-23

申请人： Achim Stankowiak ,  Horst Streitberger ,  Michael Wyschofsky

发明人： Achim Stankowiak ,  Horst Streitberger ,  Michael Wyschofsky

IPC分类号： C10L310

CPC分类号： B01D53/14 ,  B01D53/1493 ,  Y02C10/06

摘要： The present invention relates to the use of an absorption liquid for purifying a gas by removal of gaseous, acidic impurities. The gas to be purified can be any gas, such as synthesis gas or natural gas, which contains gaseous, acidic impurities such as CO2, H2S, SO2, CS2, HCN, COS or mercaptans. The absorption liquid comprises: A) from 0.01 to 4% by weight of at least one compound of the formula B) from 0.001 to 8.0% by weight of water, and C) at least one polyalkylene glycol alkyl ether of the formula R1—O—(R2—O)x—R3 to 100% by weight, where R1 is C1-C4-alkyl, R2 is ethylene or 2-methylethylene, R3 is hydrogen or C1-C4-alkyl, R4 is hydrogen or C1-C4-alkyl, R5 is C1-C4-alkylene and X is an integer from 1 to 10. The amine may be N-methyldiethanolamine and the ether may be polyethylene glycol dimethyl ether.

摘要翻译： 本发明涉及通过去除气态酸性杂质来吸收液体来净化气体的用途。 待净化的气体可以是含有气态，酸性杂质如CO 2，H 2 S，SO 2，CS 2，HCN，COS或硫醇的任何气体，例如合成气或天然气。 吸收液体包括：A）0.01至4重量％的至少一种式B）化合物0.001至8.0重量％的水，和C）至少一种100重量％的制备的聚亚烷基二醇烷基醚， 其中R 1是C 1 -C 4烷基，R 2是亚乙基或2-甲基亚乙基，R 3是氢或C 1 -C 4 - 烷基，R 4是氢或C 1 -C 4烷基，R 5是C 1 -C 4亚烷基，X是从1到 胺可以是N-甲基二乙醇胺，醚可以是聚乙二醇二甲醚。

公开(公告)号：US08361198B2

公开(公告)日：2013-01-29

申请号：US12736046

申请日：2009-02-17

申请人： Thilo Von Trotha ,  Vincent Liu ,  Michael Wyschofsky

发明人： Thilo Von Trotha ,  Vincent Liu ,  Michael Wyschofsky

IPC分类号： B01D53/047 ,  C01B3/56

CPC分类号： B01D53/0476 ,  B01D2256/16 ,  B01D2257/504 ,  C01B3/34 ,  C01B3/56 ,  C01B2203/0233 ,  C01B2203/043 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/0495 ,  C01B2203/0838 ,  C01B2203/0883 ,  C01B2203/148 ,  C01B2203/84 ,  Y02C10/08 ,  Y02P20/152 ,  Y02P30/30

摘要： A process is described for purifying synthesis gas by means of a pressure swing adsorption unit which is desorbed by a vacuum produced by a so-called ejector, which is driven by steam generated by a heat exchanger which uses the heat in the flue gas duct or in the useful-gas duct for the generation of steam. The pressure swing adsorption unit is operated advantageously in cyclic turns of adsorption under excess pressure, depressurization desorption and vacuum desorption and the gas desorbed by the ejector being cooled in a cooler so that the contained steam can be condensed and discharged or is advantageously returned to the feed gas for the synthesis gas production. The foreign gas desorbed by the pressure swing adsorption unit, which contains at least partly not yet consumed fuel gas, is recycled to the fuel gas. In an advantageous embodiment, the vacuum from the ejector is stored in an intermediate tank and applied to the pressure swing adsorption unit according to the vacuum desorption cycle. Also disclosed is a device for running this process.

摘要翻译： 描述了一种通过变压吸附单元来净化合成气的方法，所述变压吸附装置由所谓的喷射器产生的真空解吸，所述真空由利用烟气管道中的热量的热交换器产生的蒸汽驱动， 在用于产生蒸汽的有用气体管道中。 变压吸附单元有利地在过压下循环吸附循环转动，减压解吸和真空解吸，并且通过喷射器解吸的气体在冷却器中冷却，使得所含蒸汽可以冷凝和排出，或者有利地返回到 用于合成气生产的原料气。 由至少部分尚未消耗的燃料气体的变压吸附单元解吸的外来气体被再循环到燃料气体中。 在有利的实施例中，来自喷射器的真空存储在中间罐中，并根据真空解吸循环施加到变压吸附单元。 还公开了用于运行该过程的装置。

公开(公告)号：US06740258B1

公开(公告)日：2004-05-25

申请号：US09715800

申请日：2000-11-17

申请人： Michael Wyschofsky ,  Vincent Liu

发明人： Michael Wyschofsky ,  Vincent Liu

IPC分类号： C01B326

CPC分类号： C01B3/56 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/043 ,  C01B2203/0495 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/146 ,  Y02P20/128

摘要： Process and plant for the production of synthesis gas, hydrogen and/or reducing gas by means of a primary reformer heated on the shell side, used in conjunction with a pressure swing adsorption unit for purifying the product gas, the purpose of which is to find a solution to the problem of utilising the work potential of the fuel gas from the pressure swing adsorption unit, which is used to fire the primary gas reformer. This is achieved by supplying the waste desorption gas from the pressure swing adsorption unit to the inlet side of an ejector, which is driven by a part stream of the fuel gas for the primary reformer, the waste desorption gas being admixed to a main fuel gas stream and/or a regulating gas stream, depending on the particular mode of operation.

摘要翻译： 用于通过在壳侧加热的初级重整器生产合成气，氢气和/或还原气的工艺和设备，与用于净化产物气体的变压吸附单元结合使用，其目的是找到 解决了利用来自用于对主气体重整器进行燃烧的变压吸附单元的燃料气体的工作电位的问题。这是通过将来自变压吸附单元的废物解吸气体供给到入口侧 由主要重整器的燃料气体的一部分流驱动的喷射器，根据特定操作模式，将废物解吸气体与主要燃料气体流和/或调节气体流混合。

公开(公告)号：US06989047B2

公开(公告)日：2006-01-24

申请号：US10473456

申请日：2002-04-05

申请人： Michael Wyschofsky ,  Vincent Liu

发明人： Michael Wyschofsky ,  Vincent Liu

IPC分类号： B01D52/14 ,  C01C1/04

CPC分类号： C01B3/501 ,  B01D53/1425 ,  B01D53/1493 ,  B01D53/229 ,  C01B3/025 ,  C01B3/52 ,  C01B2203/0405 ,  C01B2203/0415 ,  C01B2203/0465 ,  C01B2203/048 ,  C01B2203/146 ,  C01C1/0476 ,  Y02C20/20 ,  Y02P20/129 ,  Y02P20/52

摘要： The invention relates to a process for the absorptive separation of NH3 and CH4 from a gas under high pressure, which at least contains NH3, H2, N2 and CH4, using a high-boiling, physically acting and regenerable solvent which contains homologues of alkylene glycol-alkyl-ether and which also may contain water, the absorbed components NH3, H2, N2 and CH4 being separated from the laden solvent in at least two further process steps at different pressure rates, thereby withdrawing at least one NH3-rich and at least one CH4-rich gas fraction from the solvent. This process is particularly suitable to be incorporated as unit in an ammonia production plant.

摘要翻译： 本发明涉及一种从高压气体吸收分离NH 3和CH 4 H 4的方法，其至少含有NH 3 - ，H 2，N 2和CH 4，使用高沸点的物理作用和可再生的溶剂，其含有亚烷基二醇 - 烷基的同系物 - 醚，并且其也可以含有水，吸收的组分NH 3，H 2，N 2和CH 4 在不同的压力下在至少两个另外的工艺步骤中从负载的溶剂中分离出来，从而抽出至少一个富含NH 3和富含3个富含NH 3 来自溶剂的气体馏分。 该方法特别适合作为单元并入氨生产设备中。

公开(公告)号：US20050000359A1

公开(公告)日：2005-01-06

申请号：US10484972

申请日：2002-07-17

申请人： Michael Wyschofsky ,  Dirk Hoberg

发明人： Michael Wyschofsky ,  Dirk Hoberg

IPC分类号： B01D53/14 ,  C10K1/16 ,  C10L3/10 ,  C10L10/14 ,  C10L10/18

CPC分类号： B01D53/1493 ,  C10K1/16 ,  C10K1/165

摘要： The invention relates to a process for removing components from technical gases, said components being scrubbed from the technical gas, the scrubbing agent laden with said components being purified in a separate regeneration process and the scrubbing to remove these components taking place at a temperature of +15° to −60° C. The scrubbing agent is ethylene glycol dimethyl ether (EGDME) or a mixture of various EGDMEs, said scrubbing agent having a solidification point of

摘要翻译： 本发明涉及一种从技术气体中去除组分的方法，所述组分从技术气体中洗涤，所述组分的洗涤剂在独立的再生过程中被纯化，并且在+ 15°至-60℃。洗涤剂是乙二醇二甲醚（EGDME）或各种EGDME的混合物，所述洗涤剂的凝固点<-30℃，沸点<275℃ 在常压下和摩尔质量<230g / mol。