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1.发明授权Oxidized sulfur derivatives of diaminophosphinyl compounds as urease inhibitors 失效二氨基氧膦基化合物的氧化硫衍生物作为脲酶抑制剂
公开(公告)号：US4824783A
公开(公告)日：1989-04-25
申请号：US908542
申请日：1986-09-18
摘要： The invention relates to novel urease inhibited fertilizer compositions containing urea and a urease inhibiting amount of one or more diaminophosphinyl compounds having oxidized sulfur functions, and methods and composition for inhibiting the activity of urease through use of such compounds.
摘要翻译： 本发明涉及含有尿素和脲酶抑制量的一种或多种具有氧化硫功能的二氨基氧膦基化合物的新型脲酶抑制肥料组合物，以及通过使用这些化合物抑制脲酶活性的方法和组合物。
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2.发明授权Oxidized sulfur derivatives of diaminophosphinyl compounds as urease inhibitors and urease inhibited urea based fertilizer compositions 失效二脲氧膦基化合物的氧化硫衍生物作为脲酶抑制剂和脲酶抑制尿素肥料组合物
公开(公告)号：US4696693A
公开(公告)日：1987-09-29
申请号：US861809
申请日：1986-05-12
CPC分类号： C05G3/08 , C07F9/224 , Y10S71/902
摘要： The invention relates to novel urease inhibited fertilizer compositions containing urea and a urease inhibiting amount of one or more diaminophosphinyl compounds having oxidized sulfur functions, and methods and composition for inhibiting the activity of urease through use of such compounds.
摘要翻译： 本发明涉及含有尿素和脲酶抑制量的一种或多种具有氧化硫功能的二氨基氧膦基化合物的新型脲酶抑制肥料组合物，以及通过使用这些化合物抑制脲酶活性的方法和组合物。
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公开(公告)号：US4393215A
公开(公告)日：1983-07-12
申请号：US280754
申请日：1981-07-06
IPC分类号： C07C259/02 , C07D271/08
CPC分类号： C07C259/02
摘要： Dialkoxyketoximes such as dimethoxycyclohexanone cleave with halogen and water under basic conditions to yield a series of products having an ester functionality and another functionality which is oximohalide, nitrile oxide or furoxan, depending upon the base strength and/or work-up conditions. Each of those products can be further reacted with sulfur dioxide to produce an adduct, from which an isocyanate is derived. Both the adduct and the isocyanate retain the ester functionality.
摘要翻译： 二烷氧基环己酮如二甲氧基环己酮在碱性条件下用卤素和水分解，得到一系列具有酯官能团和另一功能性的产物，它们是氧基卤化物，氧化腈或呋喃糖，这取决于碱强度和/或处理条件。 这些产物中的每一种都可以进一步与二氧化硫反应以产生加成物，从中得到异氰酸酯。 加合物和异氰酸酯保留酯官能度。
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4.发明授权S-aryl and S-aliphatic diamidophosphorothiolates as urease inhibitors and urease inhibited urea based fertilizer compositions 失效S-芳基和S-脂族二酰氨基磷酸硫醇酯作为脲酶抑制剂和脲酶抑制脲基肥料组合物
公开(公告)号：US4537614A
公开(公告)日：1985-08-27
申请号：US575787
申请日：1984-02-03
申请人： Michael Van Der Puy , Jaroslav F. Kolc , Louis G. Anello , Larry L. Hendrickson , Milorad M. Rogic , Michael D. Swerdloff
发明人： Michael Van Der Puy , Jaroslav F. Kolc , Louis G. Anello , Larry L. Hendrickson , Milorad M. Rogic , Michael D. Swerdloff
CPC分类号： C07F9/2416 , C05G3/08 , C07F9/20 , C07F9/2408 , Y10S71/902
摘要： Novel urease inhibiting phosphorothiolate compounds, urea based fertilizer compositions including such compounds, and methods and compositions for using such compounds to inhibit the activity of urease.
摘要翻译： 新型尿素酶抑制性硫代磷酸酯化合物，包含这些化合物的尿素基肥料组合物，以及使用这些化合物抑制脲酶活性的方法和组合物。
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5.发明授权Phosphoroamide urease inhibitors and urease inhibited urea based fertilizer compositions 失效磷酰脲脲酶抑制剂和尿素酶抑制尿素肥料组成
公开(公告)号：US4517007A
公开(公告)日：1985-05-14
申请号：US502439
申请日：1983-06-09
CPC分类号： C05G3/08 , Y10S71/902
摘要： Novel urease inhibiting phosphoroamide compounds and urea based fertilizer compositions including such compounds, and methods and compositions for inhibiting the activity of urease through use of a urease inhibiting effective amount of one or more of the aforementioned phosphoroamide compounds.
摘要翻译： 包含这些化合物的新型脲酶抑制磷酰胺化合物和脲基肥料组合物，以及通过使用脲酶抑制有效量的一种或多种上述磷酰胺化合物来抑制脲酶活性的方法和组合物。
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公开(公告)号：US4310702A
公开(公告)日：1982-01-12
申请号：US172798
申请日：1980-07-28
IPC分类号： C07C37/62 , C07C41/22 , C07C45/63 , C07C49/16 , C07C49/463 , C07C148/00
CPC分类号： C07C37/62 , C07C45/63 , C07C49/16 , C07C49/463
摘要： Sulfuryl chloride is reacted in the liquid phase with an organic reactant which is a ketone or aromatic alcohol unsubstituted on both ortho carbons in the presence of a moderator selected from the group consisting of aliphatic alcohols of 1-3 carbons and aliphatic ethers of 2-6 carbons, with sufficient moderator being present to selectively produce a product substantially free of compounds with more than one chlorine atom per carbonyl or aromatic hydroxy. The products, such as monochloroacetone, monochlorocyclohexanone, monochlorophenol and 2,2-bis(3-chloro-4-hydroxyphenyl)propane, are useful as chemical intermediates and as monomers for flame retardant polymers.
摘要翻译： 在液相中使硫酰氯与有机反应物反应，所述有机反应物是在两种正碳上未取代的酮或芳族醇，在选自1-3个碳原子的脂族醇和2-6个脂肪族醚的脂肪族醚的存在下， 碳，具有足够的缓和剂以选择性地产生基本上不含每个羰基或芳族羟基具有多于一个氯原子的化合物的产物。 产物如单氯丙酮，单氯环己酮，一氯酚和2,2-双（3-氯-4-羟基苯基）丙烷可用作化学中间体和作为阻燃聚合物的单体。
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公开(公告)号：US4240966A
公开(公告)日：1980-12-23
申请号：US968934
申请日：1978-12-13
IPC分类号： C07D317/72 , C07J41/00 , C07D317/44 , C07D317/10
CPC分类号： C07D317/72 , C07J41/0016
摘要： This invention describes novel cyclic ketals of .alpha.-oximinoketones and methods for the preparation of these compounds.
摘要翻译： 本发明描述了α-肟基酮的新型环状缩酮及其制备方法。
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8.发明授权.alpha.-Nitrosoketal dimers and production of .alpha.-oximinoketals therefrom 失效α-硝基二缩酮二聚体和由其衍生的α-肟基酮
公开(公告)号：US4206112A
公开(公告)日：1980-06-03
申请号：US968935
申请日：1978-12-13
IPC分类号： C07D317/72 , C07J41/00 , C07C105/00 , C07C131/00
CPC分类号： C07J41/0016 , C07D317/72
摘要： This invention describes novel ketals of .alpha.-oximinoketones, methods for the preparation of these compounds and includes novel intermediates formed during the production thereof. The novel class of compounds disclosed herein includes both .alpha.-oximinoketals, as well as the cyclic ketals of .alpha.-oximinoketones. This invention also discloses a novel class of .alpha.-nitrosoketal dimers produced during the synthesis of the corresponding .alpha.-oximinoketals, and it also discloses novel methods in the production thereof.
摘要翻译： 本发明描述了α-肟基酮的新型缩酮，制备这些化合物的方法，包括在其制备过程中形成的新型中间体。 本文公开的新一类化合物包括α-肟基酮，以及α-肟基酮的环缩酮。 本发明还公开了在合成相应的α-肟基时产生的一类新的α-亚硝基二酮二聚体，并且还公开了其生产中的新方法。
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9.发明授权Functionalized tripodal ligands for x-ray & radioactive imaging applications 失效用于x射线和放射性成像应用的功能化三齿配体
公开(公告)号：US5565184A
公开(公告)日：1996-10-15
申请号：US310514
申请日：1994-09-22
申请人： T. Jeffrey Dunn , Dennis A. Moore , Muthunadar P. Periasamy , Milorad M. Rogic , Rebecca A. Wallace , David H. White , Steven R. Woulfe
发明人： T. Jeffrey Dunn , Dennis A. Moore , Muthunadar P. Periasamy , Milorad M. Rogic , Rebecca A. Wallace , David H. White , Steven R. Woulfe
IPC分类号： G01R33/28 , A61B5/055 , A61K49/00 , A61K49/06 , C07C59/125 , C07C229/16 , C07C229/76 , C07C237/08 , C07C309/07 , C07C309/13 , C07F5/00 , C07F9/38 , C07F9/94 , C07F13/00 , A61K49/04
CPC分类号： C07C229/76 , A61K49/06 , C07C229/16 , C07C237/08 , C07C59/125 , C07F5/003 , Y10S514/836 , Y10T436/24
摘要： The present invention provides new and structurally diverse compositions comprising compounds of the general formula: ##STR1## wherein A is N or CR.sub.1, R.sub.1 is hydrogen, C.sub.1 -C.sub.8 alkyl, or C.sub.6 -C.sub.10 aryl, where the alkyl or aryl group may be optionally substituted with one or more hydroxy, C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 hydroxyalkyl, C.sub.1 -C.sub.8 alkoxy, C.sub.6 -C.sub.10 aryl, C.sub.6 -C.sub.10 hydroxyaryl, C.sub.6 -C.sub.10 aryloxy, --CO.sub.2 R.sub.2, --CONR.sub.3 R.sub.4, or NR.sub.3 R.sub.4 ; R.sub.2 -R.sub.7 are as defined within; g, h, i, j, k and m may be the same or different and are an integer from one to about six; X is --CO.sub.2 H, --PO.sub.3 H.sub.2, --SO.sub.3 H or --CONHOH.Methods for imaging including MRI, X-ray and radiation diagnosis using compositions of the invention are also provided.
摘要翻译： 本发明提供新的和结构上不同的组合物，其包含以下通式的化合物：其中A是N或CR 1，R 1是氢，C 1 -C 8烷基或C 6 -C 10芳基，其中烷基或芳基可以是任选的 被一个或多个羟基，C 1 -C 8烷基，C 1 -C 8羟烷基，C 1 -C 8烷氧基，C 6 -C 10芳基，C 6 -C 10羟基芳基，C 6 -C 10芳氧基，-CO 2 R 2，-CONR 3 R 4或NR 3 R 4取代; R2-R7如上所定义; g，h，i，j，k和m可以相同或不同，为1〜6的整数; X是-CO 2 H，-PO 3 H 2，-SO 3 H或-CONHOH。 还提供了使用本发明的组合物进行MRI，X射线和放射线诊断的成像方法。
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公开(公告)号：US5405601A
公开(公告)日：1995-04-11
申请号：US87837
申请日：1993-07-02
申请人： T. Jeffrey Dunn , Dennis A. Moore , Muthanadar Periasamy , Milorad M. Rogic , Rebecca A. Wallace , David H. White , Steven R. Woulfe
发明人： T. Jeffrey Dunn , Dennis A. Moore , Muthanadar Periasamy , Milorad M. Rogic , Rebecca A. Wallace , David H. White , Steven R. Woulfe
IPC分类号： G01R33/28 , A61B5/055 , A61K49/00 , A61K49/06 , C07C59/125 , C07C229/16 , C07C229/76 , C07C237/08 , C07C309/07 , C07C309/13 , C07F5/00 , C07F9/38 , C07F9/94 , C07F13/00 , C07C55/00 , C07C59/245
CPC分类号： C07C229/76 , A61K49/06 , C07C229/16 , C07C237/08 , C07C59/125 , C07F5/003 , Y10S514/836 , Y10T436/24
摘要： The present invention provides new and structurally diverse compositions for diagnostic imaging comprising compounds of the general formula: ##STR1## wherein A is N or CR.sub.1, R.sub.1 is hydrogen, C.sub.1 -C.sub.8 alkyl, or C.sub.6 -C.sub.10 aryl, where the alkyl or aryl group may be optionally substituted with one or more hydroxy, C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 hydroxyalkyl, C.sub.1 -C.sub.8 alkoxy, C.sub.6 -C.sub.10 aryl, C.sub.6 -C.sub.10 hydroxyaryl, C.sub.6 -C.sub.10 aryloxy, --CO.sub.2 R.sub.2, --CONR.sub.3 R.sub.4, or NR.sub.3 R.sub.4 ; D is O, --O(CH.sub.2).sub.2 O--, --O(CH.sub.2).sub.3 O--, or NR.sub.5 ; E is O, --O(CH.sub.2).sub.2 O--, --O(CH.sub.2).sub.3 O-- or NR.sub.6 ; F is O, --O(CH.sub.2).sub.2 O--, --O(CH.sub.2).sub.3 O-- or NR.sub.7 ; R.sub.2 -R.sub.7 are as defined within; g, h, i, j, k and m may be the same or different and are an integer from one to about six; X is --CO.sub.2 H, --PO.sub.3 H.sub.2, --SO.sub.3 H or --CONHOH.
摘要翻译： 本发明提供用于诊断成像的新的和结构不同的组合物，其包含以下通式的化合物：其中烷基或芳基可以任选地被一个或多个羟基，C 1 -C 8烷基 ，C 1 -C 8羟基烷基，C 1 -C 8烷氧基，C 6 -C 10芳基，C 6 -C 10羟基芳基，C 6 -C 10芳氧基，-CO 2 R 2，-CONR 3 R 4或NR 3 R 4; D是O，-O（CH 2）2 O-，-O（CH 2）3 O-或NR 5; E是O，-O（CH 2）2 O-，-O（CH 2）3 O-或NR 6; F是O，-O（CH 2）2 O-，-O（CH 2）3 O-或NR 7; R2-R7如上所定义; g，h，i，j，k和m可以相同或不同，为1〜6的整数; X是-CO 2 H，-PO 3 H 2，-SO 3 H或-CONHOH。
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