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33 条记录 (耗时 0.011 秒)

    Process for preparing fluorine-containing dicarbonyl compound
    1.
    发明授权
    Process for preparing fluorine-containing dicarbonyl compound 失效
    含氟二羰基化合物的制备方法

    公开(公告)号：US5569778A

    公开(公告)日：1996-10-29

    申请号：US428133

    申请日：1995-04-28

    申请人： Teruo Umemoto ,  Ginjiro Tomizawa

    发明人： Teruo Umemoto ,  Ginjiro Tomizawa

    IPC分类号： C07B39/00 ,  C07C45/63 ,  C07C49/457 ,  C07C49/463 ,  C07C49/813 ,  C07C67/307 ,  C07C205/43 ,  C07C205/45 ,  C07C67/287

    CPC分类号： C07C205/45 ,  C07B39/00 ,  C07C205/43 ,  C07C45/63 ,  C07C49/457 ,  C07C49/463 ,  C07C49/813 ,  C07C67/307 ,  C07C2101/08 ,  C07C2101/14

    摘要： A process for preparing a fluorine-containing dicarbonyl compound of the formula: R.sup.1 COCFR.sup.2 COR.sup.3 in which R.sup.1 is a hydrogen atom, or a substituted or unsubstituted alkyl or aryl group; R.sup.2 is a hydrogen atom, a halogen atom, or a substituted or unsubstituted alkyl or aryl group; and R.sup.3 is a hydrogen atom, or a substituted or unsubstituted alkyl, aryl, alkoxy or aryloxy group, provided that at least two of R.sup.1, R.sup.2 and R.sup.3 may together form a part of a cyclic structure with or without a hetero atom, by reacting a dicarbonyl compound of the formula: R.sup.1 COCHR.sup.2 COR.sup.3 in which R.sup.1, R.sup.2 and R.sup.3 are the same as defined above with fluorine (F.sub.2) in at least one solvent selected from the group consisting of halogenated hydrocarbons having 1 to 5 carbon atoms and nitrile compounds, or in a solvent in the presence of a salt, or an acid having pKa of 6 or less.By the above process, the fluorine-containing dicarbonyl compound is industrially prepared in a high yield.

    摘要翻译： PCT No.PCT / JP93 / 01584第 371日期：1995年4月28日 102（e）日期1995年4月28日PCT 1993年11月1日PCT公布。 第WO94 / 10120 PCT公开 日期：1994年5月11日制备下式的含氟二羰基化合物的方法：R1COCFR2COR3，其中R1是氢原子或取代或未取代的烷基或芳基; R2是氢原子，卤素原子或取代或未取代的烷基或芳基; 并且R 3是氢原子或取代或未取代的烷基，芳基，烷氧基或芳氧基，条件是R 1，R 2和R 3中的至少两个可以一起形成具有或不具有杂原子的环状结构的一部分， 一种下式的二羰基化合物：R1COCHR2COR3，其中R1，R2和R3与上述定义相同，在至少一种选自碳原子数为1〜5的卤代烃和腈化合物的溶剂中使用氟（F2），或 在溶剂中，在盐的存在下，或pKa为6以下的酸。 通过上述方法，可以高产率工业上制备含氟二羰基化合物。

    Process for preparing tetrahalocyclohexanone
    2.
    发明授权
    Process for preparing tetrahalocyclohexanone 失效
    制备四卤代环己酮的方法

    公开(公告)号：US4219505A

    公开(公告)日：1980-08-26

    申请号：US901839

    申请日：1978-05-01

    申请人： Brian J. Needham ,  John Miller

    发明人： Brian J. Needham ,  John Miller

    IPC分类号： C07C49/463 ,  B01J31/00 ,  C07B61/00 ,  C07C45/00 ,  C07C45/63 ,  C07C67/00 ,  C07C49/30

    CPC分类号： C07C45/63

    摘要： 2,2,6,6-Tetrachloro(or tetrabromo)cyclohexanone is prepared by reacting in the liquid phase chlorine or bromine with a cyclohexanone compound of formula ##STR1## where Y is hydrogen or chlorine (to produce the tetrachloro compound) or hydrogen or bromine (to produce the tetrabromo compound) in the presence as catalyst of an organophosphorus compound of formula ##STR2## where Z is chlorine or bromine; n is 0 or 1; and when n is 0, m is 0 or 2, R.sup.1 is alkyl or phenyl, and R.sup.2 and R.sup.3 are hydrogen, alkyl or phenyl; and when n is 1, m is 0, and R.sup.1, R.sup.2 and R.sup.3 are the same and each is ##STR3## alkyl or phenyl, or R.sup.1 is hydrogen and R.sup.2 and R.sup.3 are alkyl or phenyl;or a salt thereof.Each alkyl is of 1-10 carbon atoms.

    摘要翻译： 2,2,6,6-四氯（或四溴）环己酮是通过液相氯或溴与式I的环己酮化合物反应来制备的，其中Y是氢或氯（以产生四氯化合物）或氢 或溴（以产生四溴化合物）作为其中Z为氯或溴的式II的有机磷化合物的催化剂存在; n为0或1; 当n为0时，m为0或2，R1为烷基或苯基，R2和R3为氢，烷基或苯基; 当n为1时，m为0，R 1，R 2和R 3为相同且各自为烷基或苯基，或R 1为氢，R 2和R 3为烷基或苯基; 或其盐。 每个烷基具有1-10个碳原子。

    Synthesis intermediates containing a hexane ring and processes for their preparation
    5.
    发明授权
    Synthesis intermediates containing a hexane ring and processes for their preparation 失效
    含有己烷环的合成中间体及其制备方法

    公开(公告)号：US5424460A

    公开(公告)日：1995-06-13

    申请号：US139049

    申请日：1993-10-21

    申请人： Lucette Duhamel ,  Pierre Duhamel ,  Bertrand Leblond ,  Jean-Marie Poirier

    发明人： Lucette Duhamel ,  Pierre Duhamel ,  Bertrand Leblond ,  Jean-Marie Poirier

    IPC分类号： C07D301/26 ,  C07C29/10 ,  C07C29/124 ,  C07C29/64 ,  C07C35/48 ,  C07C37/06 ,  C07C39/24 ,  C07C39/26 ,  C07C39/28 ,  C07C39/373 ,  C07C45/51 ,  C07C45/58 ,  C07C49/463 ,  C07C49/687 ,  C07D303/08

    CPC分类号： C07C45/512 ,  C07C35/48 ,  C07C45/58 ,  C07C49/463 ,  C07C49/687 ,  C07D303/08

    摘要： The present invention relates to new fluorinated hexane compounds corresponding to the following general formula (II): ##STR1## in which X'.sub.2, X'.sub.3 and X'.sub.4 are the same or different, and denote a halogen or a pseudohalogen, preferably a halogen, more preferably chlorine and fluorine, with the condition that, when R.sub.1 is hydroxyl, cyano, amido, imido, ethoxy, benzyloxy, cyclohexyloxy and tert-butoxy, not all the halogens can simultaneously be chlorine and R.sub.4, R.sub.3 and R.sub.5 are simultaneously equal to H;R.sub.1 denotes a hydrogen, a hydrocarbon chain such as an alkyl chain, alkoxy, cycloalkyl ether, an aromatic group, aromatic ether or an alkoxy, carbonyl, carboxyl or acyloxy, cyano, amido, imido or hydroxyl group;R.sub.4 denotes a hydrogen, a fluorine atom, a hydrocarbon chain such as, for example, an alkyl chain, an aromatic group or a carbonyl, carboxyl or carboxamide group or else a radical joined to the hexane ring by a chalcogen or by an element of Group V, preferably of the first Period, such as an amido, alkoxy or acyloxy group;in which the radicals R.sub.3 and R.sub.5, which are different or preferably the same, denote a fluorine, or preferably hydrogen, atom or also a hydrocarbon chain as defined above in the case of R.sub.4.

    摘要翻译： 本发明涉及对应于以下通式（II）的新的氟化己烷化合物：其中X'2，X'3和X'4相同或不同，并且表示卤素或假卤素，优选 卤素，更优选氯和氟，条件是当R1是羟基，氰基，酰胺基，亚氨基，乙氧基，苄氧基，环己氧基和叔丁氧基时，不是所有的卤素都可以同时是氯，R4，R3和R5是 同时等于H; R 1表示氢，烃链如烷基链，烷氧基，环烷基醚，芳族基团，芳族醚或烷氧基，羰基，羧基或酰氧基，氰基，酰胺基，亚氨基或羟基; R4表示氢，氟原子，烃链，例如烷基链，芳族基团或羰基，羧基或羧酰胺基团，或者由硫属化合物连接到己烷环上的基团，或者由 优选第一阶段的V族如酰氨基，烷氧基或酰氧基; 其中不同或优选相同的基团R3和R5表示在R4的情况下如上所定义的氟或优选氢原子或烃链。

    Perfluorocyclohexene-1,4-dione
    7.
    发明授权
    Perfluorocyclohexene-1,4-dione 失效
    全氟环己烯-1,4-二酮

    公开(公告)号：US3931325A

    公开(公告)日：1976-01-06

    申请号：US448135

    申请日：1974-03-04

    申请人： Harold E. Doorenbos ,  Hughie R. Frick

    发明人： Harold E. Doorenbos ,  Hughie R. Frick

    IPC分类号： C07C45/63 ,  C07C49/463 ,  C08G65/00 ,  C07C49/48

    CPC分类号： C08G65/007 ,  C07C45/63 ,  C07C49/463

    摘要： Two new organic compounds are disclosed, perfluorocyclohexane-1,4-dione and perfluorocyclohexene-1,4-dione, which are obtained concurrently or alternatively by reacting fluoranil with substantially pure anhydrous cobalt trifluoride. These compounds are clear, colorless liquids which are useful as monomers in the synthesis of thermally stable elastomeric polymers. Also disclosed is the dihydrate of said perfluorocyclohexane-1,4-dione, namely, octafluoro-1,1,4,4-cyclohexanetetraol. Another aspect of this invention is a series of polyethers formed by reacting said perfluorocyclohexane-1,4-dione with cesium fluoride and a cyclic or noncyclic aliphatic perhaloalkene having from 2 to 12 carbon atoms and a fluorine atom on at least each of the carbon atoms connected by the double bond, said polymer having as a repeating unit ##SPC1##WhereinR is a divalent radical selected from the group consisting of ##EQU1## WHEREIN X is a halogen selected from the group consisting of fluorine, chlorine, bromine, iodine, or any stable combination thereof within the same molecule;n is an integer of from 1 to 4;y is an integer of from 0 to 10; andZ is an integer of from 0 to (10-y).When of sufficiently high molecular weight or when lightly cross-linked, these polymers are elastomers having high thermal stability.

    摘要翻译： 公开了两种新的有机化合物，全氟环己烷-1,4-二酮和全氟环己烯-1,4-二酮，它们同时或通过使荧蒽与基本上纯的无水三氟化碳反应得到。 这些化合物是透明无色液体，它们可用作合成热稳定弹性聚合物的单体。 还公开了所述全氟环己烷-1,4-二酮的二水合物，即八氟-1,1,4,4-环己烷四醇。 本发明的另一方面是通过使全氟环己烷-1,4-二酮与氟化铯和具有2至12个碳原子的环状或非环状脂肪族全卤代烯烃和至少每个碳原子上的氟原子反应而形成的一系列聚醚 所述聚合物具有作为重复单元的所述聚合物，其中R是选自以下的二价基团：-C = C-和-C = C-ANGLE || CnX2n X2y + 1CyCzX2z + 1 WHEREIN X是卤素 选自氟，氯，溴，碘或其相同分子内的任何稳定的组合; N是1到4的整数; Y是0到10的整数; 和Z是从0到（10-Y）的整数。