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公开(公告)号：US09670115B2
公开(公告)日：2017-06-06
申请号：US13396714
申请日：2012-02-15
IPC分类号： C07C7/167 , C07C7/163 , B01J23/50 , C07C7/148 , B01J35/00 , B01J23/46 , B01J35/10 , B01J37/02 , C10G70/00 , C10G70/02
CPC分类号： C07C7/167 , B01J23/462 , B01J23/50 , B01J35/0006 , B01J35/1009 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0201 , C07C7/14841 , C10G70/00 , C10G70/02 , Y02P20/52 , C07C11/04
摘要： A two catalyst system is described having separate catalyst beds for the selective conversion of acetylene to ethylene which reduces the concentration of acetylene, dienes, O2, and NOx is disclosed. An ethylene containing gas stream, such as an off-gas stream from a refinery catalytic cracking unit used in the production of fuels and gas oils, is treated by first contacting the gas stream with a silver catalyst supported on a metal oxide and subsequently contacting the gas stream with a ruthenium catalyst supported on metal oxide. The two catalysts are contained within contiguous continuous reactors or reactor compartments.
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公开(公告)号：US20100048972A1
公开(公告)日：2010-02-25
申请号：US12195678
申请日：2008-08-21
IPC分类号： C07C7/12
CPC分类号： C07C7/167 , B01J23/462 , B01J23/48 , B01J23/60 , B01J23/62 , B01J23/6447 , B01J23/8926 , B01J35/008 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J37/20 , Y02P20/52 , C07C11/04
摘要： A method for purification of ethylene-containing feedstreams from steam crackers or fluid catalytic crackers (FCC), wherein the feedstreams further comprises hydrogen, carbon monoxide, acetylenes, oxygen, nitric oxides, is disclosed. The method comprises contacting an ethylene-comprising gas stream with a Ru-based catalyst at reaction temperatures of at least 120°C. The process results in an ethylene-containing feedstream wherein the ethylene is essentially free of acetylenes, nitric oxides and oxygen. The purifying of the feedstream occurs with minimal loss of ethylene.
摘要翻译： 公开了一种用于从蒸气裂化器或流化催化裂化器（FCC）中纯化含乙烯进料流的方法，其中进料流还包含氢气，一氧化碳，乙炔，氧气，一氧化氮。 该方法包括在至少120℃的反应温度下使含乙烯的气流与Ru-基催化剂接触。 该方法产生含乙烯的进料流，其中乙烯基本上不含乙炔，一氧化氮和氧。 进料流的纯化以最小的乙烯损失发生。
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3.发明申请CATALYST COMPOSITION FOR SELECTIVE HYDROGENATION WITH IMPROVED CHARACTERISTICS 审中-公开具有改进特性的选择性氢化催化剂组合物公开(公告)号：US20130102819A1
公开(公告)日：2013-04-25
申请号：US13276403
申请日：2011-10-19
申请人： Normen Szesni , Alfred Hagemeyer , Frank Grossmann , Richard Fischer , Michael Urbancic , Claus Lugmair , Mingyong Sun , Hongyi C. Hou , David Michael Lowe
发明人： Normen Szesni , Alfred Hagemeyer , Frank Grossmann , Richard Fischer , Michael Urbancic , Claus Lugmair , Mingyong Sun , Hongyi C. Hou , David Michael Lowe
IPC分类号： C07C5/09 , B01J23/50 , B01J23/52 , B01J31/02 , B01J23/62 , B01J23/89 , B01J23/644 , B01J23/58 , B01J23/44 , B01J23/60
CPC分类号： B01J23/44 , B01J21/04 , B01J23/50 , B01J23/52 , B01J23/58 , B01J23/60 , B01J23/62 , B01J23/626 , B01J23/628 , B01J23/6447 , B01J23/8926 , B01J31/0277 , B01J31/0279 , B01J31/0284 , B01J35/008 , B01J35/1009 , B01J35/1038 , B01J37/0201 , B01J37/024 , B01J37/16 , B01J2231/645 , B01J2531/824 , C07C7/167 , C10G45/40 , C10G2400/20 , Y02P20/52 , C07C11/04 , C07C11/06
摘要： This invention relates to heterogeneous catalysts useful for selective hydrogenation of unsaturated hydrocarbons, comprising palladium and optionally a promoter, supported on a substrate, having an uncoated BET surface area of ≦9 m2/g, the surface being coated with an ionic liquid. Also described are methods of making the catalysts and methods of selective hydrogenation of acetylene and/or dienes in front-end mixed olefin feed streams.
摘要翻译： 本发明涉及可用于不饱和烃的选择性氢化的非均相催化剂，其包含负载在基材上的钯和任选的助催化剂，其具有未涂覆的BET表面积为9m 2 / g，该表面用离子液体涂覆。 还描述了制备催化剂的方法和在前端混合烯烃进料流中乙炔和/或二烯烃的选择性氢化的方法。
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公开(公告)号：US20130211162A1
公开(公告)日：2013-08-15
申请号：US13396714
申请日：2012-02-15
CPC分类号： C07C7/167 , B01J23/462 , B01J23/50 , B01J35/0006 , B01J35/1009 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0201 , C07C7/14841 , C10G70/00 , C10G70/02 , Y02P20/52 , C07C11/04
摘要： A two catalyst system is described having separate catalyst beds for the selective conversion of acetylene to ethylene which reduces the concentration of acetylene, dienes, O2, and NOx is disclosed. An ethylene containing gas stream, such as an off-gas stream from a refinery catalytic cracking unit used in the production of fuels and gas oils, is treated by first contacting the gas stream with a silver catalyst supported on a metal oxide and subsequently contacting the gas stream with a ruthenium catalyst supported on metal oxide. The two catalysts are contained within contiguous continuous reactors or reactor compartments.
摘要翻译： 描述了两种催化剂体系，其具有用于乙炔选择性转化为乙烯的单独的催化剂床，其中公开了降低乙炔，二烯，O 2和NO x的浓度。 通过首先使气流与负载在金属氧化物上的银催化剂接触，然后接触含有乙烯的气流，例如来自用于生产燃料和瓦斯油的炼油催化裂化装置的废气流， 气流与钌催化剂负载在金属氧化物上。 两个催化剂包含在连续的连续反应器或反应器隔室内。
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公开(公告)号：US08426660B2
公开(公告)日：2013-04-23
申请号：US12195678
申请日：2008-08-21
IPC分类号： C07C5/08
CPC分类号： C07C7/167 , B01J23/462 , B01J23/48 , B01J23/60 , B01J23/62 , B01J23/6447 , B01J23/8926 , B01J35/008 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J37/20 , Y02P20/52 , C07C11/04
摘要： A method for purification of ethylene-containing feedstreams from steam crackers or fluid catalytic crackers (FCC), wherein the feedstreams further comprises hydrogen, carbon monoxide, acetylenes, oxygen, nitric oxides, is disclosed. The method comprises contacting an ethylene-comprising gas stream with a Ru-based catalyst at reaction temperatures of at least 120°C. The process results in an ethylene-containing feedstream wherein the ethylene is essentially free of acetylenes, nitric oxides and oxygen. The purifying of the feedstream occurs with minimal loss of ethylene.
摘要翻译： 公开了一种用于从蒸气裂化器或流化催化裂化器（FCC）中纯化含乙烯进料流的方法，其中进料流还包含氢气，一氧化碳，乙炔，氧气，一氧化氮。 该方法包括在至少120℃的反应温度下使含乙烯的气流与Ru-基催化剂接触。 该方法产生含乙烯的进料流，其中乙烯基本上不含乙炔，一氧化氮和氧。 进料流的纯化以最小的乙烯损失发生。
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