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公开(公告)号：US06177530B1
公开(公告)日：2001-01-23
申请号：US09432182
申请日：1999-11-02
IPC分类号： C08F13004
CPC分类号： C09D5/165 , C09D4/00 , C08F230/04 , C08F220/18
摘要： An antifouling paint composition comprising, as a vehicle, a copolymer from a monomer mixture comprising of (a1) a metal-containing polymerizable monomer having two unsaturated groups and (a2) a metal-containing polymerizable monomer represented by the following formula (I): wherein R1 represents a hydrogen atom or a methyl group; M represents Mg, Zn or Cu; and R2 represents an organic acid residue. An antifouling paint composition comprising, as a vehicle, a copolymer from a monomer mixture comprising (a) a metal-containing polymerizable monomer and (b) a polymerizable monomer represented by the following formula (II): wherein R3 reprsents a hydrogen atom or a methyl group; R4 represents an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group or a phenyl group; and R5 represents an alkyl having 1 to 10 carbon atoms, a cycloalkyl group or a phenyl group.
摘要翻译： 一种防污涂料组合物，其包含作为载体的共聚物，该单体混合物包含（a1）具有两个不饱和基团的含金属的可聚合单体和（a2）由下式（I）表示的含金属的可聚合单体： 其中R1表示氢原子或甲基; M表示Mg，Zn或Cu; R2表示有机酸残基。 一种防污涂料组合物，其包含作为载体的共聚物，所述单体混合物包含（a）含金属的可聚合单体和（b）由下式（II）表示的可聚合单体：其中R 3表示氢原子或 甲基; R4表示碳原子数1〜10的烷基，环烷基或苯基。 R 5表示碳原子数1〜10的烷基，环烷基或苯基。
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公开(公告)号：US07928175B2
公开(公告)日：2011-04-19
申请号：US10548638
申请日：2004-03-12
IPC分类号： C09D153/00
CPC分类号： C09D143/04 , C09D5/165 , C09D5/1668 , Y10T428/31663
摘要： An object of the present invention is to provide an antifouling paint composition which shows an excellent antifouling effect in seawater for a long period of time, and has excellent adhesion and recoating properties to a substrate. The present invention relates to an antifouling pain composition comprising a copolymer which is obtained by polymerizing a monomer mixture comprising silicon-containing polymerizable monomer (a) having two (meth)acryl end groups, and which contains bivalent metal atom. The copolymer is also obtained by polymerizing a monomer mixture comprising silicon-containing polymerizable monomer (b) having one (meth)acryl end group, and metal atom containing polymerizable monomer (c,) having two unsaturated groups and metal atom selected from Mg, Zn, and Cu.
摘要翻译： 本发明的目的是提供一种防污涂料组合物，其在海水中长时间显示出优异的防污效果，并且对基材具有优异的粘附性和重涂性。 本发明涉及一种防污性疼痛组合物，其包含通过聚合包含含有两个（甲基）丙烯酸端基的含硅可聚合单体（a）并且含有二价金属原子的单体混合物而获得的共聚物。 共聚物也可以通过聚合包含具有一个（甲基）丙烯酸端基的含硅可聚合单体（b）和含有两个不饱和基团的金属原子的可聚合单体（c））和选自Mg，Zn ，和Cu。
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公开(公告)号：US20060258772A1
公开(公告)日：2006-11-16
申请号：US10548638
申请日：2004-03-12
IPC分类号： C09D5/16
CPC分类号： C09D143/04 , C09D5/165 , C09D5/1668 , Y10T428/31663
摘要： An object of the present invention is to provide an antifouling paint composition which shows an excellent antifouling effect in seawater for a long period of time, and has excellent adhesion and recoating properties to a substrate. The present invention relates to an antifouling pain composition comprising a copolymer which is obtained by polymerizing a monomer mixture comprising silicon-containing polymerizable monomer (a) having two (meth)acryl end groups, and which contains bivalent metal atom. The copolymer is also obtained by polymerizing a monomer mixture comprising silicon-containing polymerizable monomer (b) having one (meth)acryl end group, and metal atom containing polymerizable monomer (c1) having two unsaturated groups and metal atom selected from Mg, Zn, and Cu.
摘要翻译： 本发明的目的是提供一种防污涂料组合物，其在海水中长时间显示出优异的防污效果，并且对基材具有优异的粘附性和重涂性。 本发明涉及一种防污性疼痛组合物，其包含通过聚合包含含有两个（甲基）丙烯酸端基的含硅可聚合单体（a）并且含有二价金属原子的单体混合物而获得的共聚物。 共聚物也可以通过聚合包含具有一个（甲基）丙烯酸端基的含硅可聚合单体（b）和含有两个不饱和基团的可聚合单体（c 1 H 1）的金属原子的单体混合物而获得， 选自Mg，Zn和Cu的金属原子。
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4.发明授权Metal-containing monomer dissolved mixture, metal-containing resin and antifouling paint composition 有权含金属单体溶解的混合物，含金属的树脂和防污涂料组合物公开(公告)号：US06727304B2
公开(公告)日：2004-04-27
申请号：US09886111
申请日：2001-06-22
IPC分类号： C08K536
CPC分类号： C08F30/04 , C08F230/04 , C09D5/165 , C08F220/06
摘要： A metal-containing monomer dissolved mixture comprising a reaction product of an inorganic metal compound with a carboxyl group-containing radical polymerizable monomer, an organic solvent including at least an alcohol-based solvent, and water, wherein the water content is from 0.01 to 30% by weight; a metal-containing resin obtained by copolymerizing the metal-containing monomer (A) in this dissolved mixture with the other radical-polymerizable unsaturated monomer (B); an antifouling paint composition obtained by using this metal-containing resin; and an antifouling paint composition comprising a divalent metal-containing resin (C), a compound (D) of R1—SH (wherein, R1 represents an organic group having 1 to 30 carbon atoms.), and copper oxide (E), are disclosed.
摘要翻译： 一种含金属的单体溶解的混合物，其包含无机金属化合物与含羧基的自由基聚合性单体的反应产物，至少包含醇系溶剂的有机溶剂和水，其中水含量为0.01〜30 重量％ 通过使该溶解的混合物中的含金属单体（A）与其他自由基聚合性不饱和单体（B）共聚而得到的含金属树脂; 通过使用该含金属树脂得到的防污涂料组合物; 和含有二价金属的树脂（C），R 1 -SH的化合物（D）（其中，R 1表示碳原子数为1〜30的有机基团）的防污涂料组合物，铜 氧化物（E）。
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公开(公告)号：US5652067A
公开(公告)日：1997-07-29
申请号：US99556
申请日：1993-07-30
CPC分类号： H05B33/26 , H01L51/5048 , H01L51/5231 , H01L51/524 , H01L51/5253 , H05B33/04 , H05B33/12 , H05B33/14 , Y10S428/917
摘要： In an organic electroluminescent device including a substrate and formed thereon a multilayered structure successively having at least an anode layer, an organic electroluminescent layer and a cathode layer, a sealing layer having at least one compound selected from the group consisting of a metal oxide, a metal fluoride and a metal sulfide is further provided on the electrode layer formed later. A hole injecting and transporting layer is preferably provided between the anode layer and the organic electroluminescent layer. An electron injecting and transporting layer may also be provided between the organic electroluminescent layer and the cathode layer. At least one layer of the hole injecting and transporting layer, organic electroluminescent layer and electron injecting and transporting layer may be formed of a polyphosphazene compound or a polyether compound or a polyphosphate compound having an aromatic tertiary amine group in its main chain.
摘要翻译： 在包括衬底并在其上形成有依次具有至少阳极层，有机电致发光层和阴极层的多层结构的有机电致发光器件中，具有至少一种选自金属氧化物， 金属氟化物和金属硫化物进一步设置在稍后形成的电极层上。 优选在阳极层和有机电致发光层之间设置空穴注入传输层。 还可以在有机电致发光层和阴极层之间设置电子注入和传输层。 空穴注入输送层，有机电致发光层和电子注入输送层的至少一层可以在其主链中由聚磷腈化合物或聚醚化合物或具有芳香族叔胺基团的多磷酸化合物形成。
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