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1.发明授权Metal-containing monomer dissolved mixture, metal-containing resin and antifouling paint composition 有权含金属单体溶解的混合物，含金属的树脂和防污涂料组合物公开(公告)号：US06727304B2
公开(公告)日：2004-04-27
申请号：US09886111
申请日：2001-06-22
IPC分类号： C08K536
CPC分类号： C08F30/04 , C08F230/04 , C09D5/165 , C08F220/06
摘要： A metal-containing monomer dissolved mixture comprising a reaction product of an inorganic metal compound with a carboxyl group-containing radical polymerizable monomer, an organic solvent including at least an alcohol-based solvent, and water, wherein the water content is from 0.01 to 30% by weight; a metal-containing resin obtained by copolymerizing the metal-containing monomer (A) in this dissolved mixture with the other radical-polymerizable unsaturated monomer (B); an antifouling paint composition obtained by using this metal-containing resin; and an antifouling paint composition comprising a divalent metal-containing resin (C), a compound (D) of R1—SH (wherein, R1 represents an organic group having 1 to 30 carbon atoms.), and copper oxide (E), are disclosed.
摘要翻译： 一种含金属的单体溶解的混合物，其包含无机金属化合物与含羧基的自由基聚合性单体的反应产物，至少包含醇系溶剂的有机溶剂和水，其中水含量为0.01〜30 重量％ 通过使该溶解的混合物中的含金属单体（A）与其他自由基聚合性不饱和单体（B）共聚而得到的含金属树脂; 通过使用该含金属树脂得到的防污涂料组合物; 和含有二价金属的树脂（C），R 1 -SH的化合物（D）（其中，R 1表示碳原子数为1〜30的有机基团）的防污涂料组合物，铜 氧化物（E）。
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公开(公告)号：US07928175B2
公开(公告)日：2011-04-19
申请号：US10548638
申请日：2004-03-12
IPC分类号： C09D153/00
CPC分类号： C09D143/04 , C09D5/165 , C09D5/1668 , Y10T428/31663
摘要： An object of the present invention is to provide an antifouling paint composition which shows an excellent antifouling effect in seawater for a long period of time, and has excellent adhesion and recoating properties to a substrate. The present invention relates to an antifouling pain composition comprising a copolymer which is obtained by polymerizing a monomer mixture comprising silicon-containing polymerizable monomer (a) having two (meth)acryl end groups, and which contains bivalent metal atom. The copolymer is also obtained by polymerizing a monomer mixture comprising silicon-containing polymerizable monomer (b) having one (meth)acryl end group, and metal atom containing polymerizable monomer (c,) having two unsaturated groups and metal atom selected from Mg, Zn, and Cu.
摘要翻译： 本发明的目的是提供一种防污涂料组合物，其在海水中长时间显示出优异的防污效果，并且对基材具有优异的粘附性和重涂性。 本发明涉及一种防污性疼痛组合物，其包含通过聚合包含含有两个（甲基）丙烯酸端基的含硅可聚合单体（a）并且含有二价金属原子的单体混合物而获得的共聚物。 共聚物也可以通过聚合包含具有一个（甲基）丙烯酸端基的含硅可聚合单体（b）和含有两个不饱和基团的金属原子的可聚合单体（c））和选自Mg，Zn ，和Cu。
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公开(公告)号：US20060258772A1
公开(公告)日：2006-11-16
申请号：US10548638
申请日：2004-03-12
IPC分类号： C09D5/16
CPC分类号： C09D143/04 , C09D5/165 , C09D5/1668 , Y10T428/31663
摘要： An object of the present invention is to provide an antifouling paint composition which shows an excellent antifouling effect in seawater for a long period of time, and has excellent adhesion and recoating properties to a substrate. The present invention relates to an antifouling pain composition comprising a copolymer which is obtained by polymerizing a monomer mixture comprising silicon-containing polymerizable monomer (a) having two (meth)acryl end groups, and which contains bivalent metal atom. The copolymer is also obtained by polymerizing a monomer mixture comprising silicon-containing polymerizable monomer (b) having one (meth)acryl end group, and metal atom containing polymerizable monomer (c1) having two unsaturated groups and metal atom selected from Mg, Zn, and Cu.
摘要翻译： 本发明的目的是提供一种防污涂料组合物，其在海水中长时间显示出优异的防污效果，并且对基材具有优异的粘附性和重涂性。 本发明涉及一种防污性疼痛组合物，其包含通过聚合包含含有两个（甲基）丙烯酸端基的含硅可聚合单体（a）并且含有二价金属原子的单体混合物而获得的共聚物。 共聚物也可以通过聚合包含具有一个（甲基）丙烯酸端基的含硅可聚合单体（b）和含有两个不饱和基团的可聚合单体（c 1 H 1）的金属原子的单体混合物而获得， 选自Mg，Zn和Cu的金属原子。
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公开(公告)号：US06177530B1
公开(公告)日：2001-01-23
申请号：US09432182
申请日：1999-11-02
IPC分类号： C08F13004
CPC分类号： C09D5/165 , C09D4/00 , C08F230/04 , C08F220/18
摘要： An antifouling paint composition comprising, as a vehicle, a copolymer from a monomer mixture comprising of (a1) a metal-containing polymerizable monomer having two unsaturated groups and (a2) a metal-containing polymerizable monomer represented by the following formula (I): wherein R1 represents a hydrogen atom or a methyl group; M represents Mg, Zn or Cu; and R2 represents an organic acid residue. An antifouling paint composition comprising, as a vehicle, a copolymer from a monomer mixture comprising (a) a metal-containing polymerizable monomer and (b) a polymerizable monomer represented by the following formula (II): wherein R3 reprsents a hydrogen atom or a methyl group; R4 represents an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group or a phenyl group; and R5 represents an alkyl having 1 to 10 carbon atoms, a cycloalkyl group or a phenyl group.
摘要翻译： 一种防污涂料组合物，其包含作为载体的共聚物，该单体混合物包含（a1）具有两个不饱和基团的含金属的可聚合单体和（a2）由下式（I）表示的含金属的可聚合单体： 其中R1表示氢原子或甲基; M表示Mg，Zn或Cu; R2表示有机酸残基。 一种防污涂料组合物，其包含作为载体的共聚物，所述单体混合物包含（a）含金属的可聚合单体和（b）由下式（II）表示的可聚合单体：其中R 3表示氢原子或 甲基; R4表示碳原子数1〜10的烷基，环烷基或苯基。 R 5表示碳原子数1〜10的烷基，环烷基或苯基。
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公开(公告)号：US6037416A
公开(公告)日：2000-03-14
申请号：US11062
申请日：1998-02-10
申请人： Akio Iwamoto , Takeshi Kato , Shinobu Fujie , Kazuhiko Hotta , Kunio Iwase , Hiroshi Takeuchi
发明人： Akio Iwamoto , Takeshi Kato , Shinobu Fujie , Kazuhiko Hotta , Kunio Iwase , Hiroshi Takeuchi
IPC分类号： C08L33/06 , C09D133/06 , C08L33/14 , C08L25/14
CPC分类号： C09D133/064 , C09D133/068 , C08L33/064 , C08L33/068
摘要： A thermosetting coating composition comprising an acrylic copolymer (A) containing vinyl monomer units each having an .alpha.,.beta.-dicarboxylic acid anhydride group and vinyl monomer units each having an .alpha.,.beta.-dicarboxylic monoester group in a total amount of 5-40 wt % and containing the vinyl monomer units with .alpha.,.beta.-dicarboxylic acid anhydride groups at 0.3-5 wt %, and an acrylic copolymer (B) with epoxy groups.
摘要翻译： PCT No.PCT / JP95 / 01604 Sec。 371日期1998年2月10日 102（e）1998年2月10日日期PCT提交1995年8月10日PCT公布。 出版物WO97 / 06216 日期1997年2月20日一种包含含有各自具有α，β-二羧酸酐基团的乙烯基单体单元的丙烯酸共聚物（A）和各自具有α，β-二羧酸单酯基团的乙烯基单体单元的热固性涂料组合物，其总量为 5-40重量％，并且含有0.3-5重量％的α，β-二羧酸酐基团的乙烯基单体单元和具有环氧基团的丙烯酸共聚物（B）。
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公开(公告)号：US5064695A
公开(公告)日：1991-11-12
申请号：US580969
申请日：1990-09-12
申请人： Kazuhiko Hotta , Koichiro Kido , Shogo Yamamoto
发明人： Kazuhiko Hotta , Koichiro Kido , Shogo Yamamoto
CPC分类号： B05D7/532 , C08G18/6254 , C08G18/6279 , C09D133/066 , B05D2201/02 , B05D2401/10 , B05D2502/00 , B05D2506/10 , C08L75/04
摘要： A method for forming a coating film is here disclosed which comprises the steps of coating a member with a coating material containing a pigment for a thermosetting base coat, overcoating the coated member with a coating material for a thermosetting clear coat in a wet-on-wet coating manner, and then thermosetting the uncured coating films simultaneously;a binder component in the coating material for the base coat comprising50 to 90% by weight of an acrylic copolymer having a hydroxyl value of from 40 to 80 mg KOH/g and an acid value of from 0.5 to 30 mg KOH/g and a glass transition temperature of from -40.degree. to 20.degree. C. which is obtained by copolymerizing 10 to 40% by weight of a hydroxyl group-containing (meth)acrylic ester, 0.2 to 10% by weight of a carboxyl group-containing vinyl monomer, 30 to 89.8% by weight of a (meth)acrylic ester and 0 to 30% by weight of another vinyl monomer, and10 to 50% by weight of a curing agent;a binder component in the coating material for the clear coat comprisingan acrylic copolymer having a hydroxyl value of from 50 to 180 mg KOH/g, an acid value of from 2 to 40 mg KOH/g and a glass transition temperature of from -40.degree. to 20.degree. C. which is obtained by copolymerizing5 to 60% by weight of a fluorine-containing (meth)-acrylic ester, 10 to 60% by weight of a hydroxyl group-containing (meth)acrylic ester, 0.2 to 10% by weight of a vinyl monomer containing an acidic group, 15 to 70% by weight of a (meth)acrylic ester and 5 to 50% by weight of another vinyl monomer, anda polyisocyanate compound;a ratio X/Y of an equivalent (X) of the OH group present in the acrylic copolymer to an equivalent (Y) of the NCO group in the polyisocyanate compound being in the range of from 1/0.5 to 1/1.5.
摘要翻译： 这里公开了一种形成涂膜的方法，其包括以下步骤：用含有用于热固性基底涂层的颜料的涂层材料涂覆部件，用涂覆材料涂覆用于热固性透明涂层的涂层材料， 湿法涂布，然后同时热固未固化涂膜; 用于底涂层的涂料中的粘合剂组分包含羟基值为40至80mg KOH / g，酸值为0.5至30mg KOH / g的丙烯酸共聚物的50至90重量％，和 通过共聚10〜40重量％的含羟基的（甲基）丙烯酸酯，0.2〜10重量％的含羧基的乙烯基单体得到的玻璃化转变温度为-40〜20℃ ，30〜89.8重量％的（甲基）丙烯酸酯和0〜30重量％的其它乙烯基单体，10〜50重量％的固化剂; 用于透明涂层的涂料中的粘合剂组分包括羟值为50至180mg KOH / g，酸值为2至40mg KOH / g和玻璃化转变温度为-40℃的丙烯酸共聚物 通过使5〜60重量％的含氟（甲基）丙烯酸酯，10〜60重量％的含羟基的（甲基）丙烯酸酯，0.2〜10重量％ 含有酸性基团的乙烯基单体的重量％，（甲基）丙烯酸酯15〜70重量％，其它乙烯基单体5〜50重量％，多异氰酸酯化合物; 存在于丙烯酸类共聚物中的OH基当量（X）与多异氰酸酯化合物中的NCO基的当量（Y）的比X / Y为1 / 0.5〜1 / 1.5。
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公开(公告)号：US4741932A
公开(公告)日：1988-05-03
申请号：US68808
申请日：1987-06-30
IPC分类号： C08L61/20 , C09D133/06 , B05D3/02
CPC分类号： C09D133/066 , C08L61/20
摘要： A coating composition comprising (A) 100 parts by weight of an acrylic copolymer and (B) from 0 to 40 parts by weight of a curing agent, wherein said acrylic copolymer is a copolymer of a monomer mixture composed essentially of:(1) from 1 to 50% by weight of 1,4-butanediol mono(meth)acrylate,(2) from 0.2 to 10% by weight of an .alpha.,.beta.-monoethylenic unsaturated carboxylic acid, and(3) from 40 to 98.8% by weight of other copolymerizable monomers,provided that the total of the 1,4-butanediol mono(meth)acrylate and hydroxyl group-containing monomers in the copolymerizable monomers, is not more than 50% by weight of the monomer mixture.
摘要翻译： 一种涂料组合物，其包含（A）100重量份的丙烯酸共聚物和（B）0-40重量份的固化剂，其中所述丙烯酸共聚物是基本上由以下组成的单体混合物的共聚物：（1） 1〜50重量％的1,4-丁二醇单（甲基）丙烯酸酯，（2）0.2〜10重量％的α，β-单亚乙烯基不饱和羧酸，（3）40〜98.8重量％ 的其它可共聚单体，只要共聚单体中的1,4-丁二醇单（甲基）丙烯酸酯和含羟基的单体的总量不超过单体混合物的50重量％。
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公开(公告)号：US5459944A
公开(公告)日：1995-10-24
申请号：US110803
申请日：1993-08-23
申请人： Toshio Tatsutani , Tetsuya Tanaka , Toshihiko Horii , Kazuhiko Hotta , Keiu Kawasaki , Keiichi Hasegawa , Yoshiyuki Umai , Masaaki Sendo
发明人： Toshio Tatsutani , Tetsuya Tanaka , Toshihiko Horii , Kazuhiko Hotta , Keiu Kawasaki , Keiichi Hasegawa , Yoshiyuki Umai , Masaaki Sendo
CPC分类号： A47K10/48
摘要： A hand dryer in which a channel-like hand insertion unit 5 opening at the front face and side faces is formed in the front face of a case 6 which functions as an outer shell. Upper and lower blowout nozzles 32 and 33 are disposed in the upper and lower faces of the hand insertion unit 5. A high-pressure air flow generation device 7 supplies high-pressure air flow to the blowout nozzles 32 and 33. A high-speed wind generated in the hand insertion unit 5 blows water on hands to the inner portion of the hand insertion unit 5. The blown water is drained to the outside of the hand insertion unit 5, through drainage holes 18 which are disposed at lateral ends of the bottom face of the hand insertion unit 5. Thereby, the blown water from the hands can be smoothly drained without remaining in the hand insertion unit.
摘要翻译： 在作为外壳的壳体6的前面形成有在前面和侧面开口的通道状的手插入单元5的手动干燥机。 上下喷孔32和33设置在手插入单元5的上表面和下表面中。高压空气流产生装置7向吹出喷嘴32和33提供高压空气流。高速气流 在手插入单元5中产生的风将手上的水吹到手插入单元5的内部。吹出的水通过设置在手插入单元5的外侧的排水孔18排出到手插入单元5的外部。 因此，能够平稳地排出来自手的吹出水，而不会残留在手插入单元中。
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