公开(公告)号：US20090030093A1

公开(公告)日：2009-01-29

申请号：US12180957

申请日：2008-07-28

申请人： Mubarik Mahmood Chowdhry ,  Xavier Sava ,  Monica Haag ,  Jacob Wildeson ,  Stefan Mecking ,  Ludmila Kolb

发明人： Mubarik Mahmood Chowdhry ,  Xavier Sava ,  Monica Haag ,  Jacob Wildeson ,  Stefan Mecking ,  Ludmila Kolb

IPC分类号： A61K47/32 ,  C08G61/04 ,  C08F4/06

CPC分类号： C08F110/02 ,  C08F2/22 ,  C08F4/80

摘要： Process for the emulsion polymerization of one or more olefins by reacting a quinoid compound with a metal compound and a phosphine compound which is substituted by at least one polar radical and subsequently using the reaction product for the polymerization or copolymerization of olefins in water or in a solvent mixture which contains at least 50% by weight of water and at least one emulsifier.

摘要翻译： 通过使喹啉化合物与金属化合物反应并被至少一个极性基团取代的膦化合物反应并随后使用反应产物在烯烃在水中或在水中的聚合或共聚来使一种或多种烯烃乳液聚合的方法 溶剂混合物，其含有至少50重量％的水和至少一种乳化剂。

公开(公告)号：US06800699B2

公开(公告)日：2004-10-05

申请号：US10015752

申请日：2001-12-17

申请人： Markus Schmid ,  Mubarik Mahmood Chowdhry ,  Marc Oliver Kristen ,  Stefan Mecking ,  Florian M. Bauers

发明人： Markus Schmid ,  Mubarik Mahmood Chowdhry ,  Marc Oliver Kristen ,  Stefan Mecking ,  Florian M. Bauers

IPC分类号： C08F444

CPC分类号： C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08K5/0091 ,  C08F4/74 ,  C08F2/32 ,  C08F2500/03

摘要： Process for the production of aqueous polymer dispersions by reaction of one or more olefinically unsaturated compounds in aqueous medium in the presence of a complex compound which possesses the structural element Y—M—E, E standing for nitrogen, M for a transition metal of groups 7 to 10 of the periodic system of the elements and Y for oxygen, sulfur, nitrogen or phosphorus, and which possesses no hydrophilic groups in its ligand system.

摘要翻译： 通过一种或多种烯属不饱和化合物在水性介质中在配位化合物存在下反应生产含水聚合物分散体的方法，所述络合化合物具有结构元素YME，E代表氮，M代表7至10族的过渡金属 元素的周期性系统，Y为氧，硫，氮或磷，并且在其配体体系中不具有亲水基团。

公开(公告)号：US07417098B2

公开(公告)日：2008-08-26

申请号：US10579098

申请日：2004-11-06

申请人： Mubarik Mahmood Chowdhry ,  Xavier Sava ,  Monica Haag ,  Jacob Wildeson ,  Stefan Mecking ,  Ludmila Kolb

发明人： Mubarik Mahmood Chowdhry ,  Xavier Sava ,  Monica Haag ,  Jacob Wildeson ,  Stefan Mecking ,  Ludmila Kolb

IPC分类号： C08F4/42

CPC分类号： C08F110/02 ,  C08F2/22 ,  C08F4/80

摘要： Process for the emulsion polymerization of one or more olefins by reacting a quinoid compound with a metal compound and a phosphine compound which is substituted by at least one polar radical and subsequently using the reaction product for the polymerization or copolymerization of olefins in water or in a solvent mixture which contains at least 50% by weight of water and at least one emulsifier.

摘要翻译： 通过使喹啉化合物与金属化合物反应并被至少一个极性基团取代的膦化合物反应并随后使用反应产物在烯烃在水中或在水中的聚合或共聚来使一种或多种烯烃乳液聚合的方法 溶剂混合物，其含有至少50重量％的水和至少一种乳化剂。

公开(公告)号：US07332565B2

公开(公告)日：2008-02-19

申请号：US10552994

申请日：2004-04-13

申请人： Mubarik Mahmood Chowdhry ,  Wolfgang Gaschler

发明人： Mubarik Mahmood Chowdhry ,  Wolfgang Gaschler

IPC分类号： C08F6/00

CPC分类号： C08F6/006

摘要： A method for reducing the amount of residual monomer in aqueous polymer dispersions by aftertreatment with an initiator system comprises aftertreating the aqueous polymer dispersion with addition of an initiator system essentially comprising a) from 0.001 to 5% by weight, based on the total monomer amount used to prepare the polymer dispersion, of an inorganic salt of persulfuric acid, b) from 0.005 to 5% by weight, based on the total monomer amount used to prepare the polymer dispersion, of a methyl ketone, and c) optionally, catalytic amounts of a metal ion which is able to exist in a plurality of valence states.

摘要翻译： 通过用引发剂体系进行后处理来减少聚合物水分散体中的残余单体的量的方法包括：通过加入引发剂体系对聚合物水分散体进行后处理，该引发剂体系基本上包含a）基于所用总单体量的0.001至5重量％ 制备聚合物分散体，过硫酸的无机盐，b）基于用于制备聚合物分散体的总单体量为0.005-5重量％的甲基酮，和c）任选的催化量的 能够以多个价态存在的金属离子。

公开(公告)号：US08293825B2

公开(公告)日：2012-10-23

申请号：US12922983

申请日：2009-03-20

申请人： Alexandre Terrenoire ,  Chris Titmarsh ,  Hideki Yamashita ,  Chee Seng Yong ,  Mubarik Mahmood Chowdhry ,  Mun Hoe Stanley Kwan ,  Jonathan Allen

发明人： Alexandre Terrenoire ,  Chris Titmarsh ,  Hideki Yamashita ,  Chee Seng Yong ,  Mubarik Mahmood Chowdhry ,  Mun Hoe Stanley Kwan ,  Jonathan Allen

IPC分类号： C08K5/521

CPC分类号： C09D143/02 ,  C08F220/18 ,  C08F230/02 ,  C08K5/521 ,  C09D4/00

摘要： The present invention relates to the use of a polymer dispersion (PD) comprising at least one polymer (P), obtainable by free-radical emulsion polymerization of at least one ethylenically unsaturated monomer (M1) and at least one monomer (M2) different therefrom and selected from esters of phosphonic acid or of phosphoric acid with unalkoxylated or alkoxylated hydroxyalkyl(meth)acrylates, and at least one emulsifier (E) selected from phosphoric esters with unalkoxylated or alkoxylated C8-C30 alkanols, and their salts, in coating materials to improve the scrub resistance of the coatings produced therefrom and/or to improve the burnish resistance of the coatings produced therefrom and/or to improve the stain resistance of the coatings produced therefrom and/or to improve the pigment distribution in the coatings produced therefrom and/or to reduce the emission of volatile organic compounds by the coatings produced therefrom, to polymer dispersions used in accordance with the invention, and to coating materials comprising the polymer dispersions of the invention.

摘要翻译： 本发明涉及包含至少一种聚合物（P）的聚合物分散体（PD）的用途，所述聚合物（P）可通过至少一种烯属不饱和单体（M1）和至少一种不同于其的烯属不饱和单体（M2）的自由基乳液聚合而获得 并选自膦酸或磷酸与未烷氧基化或烷氧基化羟基烷基（甲基）丙烯酸酯的酯，和至少一种选自具有非烷氧基化或烷氧基化的C 8 -C 30链烷醇的磷酸酯及其盐的乳化剂（E） 提高由其制备的涂料的耐擦洗性和/或提高由其制备的涂料的耐光泽性和/或改善由其制备的涂料的耐污染性和/或改善由其制备的涂料中的颜料分布和/ 或者通过由其制备的涂层来减少挥发性有机化合物的排放，以减少根据本发明使用的聚合物分散体 d涂覆包含本发明聚合物分散体的材料。

公开(公告)号：US08013085B2

公开(公告)日：2011-09-06

申请号：US10558743

申请日：2004-06-04

申请人： Markus Schmid ,  Mubarik Mahmood Chowdhry ,  Dieter Distler ,  Reinhold J. Leyrer

发明人： Markus Schmid ,  Mubarik Mahmood Chowdhry ,  Dieter Distler ,  Reinhold J. Leyrer

IPC分类号： C08F2/16

CPC分类号： C08F291/00 ,  C08F295/00

摘要： Process for preparing an aqueous polymer dispersion by polymerizing at least one ethylenically unsaturated monomer B in an aqueous medium in the presence of polymer particles A and at least one dispersant.

摘要翻译： 通过在聚合物颗粒A和至少一种分散剂的存在下在水性介质中聚合至少一种烯属不饱和单体B来制备聚合物水分散体的方法。

公开(公告)号：US20110009540A1

公开(公告)日：2011-01-13

申请号：US12922983

申请日：2009-03-20

申请人： Alexandre Terrenoire ,  Chris Titmarsh ,  Hideki Yamashita ,  Chee Seng Yong ,  Mubarik Mahmood Chowdhry ,  Mun Hoe Stanley Kwan ,  Jonathan Allen

发明人： Alexandre Terrenoire ,  Chris Titmarsh ,  Hideki Yamashita ,  Chee Seng Yong ,  Mubarik Mahmood Chowdhry ,  Mun Hoe Stanley Kwan ,  Jonathan Allen

IPC分类号： C08K5/521

CPC分类号： C09D143/02 ,  C08F220/18 ,  C08F230/02 ,  C08K5/521 ,  C09D4/00

摘要： The present invention relates to the use of a polymer dispersion (PD) comprising at least one polymer (P), obtainable by free-radical emulsion polymerization of at least one ethylenically unsaturated monomer (M1) and at least one monomer (M2) different therefrom and selected from esters of phosphonic acid or of phosphoric acid with unalkoxylated or alkoxylated hydroxyalkyl (meth)acrylates, and at least one emulsifier (E) selected from phosphoric esters with unalkoxylated or alkoxylated C8-C30 alkanols, and their salts, in coating materials to improve the scrub resistance of the coatings produced therefrom and/or to improve the burnish resistance of the coatings produced therefrom and/or to improve the stain resistance of the coatings produced therefrom and/or to improve the pigment distribution in the coatings produced therefrom and/or to reduce the emission of volatile organic compounds by the coatings produced therefrom, to polymer dispersions used in accordance with the invention, and to coating materials comprising the polymer dispersions of the invention.

摘要翻译： 本发明涉及包含至少一种聚合物（P）的聚合物分散体（PD）的用途，所述聚合物（P）可通过至少一种烯属不饱和单体（M1）和至少一种不同于其的烯属不饱和单体（M2）的自由基乳液聚合而获得 并选自膦酸或磷酸与未烷氧基化或烷氧基化羟基烷基（甲基）丙烯酸酯的酯，和至少一种选自具有非烷氧基化或烷氧基化的C 8 -C 30链烷醇的磷酸酯及其盐的乳化剂（E） 提高由其制备的涂料的耐擦洗性和/或提高由其制备的涂料的耐光泽性和/或改善由其制备的涂料的耐污染性和/或改善由其制备的涂料中的颜料分布和/ 或通过由其制备的涂层来减少挥发性有机化合物的排放，以减少根据本发明使用的聚合物分散体 和包含本发明的聚合物分散体的涂料。

公开(公告)号：US07462673B2

公开(公告)日：2008-12-09

申请号：US10556605

申请日：2004-05-06

申请人： Markus Schmid ,  Mubarik Mahmood Chowdhry ,  Peter Preishuber-Pfluegl ,  Xavier Sava ,  Ekkehard Lindner ,  Mahmoud Sunjuk ,  Peter Wegner

发明人： Markus Schmid ,  Mubarik Mahmood Chowdhry ,  Peter Preishuber-Pfluegl ,  Xavier Sava ,  Ekkehard Lindner ,  Mahmoud Sunjuk ,  Peter Wegner

IPC分类号： C08F4/26

CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F2/18 ,  C08F4/7016

摘要： Process for preparing an aqueous polymer dispersion by polymerization of at least one olefinically unsaturated compound in an aqueous medium in the presence of at least one dispersant and a solid polymerization catalyst.

摘要翻译： 在至少一种分散剂和固体聚合催化剂的存在下，通过在水介质中聚合至少一种烯属不饱和化合物来制备聚合物水分散体的方法。

公开(公告)号：US07750096B2

公开(公告)日：2010-07-06

申请号：US10566653

申请日：2004-07-08

申请人： Mubarik Mahmood Chowdhry ,  Ulrich Nieken ,  Monica Haag

发明人： Mubarik Mahmood Chowdhry ,  Ulrich Nieken ,  Monica Haag

IPC分类号： C08F4/42 ,  C08F4/06

CPC分类号： C08F10/00 ,  C08F4/80 ,  C08F2/24

摘要： An aqueous polymer dispersion is prepared by reacting at least one olefin in the presence of at least one polymerization catalyst and one emulsifier in an aqueous medium by a process wherein the polymerization catalyst is prepared in an in situ reaction by reacting the ligand compound 2,6-dichloro-para-benzoquinone (Ia) and/or 2,3,6-trichloro-para-benzoquinone (Ib) with a phosphine compound or diphosphine compound and with a metal compound and the polymerization reaction is effected in an aqueous medium.

摘要翻译： 水性聚合物分散体是通过使至少一种烯烃在至少一种聚合催化剂和一种乳化剂存在下在水性介质中通过其中聚合催化剂在原位反应中通过使配体化合物2,6 （Ia）和/或2,3,6-三氯 - 对苯醌（Ib）与膦化合物或二膦化合物和金属化合物反应，聚合反应在水性介质中进行。

公开(公告)号：US07566760B2

公开(公告)日：2009-07-28

申请号：US10524216

申请日：2003-07-24

申请人： Mubarik Mahmood Chowdhry ,  Markus Schmid ,  Peter Preishuber-Pfluegl ,  Xavier Sava ,  Horst Weiss ,  Stefan Mecking ,  Martin Zuideveld ,  Florian M. Bauers

发明人： Mubarik Mahmood Chowdhry ,  Markus Schmid ,  Peter Preishuber-Pfluegl ,  Xavier Sava ,  Horst Weiss ,  Stefan Mecking ,  Martin Zuideveld ,  Florian M. Bauers

IPC分类号： C08F4/26 ,  C08F4/70 ,  C08F2/22

CPC分类号： C08F110/02 ,  C08F4/80 ,  C08F2/24

摘要： The invention relates to a method for the production of aqueous polymer dispersions, by the polymerisation of one or more olefins in aqueous media in the presence of dispersing agents and optionally organic solvents, characterised in that the polymerisation of the olefin(s) is catalysed by means of one or more complex compounds of general formula (I), where at least one of the groups R1 to R9 must be in the form of a group of the following general formula (II) where Z=an electron-withdrawing group and n=a whole number from 1 to 5.

摘要翻译： 本发明涉及通过在分散剂和任选的有机溶剂的存在下在水性介质中聚合一种或多种烯烃的方法来制备聚合物水分散体，其特征在于烯烃的聚合由 一种或多种通式（I）的络合物的手段，其中基团R 1至R 9中的至少一个必须为以下通式（II）的基团的形式，其中Z =吸电子基团和n =从1到5的整数。