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    Polymer dispersions containing phosphorous polymers and emulsifiers
    5.
    发明授权
    Polymer dispersions containing phosphorous polymers and emulsifiers 有权
    含有聚合物和乳化剂的聚合物分散体

    公开(公告)号：US08293825B2

    公开(公告)日：2012-10-23

    申请号：US12922983

    申请日：2009-03-20

    申请人： Alexandre Terrenoire ,  Chris Titmarsh ,  Hideki Yamashita ,  Chee Seng Yong ,  Mubarik Mahmood Chowdhry ,  Mun Hoe Stanley Kwan ,  Jonathan Allen

    发明人： Alexandre Terrenoire ,  Chris Titmarsh ,  Hideki Yamashita ,  Chee Seng Yong ,  Mubarik Mahmood Chowdhry ,  Mun Hoe Stanley Kwan ,  Jonathan Allen

    IPC分类号： C08K5/521

    CPC分类号： C09D143/02 ,  C08F220/18 ,  C08F230/02 ,  C08K5/521 ,  C09D4/00

    摘要： The present invention relates to the use of a polymer dispersion (PD) comprising at least one polymer (P), obtainable by free-radical emulsion polymerization of at least one ethylenically unsaturated monomer (M1) and at least one monomer (M2) different therefrom and selected from esters of phosphonic acid or of phosphoric acid with unalkoxylated or alkoxylated hydroxyalkyl(meth)acrylates, and at least one emulsifier (E) selected from phosphoric esters with unalkoxylated or alkoxylated C8-C30 alkanols, and their salts, in coating materials to improve the scrub resistance of the coatings produced therefrom and/or to improve the burnish resistance of the coatings produced therefrom and/or to improve the stain resistance of the coatings produced therefrom and/or to improve the pigment distribution in the coatings produced therefrom and/or to reduce the emission of volatile organic compounds by the coatings produced therefrom, to polymer dispersions used in accordance with the invention, and to coating materials comprising the polymer dispersions of the invention.

    摘要翻译： 本发明涉及包含至少一种聚合物（P）的聚合物分散体（PD）的用途，所述聚合物（P）可通过至少一种烯属不饱和单体（M1）和至少一种不同于其的烯属不饱和单体（M2）的自由基乳液聚合而获得 并选自膦酸或磷酸与未烷氧基化或烷氧基化羟基烷基（甲基）丙烯酸酯的酯，和至少一种选自具有非烷氧基化或烷氧基化的C 8 -C 30链烷醇的磷酸酯及其盐的乳化剂（E） 提高由其制备的涂料的耐擦洗性和/或提高由其制备的涂料的耐光泽性和/或改善由其制备的涂料的耐污染性和/或改善由其制备的涂料中的颜料分布和/ 或者通过由其制备的涂层来减少挥发性有机化合物的排放，以减少根据本发明使用的聚合物分散体 d涂覆包含本发明聚合物分散体的材料。

    POLYMER DISPERSIONS CONTAINING PHOSPHOROUS POLYMERS AND EMULSIFIERS
    6.
    发明申请
    POLYMER DISPERSIONS CONTAINING PHOSPHOROUS POLYMERS AND EMULSIFIERS 有权
    含聚磷酸酯和乳化剂的聚合物分散体

    公开(公告)号：US20110009540A1

    公开(公告)日：2011-01-13

    申请号：US12922983

    申请日：2009-03-20

    申请人： Alexandre Terrenoire ,  Chris Titmarsh ,  Hideki Yamashita ,  Chee Seng Yong ,  Mubarik Mahmood Chowdhry ,  Mun Hoe Stanley Kwan ,  Jonathan Allen

    发明人： Alexandre Terrenoire ,  Chris Titmarsh ,  Hideki Yamashita ,  Chee Seng Yong ,  Mubarik Mahmood Chowdhry ,  Mun Hoe Stanley Kwan ,  Jonathan Allen

    IPC分类号： C08K5/521

    CPC分类号： C09D143/02 ,  C08F220/18 ,  C08F230/02 ,  C08K5/521 ,  C09D4/00

    摘要： The present invention relates to the use of a polymer dispersion (PD) comprising at least one polymer (P), obtainable by free-radical emulsion polymerization of at least one ethylenically unsaturated monomer (M1) and at least one monomer (M2) different therefrom and selected from esters of phosphonic acid or of phosphoric acid with unalkoxylated or alkoxylated hydroxyalkyl (meth)acrylates, and at least one emulsifier (E) selected from phosphoric esters with unalkoxylated or alkoxylated C8-C30 alkanols, and their salts, in coating materials to improve the scrub resistance of the coatings produced therefrom and/or to improve the burnish resistance of the coatings produced therefrom and/or to improve the stain resistance of the coatings produced therefrom and/or to improve the pigment distribution in the coatings produced therefrom and/or to reduce the emission of volatile organic compounds by the coatings produced therefrom, to polymer dispersions used in accordance with the invention, and to coating materials comprising the polymer dispersions of the invention.

    摘要翻译： 本发明涉及包含至少一种聚合物（P）的聚合物分散体（PD）的用途，所述聚合物（P）可通过至少一种烯属不饱和单体（M1）和至少一种不同于其的烯属不饱和单体（M2）的自由基乳液聚合而获得 并选自膦酸或磷酸与未烷氧基化或烷氧基化羟基烷基（甲基）丙烯酸酯的酯，和至少一种选自具有非烷氧基化或烷氧基化的C 8 -C 30链烷醇的磷酸酯及其盐的乳化剂（E） 提高由其制备的涂料的耐擦洗性和/或提高由其制备的涂料的耐光泽性和/或改善由其制备的涂料的耐污染性和/或改善由其制备的涂料中的颜料分布和/ 或通过由其制备的涂层来减少挥发性有机化合物的排放，以减少根据本发明使用的聚合物分散体 和包含本发明的聚合物分散体的涂料。

    Binder compositions comprising boric acid or boric acid salt
    7.
    发明授权
    Binder compositions comprising boric acid or boric acid salt 有权
    包含硼酸或硼酸盐的粘合剂组合物

    公开(公告)号：US08329800B2

    公开(公告)日：2012-12-11

    申请号：US13141178

    申请日：2009-12-21

    申请人： Alexandre Terrenoire ,  Frank Reinhold ,  Stephan Amthor ,  Michael Gross ,  Konrad Roschmann ,  Stefan Becker ,  Kamesh Vyakaranam ,  Jens Hartig

    发明人： Alexandre Terrenoire ,  Frank Reinhold ,  Stephan Amthor ,  Michael Gross ,  Konrad Roschmann ,  Stefan Becker ,  Kamesh Vyakaranam ,  Jens Hartig

    IPC分类号： C08K3/38 ,  C08K3/00

    CPC分类号： C08F2/22 ,  C08F220/36 ,  C09J133/02

    摘要： An aqueous binder composition comprising: a) a water-insoluble polymer (P) in the form of dispersed polymer particles having a glass transition temperature in the range from −50° C. to 50° C., obtained by free-radical polymerization of ethylenically unsaturated monomers M, the monomers M comprising: 80% to 99.9% by weight, based on the total amount of monomers M, of at least one neutral, monoethylenically unsaturated monomer M1 of low water-solubility; and 0.1% to 20% by weight, based on the total amount of monomers M, of at least one monoethylenically unsaturated monomer M2 which carries at least one carboxyl group and/or at least one carboxamido group (CONH2); and b) boric acid and/or at least one salt of boric acid is provided. Also provided are a process to prepare the binder composition and the use thereof.

    摘要翻译： 一种水性粘合剂组合物，其包含：a）具有玻璃化转变温度在-50℃至50℃范围内的分散聚合物颗粒形式的水不溶性聚合物（P），其通过自由基聚合获得 烯属不饱和单体M，单体M包含：基于单体M的总量为80-99.9％（重量）的至少一种低水溶性的中性单烯属不饱和单体M1; 至少一种携带至少一个羧基和/或至少一个羧酰胺基（CONH 2）的单烯属不饱和单体M2，基于单体M的总量为0.1〜20重量％。 和b）提供硼酸和/或至少一种硼酸盐。 还提供了制备粘合剂组合物的方法及其用途。