PROCESS FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF ETHYLENE WITH ALPHA-OLEFIN BY USING THE TRANSITION METAL COMPOUND
    4.
    发明申请
    PROCESS FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF ETHYLENE WITH ALPHA-OLEFIN BY USING THE TRANSITION METAL COMPOUND 有权
    通过使用过渡金属化合物制备乙烯共聚物或乙烯与α-烯烃的共聚物的方法

    公开(公告)号:US20110319576A1

    公开(公告)日:2011-12-29

    申请号:US13223636

    申请日:2011-09-01

    IPC分类号: C08F10/02 C08F4/6592 C08F4/76

    摘要: Provided are transition metal catalytic systems for preparing ethylene homopolymers or copolymers of ethylene with α-olefins. More specifically, provided are Group 4 transition metal catalysts, which is characterized in that the catalyst comprises around the Group 4 transition metal a cyclopentadiene derivative, and at least one aryloxide ligand(s) having a fluorenyl group or a derivative thereof (which is ready to be substituted at 9-position) that functions as an electron donor and serves to stabilize the catalytic system by surrounding an oxygen atom that links the ligand to the transition metal at ortho-position, and there is no cross-linkage between the ligands; catalytic systems comprising such transition metal catalyst and aluminoxane cocatalyst or boron compound cocatalyst; and processes for preparing ethylene homopolymers or copolymers of ethylene with α-olefins by using the same.

    摘要翻译: 提供了用于制备乙烯均聚物或乙烯与α-烯烃的共聚物的过渡金属催化体系。 更具体地,提供了第4族过渡金属催化剂,其特征在于催化剂包含围绕第4族过渡金属环戊二烯衍生物和至少一种具有芴基或其衍生物的芳氧基配体(其准备好 在9位被取代),其用作电子给体并且用于通过围绕在配位体处将配体连接到过渡金属的氧原子来稳定催化体系,并且配体之间不存在交联; 包含这种过渡金属催化剂和铝氧烷助催化剂或硼化合物助催化剂的催化体系; 以及通过使用它们制备乙烯均聚物或乙烯与α-烯烃的共聚物的方法。

    Method for preparing elastomeric copolymers of ethylene and α-olefins
    6.
    发明授权
    Method for preparing elastomeric copolymers of ethylene and α-olefins 有权
    制备乙烯和α-烯烃弹性共聚物的方法

    公开(公告)号:US08013086B2

    公开(公告)日:2011-09-06

    申请号:US12612157

    申请日:2009-11-04

    摘要: Provided is a process for preparing copolymers of ethylene with α-olefin. More specifically, provided are transition metal compound being useful as catalyst for preparing those copolymers, a catalyst composition comprising the same, and a process for preparing elastic copolymers of ethylene with α-olefin, having the density of not more than 0.910, which can be adopted to a wide variety of applications including film, electric wires, and hot-melt adhesives. The catalyst composition is a catalytic system which comprises transition metal catalyst comprising a cyclopentadiene derivative and at least one anionic ligand(s) of aryloxy group with an aryl derivative at ortho-position, and boron or aluminum compound as an activator. Provided is a process for copolymerizing ethylene with α-olefin to produce copolymer having narrow molecular weight distribution and uniform density distribution with the density of not more than 0.910, with high activity and excellent reactivity on higher α-olefin.

    摘要翻译: 提供一种制备乙烯与α-烯烃的共聚物的方法。 更具体地,提供了用作制备那些共聚物的催化剂的过渡金属化合物,包含它们的催化剂组合物,以及制备乙烯与α-烯烃的弹性共聚物的方法,其密度不大于0.910,其可以是 适用于各种应用,包括胶片,电线和热熔胶。 催化剂组合物是一种催化体系,其包含过渡金属催化剂,其包含环戊二烯衍生物和至少一个芳氧基的阴离子配体与邻位的芳基衍生物,以及硼或铝化合物作为活化剂。 本发明提供一种乙烯与α-烯烃共聚以制备密度不大于0.910的分子量分布窄,密度分布均匀的共聚物,对高级α-烯烃具有高活性和优异的反应性的方法。

    Polymer electrolyte composition and dye-sensitized solar cell containing the same
    9.
    发明授权
    Polymer electrolyte composition and dye-sensitized solar cell containing the same 有权
    聚合物电解质组合物和含有它的染料敏化太阳能电池

    公开(公告)号:US08900483B2

    公开(公告)日:2014-12-02

    申请号:US13431411

    申请日:2012-03-27

    摘要: Disclosed is a polymer electrolyte composition, a gel-type polymer electrolyte obtained by mixing the same at normal temperature, and a dye-sensitized solar cell containing the electrolyte. Since the poly(alkylene carbonate)-based polymer is included, a crosslinking process by radiation of heat or UV is not required when the polymer electrolyte is manufactured, such that a manufacturing process is simple. Accordingly, the polymer electrolyte is useful for mass production of a solar cell and maintained in a uniform state without a phase separation between two components due to excellent affinity between the polymer and the organic solvent included in the electrolyte, and has excellent electrode-electrolyte interface property in the solar cell due to an adhesive property of the gelled polymer electrolyte.

    摘要翻译: 公开了一种聚合物电解质组合物,通常在常温下将其混合而获得的凝胶型聚合物电解质和含有电解质的染料敏化太阳能电池。 由于包含聚(碳酸亚烷基碳酸酯)基聚合物,所以当制造聚合物电解质时,不需要通过辐射热或UV的交联过程,使得制造过程简单。 因此,由于聚合物与包含在电解质中的有机溶剂之间的亲和性优异,聚合物电解质可用于大量生产太阳能电池并保持在均匀状态,而不会由于两种组分之间的相分离,并且具有优异的电极 - 电解质界面 由于胶凝聚合物电解质的粘合性,在太阳能电池中的性能。