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公开(公告)号:US3926846A
公开(公告)日:1975-12-16
申请号:US40628573
申请日:1973-10-15
发明人: ONO TETSUJI , NAKANISHI YOSHIYUKI , SUZUKI TAKEHIKO , OKUDA YUKIO
IPC分类号: B01J23/22 , B01J27/198 , C07C51/265 , B01J27/18
CPC分类号: B01J27/198 , B01J23/22 , C07C51/265 , C07C63/16
摘要: A catalyst for the preparation of phthalic anhydride by vapor phase catalytic oxidation of either ortho-xylene or naphthalene with a molecular oxygen-containing gas which comprises a catalytically active substance supported on a porous inert carrier, said catalytically active substance comprising 1 to 20 parts by weight of V2O5 and, correspondingly, 99 to 80 parts by weight of TiO2 and, based on the total weight of the V2O5 and TiO2, 0.02 to 5.0 % by weight of Nb2O5, 0.1 to 5.0 % by weight of P2O5, 0 to 0.25 % by weight of K2O and 0 to 0.5% by weight of Cs2O, the total weight of K2O and Cs2O being at least 0.05 % by weight and optionally 0 to 5.0 % by weight of at least one member selected from the group consisting of rare earth elements, ZnO and Tl2O.
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公开(公告)号:US3886092A
公开(公告)日:1975-05-27
申请号:US39647473
申请日:1973-09-12
IPC分类号: B01J23/88 , B01J23/887 , B01J23/888 , B01J35/10 , C07C51/25 , B01J11/06
CPC分类号: B01J23/8878 , B01J23/8885 , B01J35/10 , B01J35/1009 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/17 , B01J2523/31 , B01J2523/55 , B01J2523/67 , B01J2523/68 , B01J2523/69 , B01J2523/41
摘要: A process for producing unsaturated carboxylic acids, which comprises oxidizing unsaturated aldehydes in the vapor phase in the presence of a catalyst comprising a catalytic oxide supported on an inert carrier, such catalytic oxide containing metal elements in the atomic ratio Mo:V:Cu:Cr:W of 12:2-14:1-6:0-4:0-12 with the proviso that Cr + W is not 0.
摘要翻译: 一种制备不饱和羧酸的方法,其包括在催化剂存在下在气相中氧化不饱和醛,所述催化剂包含负载在惰性载体上的催化氧化物,所述催化氧化物含有原子比为Mo:V:Cu:Cr :W为12:2-14:1-6:0-4:0-12,条件是Cr + W不为0。
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公开(公告)号:US3660471A
公开(公告)日:1972-05-02
申请号:US3660471D
申请日:1968-10-28
发明人: SAWANO TOSHIMI , KOIKE HIROSHI , KURATA NAOJI , OKUDA YUKIO
IPC分类号: C07C303/14 , C07C309/04 , C07C143/02
CPC分类号: C07C309/00
摘要: A PROCESS FOR PREPARATION OF MONOSULPHONIC ACIDS AT HIGH SELECTIVITY WHICH COMPRISES REACTING STRAIGHT-CHAIN PARAFFINIC HYDROCARBONS HAVING 10 TO 30 CARBON ATOMS WITH SULPHUR DIOXIDE AND OXYGEN TO PRODUCE THE CORRESPONDING SULPHONIC ACIDS, CHARACTERISED IN THAT THE REACTION IS CARRIED OUT UNDER SUCH CONDITIONS AS TO BRING ABOUT A HOMOGENEOUS REACTION LIQUID PHASE, I.E., THE CONCENTRATION OF SULPHUR DIOXIDE IN THE REACTION LIQUID PHASE BEING 7 TO 23% BY WEIGHT, THE REACTION TEMPERATURE BEING 17 TO 37*C., AND THE CONVERSION OF THE STRAIGHT-CHAIN PARAFFINIC HYDROCARBON BEING 1 TO 7%.
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公开(公告)号:US3506621A
公开(公告)日:1970-04-14
申请号:US3506621D
申请日:1968-03-05
发明人: FUKUSHIMA SABURO , TAKIYAMA KEIICHI , NIKKI MASAO
CPC分类号: C08G63/42 , C08L67/00 , C08L2666/02
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公开(公告)号:US3085102A
公开(公告)日:1963-04-09
申请号:US2114060
申请日:1960-04-11
发明人: TAIZO YATAGAI , SUMIO MATSUDA , HARUO MATSUDA
IPC分类号: C07F7/22
CPC分类号: C07F7/2216
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公开(公告)号:US3920783A
公开(公告)日:1975-11-18
申请号:US39728473
申请日:1973-09-14
发明人: HARA HARUICHI , ADACHI AKIYOSHI
CPC分类号: B30B11/227 , B01J2/20 , Y10T225/371
摘要: A method of producing from a kneaded mass pellets moulded to a uniform dimension, which comprises disposing a surface which travels while being maintained at a specified distance from an extrusion outlet of an extruder and substantially at right angles to the direction of extrusion, and extruding a kneaded mass from the extruder, causing the distal end of the rodlike mass being extruded from the extrusion outlet to contact said traveling surface, and breaking off said rodlike mass at the rim of the extrusion outlet by the motive force of the traveling surface.
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公开(公告)号:US3898184A
公开(公告)日:1975-08-05
申请号:US38917573
申请日:1973-08-17
发明人: HARA HARUICHI , ICHIHARA SHOICHI , SAITO KOICHI , OHHATA TOMOHISA , HORIE KOSHI , OHARA TAKASHI
IPC分类号: B01D53/34 , B01J23/652 , B01J37/16 , B01J11/06
CPC分类号: B01J37/16 , B01D53/34 , B01J23/6522
摘要: A method for the production of exhaust or waste gases purifying catalysts which comprises soaking a granular activated alumina in an aqueous solution containing trivalent chromium ions and hexavalent chromium ions in a chromic atomic ratio of 1:1 to 1:20 and having an adjusted pH of 0.5 to 4.5 as to deposit the chromium compounds onto the alumina support in an amount as chromium oxide of 5 to 30 percent by weight based on the weight of the catalyst, drying and calcining the so impregnated alumina support, treating the resulting supported composition with an aqueous solution of a compound of at least one metal selected from the group consisting of palladium and platinum as to deposit the metallic compound in an amount as the metal of 0.05 to 2 g/liter-catalyst on to the supported composition and, after drying, activating the so treated supported composition. The activation is performed either by calcining the composition at a temperature of 300* to 800*C in an oxidative atmosphere or by heating it at a temperature of 80* to 250*C in the presence of a vapourized organic reducing agent.
摘要翻译: 一种生产排气或废气净化催化剂的方法,其包括将粒状活性氧化铝浸入含有三价铬离子和六价铬离子的水溶液中,铬原子比为1:1至1:20,调节pH值为 0.5至4.5以将铬化合物沉积在氧化铝载体上,其量为基于催化剂重量的5-30重量%的氧化铬,干燥和煅烧所浸渍的氧化铝载体,用 选自钯和铂中的至少一种金属的化合物的水溶液,以将金属化合物以0.05至2g / l催化剂的金属沉积到负载的组合物上,并且在干燥之后, 激活如此处理的支持组合物。 活化可以通过在氧化气氛中在300〜800℃的温度下煅烧组合物,或者在蒸发的有机还原剂的存在下,在80〜250℃的温度下进行加热。
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公开(公告)号:US3870655A
公开(公告)日:1975-03-11
申请号:US32681473
申请日:1973-01-26
发明人: NANBA YOKU , ONO TETSUJI , OKUDA YUKIO
IPC分类号: C07C50/18 , B01J21/00 , B01J21/06 , B01J23/00 , B01J23/22 , B01J27/00 , C07B61/00 , C07C45/00 , C07C67/00 , B01J11/82
CPC分类号: B01J23/22
摘要: A catalyst for the preparation of anthraquinone by vapor phase oxidation of anthracene with a molecular oxygen-containing gas comprising a catalytic material supported on an inert carrier, said catalytic material comprising 100 parts by weight, calculated as titanium dioxide, of titanium, 1 to 45 parts by weight, calculated as vanadium pentoxide, of vanadium, 0.05 to 15 parts by weight, calculated as oxide thereof, of at least two metal oxides selected from the group consisting of Li2O, Na2O, K2O, Rb2O, Cs2O and Tl2O, 0 to 5 parts by weight, calculated as phosphorus pentoxide, of phosphorus and 0 to 5 parts by weight, calculated as niobium pentoxide, of niobium.
摘要翻译: 一种催化剂,用于通过含有支撑在惰性载体上的催化材料的含分子氧气体气相氧化蒽来制备蒽醌,所述催化材料包含100重量份(以二氧化钛计)钛,1至45 按五氧化二钒计算的钒,以氧化物计0.05至15重量份的选自Li 2 O,Na 2 O,K 2 O,Rb 2 O,Cs 2 O和T 2 O 2中的至少两种金属氧化物,0至 5重量份,以五氧化二磷计算,为磷,0〜5重量份,以五氧化二铌计,为铌。
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公开(公告)号:US3833649A
公开(公告)日:1974-09-03
申请号:US19066171
申请日:1971-10-19
IPC分类号: B01J23/00 , B01J23/16 , B01J23/72 , B01J23/86 , C07B61/00 , C07C51/00 , C07C51/25 , C07C57/055 , C07C67/00 , C07C51/26 , C07C57/04
CPC分类号: B01J23/868 , C07C51/252 , C07C57/04
摘要: A PROCESS FOR PRODUCING UNSATURATED CARBOXYLIC ACIDS, WHICH COMPRISES OXIDIZING UNSATURATED ALDEHYDES IN THE VAPOR PHASE IN THE PRESENCE OF A CATALYST COMPRISING A CATALYTIC OXIDE SUPPORTED ON AN INERT CARRIER, SUCH CATALYTIC OXIDE CONTAINING METAL ELEMENTS IN THE ATOMIC RATIO M0:V:CU:CR:W OF 12:2-14:1-6:0-4:0-12 WITH THE PROVISO THAT CR+W IS NOT O.
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公开(公告)号:US3799978A
公开(公告)日:1974-03-26
申请号:US21168071
申请日:1971-12-23
发明人: OHARA T , NINOMIYA M , YANAGISAWA I , UESHIMA M , TAKATA M
CPC分类号: B01J23/8885 , C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要: A PROCESS FOR THE PREPARATION OF UNSATURATED CARBONYL COMPOUNDS WHICH COMPRISES THE CATALYTIC VAPOR PHASE OXIDATION OF AN OLEFIN HAVING AT LEASY 3 CARBON ATOMS IN THE PRESENCE OF A CATALYTIC OXIDE IN WHICH THE ATOMIC RATIO AMONG THE CONSTITUENT ELEMENTS, CKO;FE:BI:W:MO:SI:Z RANGES 2:0-20:0:0:1-10:0:0:5-10.0:0-11.5:015.0:0.005-1.0, WITH THE PROVISO THAT W PLUS MO EQUALS 12.0, AND Z STANDS FOR AN ALKALINE EARTH METAL.
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