摘要:
A process for producing unsaturated carboxylic acids, which comprises oxidizing unsaturated aldehydes in the vapor phase in the presence of a catalyst comprising a catalytic oxide supported on an inert carrier, such catalytic oxide containing metal elements in the atomic ratio Mo:V:Cu:Cr:W of 12:2-14:1-6:0-4:0-12 with the proviso that Cr + W is not 0.
摘要:
A method for the production of exhaust or waste gases purifying catalysts which comprises soaking a granular activated alumina in an aqueous solution containing trivalent chromium ions and hexavalent chromium ions in a chromic atomic ratio of 1:1 to 1:20 and having an adjusted pH of 0.5 to 4.5 as to deposit the chromium compounds onto the alumina support in an amount as chromium oxide of 5 to 30 percent by weight based on the weight of the catalyst, drying and calcining the so impregnated alumina support, treating the resulting supported composition with an aqueous solution of a compound of at least one metal selected from the group consisting of palladium and platinum as to deposit the metallic compound in an amount as the metal of 0.05 to 2 g/liter-catalyst on to the supported composition and, after drying, activating the so treated supported composition. The activation is performed either by calcining the composition at a temperature of 300* to 800*C in an oxidative atmosphere or by heating it at a temperature of 80* to 250*C in the presence of a vapourized organic reducing agent.
摘要:
A PROCESS FOR PRODUCING UNSATURATED CARBOXYLIC ACIDS, WHICH COMPRISES OXIDIZING UNSATURATED ALDEHYDES IN THE VAPOR PHASE IN THE PRESENCE OF A CATALYST COMPRISING A CATALYTIC OXIDE SUPPORTED ON AN INERT CARRIER, SUCH CATALYTIC OXIDE CONTAINING METAL ELEMENTS IN THE ATOMIC RATIO M0:V:CU:CR:W OF 12:2-14:1-6:0-4:0-12 WITH THE PROVISO THAT CR+W IS NOT O.
摘要:
A catalyst used for the purification of exhaust gases from internal combustion engine and waste gases from industrial plants is produced by dissolving an alumina sol with an inorganic acid to form an alumina sol solution, adding thereto a powdered alumina which contains at least 50 % by weight of rho alumina and is capable of forming, upon calcination, an activated alumina to form an alumina slurry, immersing in the alumina slurry a monolithic multicellular chemically inert support, while maintaining said alumina slurry at 0* to 30*C, to deposit an alumina layer on to the surface of said support, aging the alumina layer at a temperature of 50*C or below for at least 30 minutes, drying the alumina layer to form a thin alumina film on the surface of the support, impregnating the so treated support in a noble metal containing solution and activating the so impregnated support.
摘要:
A catalytic oxide, particularly adapted for the preparation of unsaturated carbonyl compounds through the catalytic vapor phase oxidation of olefins, wherein the atomic ratio among the constituent elements, Co:Fe:Bi:W:Mo:Si:Z, is within the range of 2.0-20.0 : 0.1-10.0 : 0.1-10.0 : 0.5-10.0 : 2.0-11.5 : 0-15.0 : 0.005-1.0, with the proviso that W plus Mo equals 12.0, and Z represents an alkaline earth metal.
摘要:
A process for recovering ammonia gas from an aqueous solution containing ammonia and carbon dioxide which comprises countercurrently contacting such aqueous solution with a desorption gas selected from air, oxygen, nitrogen and mixtures thereof. The molar ratio of ammonia to carbon dioxide in the aqueous solution is at least 2, such aqueous solution being one obtained upon the synthesis of urea from ammonia and carbon dioxide or from the production of an aromatic nitrile by the ammoxidation of an aromatic hydrocarbon.
摘要:
A catalyst composition consisting essentially of the metallic elements Co, Fe, Bi, W, Mo, Si and Z in which the atomic ratio among metallic elements, Co:Fe:Bi:W:Mo:Si:Z is within the range of 2.0-20.0:0.1-10.0:0.1-10.0:0.5-10.0:2.0-11.5:0.5-15.0:0.0051.0, with the proviso that W plus Mo equals 12.0, and Z represents an alkali metal.
摘要:
Noble metal catalysts are prepared by supporting a noble metal onto a refractory porous inorganic support from an aqueous medium containing a noble metal or a compound thereof in the presence of a nonionic surface active agent of poly(oxyethylene) type having an average molecular weight of at least 500 and subjecting the so treated support to activation.