公开(公告)号：US20130184494A1

公开(公告)日：2013-07-18

申请号：US13877057

申请日：2011-09-26

申请人： Kazunori Kurosawa ,  Joji Funatsu ,  Naoya Katagiri ,  Junichi Kugimoto

发明人： Kazunori Kurosawa ,  Joji Funatsu ,  Naoya Katagiri ,  Junichi Kugimoto

IPC分类号： C07C407/00 ,  C07C45/33 ,  C07C251/44 ,  C07C29/50 ,  C07C251/36 ,  C07C251/48 ,  B01J31/04 ,  B01J19/02

CPC分类号： C07C407/00 ,  B01J19/02 ,  B01J31/0241 ,  B01J31/0247 ,  B01J31/0258 ,  B01J31/04 ,  B01J31/2239 ,  B01J2231/70 ,  B01J2531/845 ,  C07C29/50 ,  C07C45/33 ,  C07C251/36 ,  C07C251/44 ,  C07C251/48 ,  C07C2601/14 ,  C07C49/303 ,  C07C35/08

摘要： According to the first embodiment of the present invention, an oxide of a hydrocarbon compound can be produced with high yield and high productivity by oxidizing the hydrocarbon compound with molecular oxygen in the co-presence of an N-hydroxy compound, such as methyl ethyl ketone or N-hydroxysuccinimide, and a phosphate ester, such as dibutyl phosphate. According to another embodiment of the present invention, an oxide of a hydrocarbon compound can be produced with high yield by using an oxidation catalyst that comprises an oxime compound, such as methyl ethyl ketone. According to another embodiment of the present invention, an alcohol and/or a ketone can be produced with high yield by oxidizing the hydrocarbon compound at a temperature of 160° C. or less, and by decomposing the resulting hydroperoxide, for example, in a unit having an inner surface formed by a material from which no transition metal ion is generated.

摘要翻译： 根据本发明的第一实施方案，通过在N-羟基化合物如甲基乙基酮的共存下用分子氧氧化烃化合物，可以高产率和高生产率制备烃化合物的氧化物 或N-羟基琥珀酰亚胺，和磷酸酯，例如磷酸二丁酯。 根据本发明的另一个实施方案，可以通过使用包含肟化合物如甲基乙基酮的氧化催化剂，以高产率制备烃化合物的氧化物。 根据本发明的另一个实施方案，通过在160℃或更低的温度下氧化烃化合物，并且通过将所得的氢过氧化物分解，可以以高产率制备醇和/或酮，例如在 单元具有由不产生过渡金属离子的材料形成的内表面。