公开(公告)号：US20120186636A1

公开(公告)日：2012-07-26

申请号：US13388845

申请日：2010-08-04

申请人： Anthony Bonnet ,  Francois Beaume ,  Nicolas Devaux ,  Karine Triballier ,  Stephane Bizet ,  Frederic Godefroy

发明人： Anthony Bonnet ,  Francois Beaume ,  Nicolas Devaux ,  Karine Triballier ,  Stephane Bizet ,  Frederic Godefroy

IPC分类号： C08L27/12 ,  H01L31/02 ,  C08K3/22 ,  C08K9/00 ,  C08L27/20 ,  B32B5/00 ,  B29C49/00 ,  B82Y30/00

CPC分类号： C08J5/18 ,  C08J3/226 ,  C08J2327/16 ,  C08J2427/16 ,  C08K3/22 ,  C08L27/12 ,  C08L27/16 ,  H01L31/0481 ,  Y02E10/50 ,  C08L33/12

摘要： The present invention relates to a polymeric composition composed of a fluoropolymer and of zinc oxide (ZnO) of nanometric size which is intended for the manufacture of films transparent in the visible region and opaque to UV radiation. More particularly, in the composition according to the invention, the said filler is present in a proportion by weight of 0.1 to 10%, preferably of 0.5 to 6%, the ZnO particles have a size ranging from 25 to 40 nm, preferably from 30 to 35 nm, these particles have a surface treatment and the said composition is devoid of acrylic polymers.

摘要翻译： 本发明涉及由氟聚合物和纳米尺寸的氧化锌（ZnO）组成的聚合物组合物，其用于制造在可见光区域透明且对UV辐射不透明的膜。 更具体地说，在根据本发明的组合物中，所述填料以0.1至10重量％，优选0.5至6重量％的比例存在，ZnO颗粒的尺寸范围为25至40nm，优选为30 至35nm，这些颗粒具有表面处理，并且所述组合物没有丙烯酸聚合物。

公开(公告)号：US20130112268A1

公开(公告)日：2013-05-09

申请号：US13522037

申请日：2011-01-11

申请人： Anthony Bonnet ,  Francois Beaume ,  Stephane Bizet ,  Nicolas Devaux

发明人： Anthony Bonnet ,  Francois Beaume ,  Stephane Bizet ,  Nicolas Devaux

IPC分类号： C08K3/22 ,  H01L31/048

CPC分类号： C08K3/22 ,  C08J3/201 ,  C08J5/18 ,  C08J2327/16 ,  C08L27/16 ,  H01L31/049 ,  Y02E10/50

摘要： The present invention relates to a composition consisting of a fluoropolymer and a white inorganic filler, said composition being intended for the manufacture of monolayer films opaque to visible tight and to UV radiation, useable in particular in the field of photovoltaic cells. The polymeric composition consists of a fluoropolymer and zinc oxide (ZnO), said filler being present in said composition in a weight proportion of 20 to 40%, preferably 20 to 35%. The use of this filler serves on the one hand to avoid the addition of acrylic polymers to the fluoropolymer, and on the other hand, to use processing temperatures that are compatible with the manufacture of a monolayer film by extrusion blow moulding, that is, a temperature of about 220 to 260° C., thereby serving to prevent the degradation of the fluoropolymer.

摘要翻译： 本发明涉及一种由氟聚合物和白色无机填料组成的组合物，所述组合物旨在用于制造对于可见的紧密和紫外线辐射不透明的单层膜，特别是在光伏电池领域中。 聚合物组合物由氟聚合物和氧化锌（ZnO）组成，所述填料以20-40％，优选20-35％的重量比存在于所述组合物中。 使用这种填料一方面是为了避免向含氟聚合物中加入丙烯酸聚合物，另一方面，使用通过挤出吹塑成型制备单层膜的加工温度，即， 温度为约220至260℃，从而用于防止含氟聚合物的降解。

公开(公告)号：US20130009110A1

公开(公告)日：2013-01-10

申请号：US13543024

申请日：2012-07-06

申请人： Benoit BRULE ,  Nicolas Devaux ,  Patrick M. Piccione ,  Eric Gamache ,  Catherine Bluteau ,  Nour-Eddine El Bounia

发明人： Benoit BRULE ,  Nicolas Devaux ,  Patrick M. Piccione ,  Eric Gamache ,  Catherine Bluteau ,  Nour-Eddine El Bounia

IPC分类号： H01B1/24 ,  B29C45/00 ,  B82Y40/00

CPC分类号： H01B1/24 ,  B82Y30/00

摘要： Methods for controlling and improving the conductivity of thermoplastic polymer composites containing CNTs or even for making these materials conductive when they are initially insulating. For example, methods including either injection moulding or extrusion at a temperature above the melting temperature of the polymer, or a subsequent heat treatment step of said composite obtained by injection moulding or extrusion.

摘要翻译： 用于控制和改善含有CNT的热塑性聚合物复合材料的导电性的方法，或甚至当这些材料最初绝缘时使其导电。 例如，在高于聚合物的熔融温度的温度下进行注射成型或挤出的方法，或通过注射成型或挤出获得的所述复合材料的随后的热处理步骤。

公开(公告)号：US08878054B2

公开(公告)日：2014-11-04

申请号：US12532573

申请日：2009-02-06

申请人： Stephane Bizet ,  Anthony Bonnet ,  Nicolas Devaux ,  Johann Laffargue ,  Aude Lapprand

发明人： Stephane Bizet ,  Anthony Bonnet ,  Nicolas Devaux ,  Johann Laffargue ,  Aude Lapprand

IPC分类号： H01L31/00 ,  B32B27/28 ,  B32B27/08 ,  B32B27/30 ,  C08L27/16 ,  C08L33/12 ,  H01L31/048

CPC分类号： B32B27/28 ,  B32B7/12 ,  B32B27/08 ,  B32B27/18 ,  B32B27/30 ,  B32B27/304 ,  B32B27/308 ,  B32B27/32 ,  B32B27/322 ,  B32B2250/03 ,  B32B2250/40 ,  B32B2264/02 ,  B32B2307/30 ,  B32B2307/306 ,  B32B2307/308 ,  B32B2307/41 ,  B32B2307/50 ,  B32B2307/546 ,  B32B2307/71 ,  B32B2307/712 ,  B32B2307/714 ,  B32B2457/12 ,  C08L27/16 ,  C08L33/12 ,  H01L31/048 ,  H01L31/0481 ,  H01L31/049 ,  Y02E10/50 ,  Y10T428/24231 ,  Y10T428/24975 ,  Y10T428/25 ,  Y10T428/265 ,  Y10T428/3154 ,  C08L2666/04

摘要： The invention relates to a multilayer film of A/B/C structure comprising: a first layer of composition A, comprising a fluoropolymer; a second layer of composition B, comprising a filled fluoropolymer; and a third layer of composition C, comprising a fluoropolymer, characterized in that the first and third layers have a melting point above 150° C., measured by DSC, and in that the transmittance in visible light is less than 30% for a multilayer film thickness of 25 μm. The invention also relates to the use of a fluoropolymer-based film preferably for a photovoltaic cell back panel, a high-performance textile or a metal, the film adhering to the substrate by means of an adhesive layer placed between the substrate and the film.

摘要翻译： 本发明涉及一种A / B / C结构的多层膜，其包括：第一层组合物A，其包含含氟聚合物; 组合物B的第二层，包含填充的含氟聚合物; 以及包含含氟聚合物的组合物C的第三层，其特征在于，通过DSC测量，第一层和第三层的熔点高于150℃，并且对于多层膜，可见光的透射率小于30％ 膜厚25微米。 本发明还涉及优选用于光伏电池背板，高性能织物或金属的氟聚合物基膜的使用，所述膜通过设置在基板和膜之间的粘合剂层粘附到基板。

公开(公告)号：US20130319510A1

公开(公告)日：2013-12-05

申请号：US13879138

申请日：2011-09-30

申请人： Anthony Bonnet ,  Nicolas Devaux ,  Barbara Ramfel ,  Emmanuel Veret ,  Stephane Bizet ,  Gregory S. O'Brien

发明人： Anthony Bonnet ,  Nicolas Devaux ,  Barbara Ramfel ,  Emmanuel Veret ,  Stephane Bizet ,  Gregory S. O'Brien

IPC分类号： H01L31/048 ,  B29C49/00 ,  B29C39/00 ,  B29C49/04 ,  B29C47/00

CPC分类号： B29C39/003 ,  B29C48/022 ,  B29C49/0005 ,  B29C49/04 ,  C08J5/18 ,  C08J2327/12 ,  C08J2327/16 ,  C08K3/22 ,  C08L27/12 ,  C08L27/16 ,  C08L33/00 ,  C08L33/12 ,  C08L2205/02 ,  C08L2205/03 ,  H01L31/0481 ,  H01L31/049 ,  Y02E10/50 ,  C08L2666/04

摘要： The present invention relates to a composition comprising a fluoropolymer and two white inorganic fillers, the said composition being intended for the manufacture of thin monolayer films which are opaque to visible light and to UV rays and which can be used in particular in the field of photovoltaic cells. This composition consists of at least one fluoropolymer and of two white inorganic fillers, which are zinc oxide and titanium oxide; they are present in a proportion by weight ranging from 5 to 30% and from 3 to 7.5% respectively, The said composition additionally comprises less than 5% by weight of acrylic polymer, with respect to the total weight of the composition.

摘要翻译： 本发明涉及包含含氟聚合物和两种白色无机填料的组合物，所述组合物旨在用于制造对可见光和紫外线不透明的薄单层膜，其特别可用于光电领域 细胞。 该组合物由至少一种氟聚合物和两种白色无机填料组成，它们是氧化锌和氧化钛; 它们分别以5至30％和3至7.5％的重量比例存在。所述组合物相对于组合物的总重量另外包含小于5重量％的丙烯酸聚合物。

公开(公告)号：US20130022806A1

公开(公告)日：2013-01-24

申请号：US13637398

申请日：2011-03-29

申请人： Anthony Bonnet ,  Nicolas Devaux ,  Stephane Bizet ,  Nadine Rivas ,  Frederic Godefroy

发明人： Anthony Bonnet ,  Nicolas Devaux ,  Stephane Bizet ,  Nadine Rivas ,  Frederic Godefroy

IPC分类号： B32B27/08 ,  A01G13/02 ,  A01G9/14 ,  B29C49/22

CPC分类号： B32B27/08 ,  A01G9/1438 ,  B32B27/28 ,  B32B27/304 ,  B32B27/322 ,  B32B2250/42 ,  B32B2307/51 ,  B32B2307/5825 ,  B32B2307/732 ,  B32B2410/00 ,  Y02A40/252 ,  Y10T428/3154

摘要： The present invention relates to multilayer films made of fluoro polymers, which have properties that make them suitable for use in the agricultural field, especially as greenhouse covering films. According to a first aspect, the invention relates to multilayer fluorinated films comprising at least three layers, including a layer A made of a first vinylidene fluoride copolymer with a crystallization temperature TcA, and a layer B made of a second vinylidene fluoride copolymer with a crystallization temperature TcB, TcA being greater than TcB, layers A and B being alternating, layer A being placed to the exterior and layer B between two layers A. Another subject of the invention relates to the use of the film according to the invention as an agricultural covering material, especially as a greenhouse covering.

摘要翻译： 本发明涉及由氟聚合物制成的多层膜，其具有使其适合用于农业领域，特别是作为温室覆盖膜的性质。 根据第一方面，本发明涉及包括至少三层的多层氟化膜，包括由结晶温度TcA的第一偏二氟乙烯共聚物制成的层A和由具有结晶的第二偏二氟乙烯共聚物制成的层B 温度TcB，TcA大于TcB，层A和B是交替的，层A被放置在两层A之间的外部和层B.本发明的另一个主题涉及根据本发明的膜作为农业 覆盖材料，特别是作为温室覆盖物。

公开(公告)号：US20100084616A1

公开(公告)日：2010-04-08

申请号：US12444912

申请日：2007-10-01

申请人： Benoit Brule ,  Nicolas Devaux ,  Patrick M. Piccione ,  Eric Gamache ,  Catherine Bluteau ,  Nour-Eddine El Bounia

发明人： Benoit Brule ,  Nicolas Devaux ,  Patrick M. Piccione ,  Eric Gamache ,  Catherine Bluteau ,  Nour-Eddine El Bounia

IPC分类号： H01B1/24 ,  C08K7/24

CPC分类号： H01B1/24 ,  B82Y30/00

摘要： The invention relates to methods for controlling and improving the conductivity of thermoplastic polymer composites containing CNTs or even for making these materials conductive when they are initially insulating.The present invention relates to a conductive composite, based on a thermoplastic polymer and on carbon nanotubes (CNTs), and the methods for preparing said conductive composite, the methods comprising either injection moulding or extrusion at a temperature above the melting temperature of the polymer, or a subsequent heat treatment step of said composite obtained by injection moulding or extrusion.

摘要翻译： 本发明涉及用于控制和改善含有CNT的热塑性聚合物复合材料的导电性的方法，或者甚至当这些材料最初绝缘时使其导电。 本发明涉及基于热塑性聚合物和碳纳米管（CNT）的导电复合材料以及制备所述导电复合材料的方法，所述方法包括在高于聚合物熔融温度的温度下进行注塑或挤出， 或通过注射成型或挤出获得的所述复合材料的后续热处理步骤。

公开(公告)号：US20130053498A1

公开(公告)日：2013-02-28

申请号：US13660301

申请日：2012-10-25

申请人： Anthony Bonnet ,  Francois Beaume ,  Nicolas Devaux ,  Karine Triballier ,  Stephane Bizet ,  Frederic Godefroy

发明人： Anthony Bonnet ,  Francois Beaume ,  Nicolas Devaux ,  Karine Triballier ,  Stephane Bizet ,  Frederic Godefroy

IPC分类号： C08L27/16 ,  C08K3/26 ,  C08K3/22

CPC分类号： C08J5/18 ,  C08J3/226 ,  C08J2327/16 ,  C08J2427/16 ,  C08K3/22 ,  C08L27/12 ,  C08L27/16 ,  H01L31/0481 ,  Y02E10/50 ,  C08L33/12

摘要： The present invention relates to a process for forming a polymeric composition composed of a fluoropolymer and of zinc oxide (ZnO) of nanometric size from an acrylic masterbatch. The polymeric composition is intended for the manufacture of films transparent in the visible region and opaque to UV radiation. More particularly, in the composition according to the invention, the filler is present in a proportion by weight of 0.1 to 10%, preferably of 0.5 to 6%, the ZnO particles have a size ranging from 25 to 40 nm, preferably from 30 to 35 nm, these particles have a surface treatment and the said composition is devoid of acrylic polymers.

摘要翻译： 本发明涉及由丙烯酸酯母料形成由含氟聚合物和纳米尺寸的氧化锌（ZnO）组成的聚合物组合物的方法。 聚合物组合物用于制造在可见光区域透明且对UV辐射不透明的膜。 更具体地说，在根据本发明的组合物中，填料的重量比为0.1〜10％，优选为0.5〜6％，ZnO粒子的粒度为25〜40nm，优选为30〜 35nm，这些颗粒具有表面处理，并且所述组合物没有丙烯酸聚合物。