公开(公告)号：US20130090419A1

公开(公告)日：2013-04-11

申请号：US13253213

申请日：2011-10-05

申请人： Rick L. Archey ,  James P. Mason ,  Pierre Moulinie ,  Richard Peterman ,  Mary Ann Wittig

发明人： Rick L. Archey ,  James P. Mason ,  Pierre Moulinie ,  Richard Peterman ,  Mary Ann Wittig

IPC分类号： C08L69/00 ,  C08K5/107 ,  C08J3/20 ,  C08K5/103

CPC分类号： C08K5/109 ,  C08L69/00

摘要： The present invention relates to compositions containing a polycarbonate including a bisphenol compound and an effective amount of a bishaloformate component present in an amount sufficient to reduce the average unbound bisphenol compound level found in water after immersion in deionized water for two weeks at 40° C. of the composition to less than about 20 ppb. Also provided are methods for increasing the water resistance of a polycarbonate composition. The method involves adding an effective amount of a bishaloformate component to the polycarbonate composition such that the polycarbonate composition has an average unbound bisphenol compound level found in water after immersion in deionized water for two weeks at 40° C. of less than about 20 ppb.

摘要翻译： 本发明涉及包含双酚化合物的聚碳酸酯和有效量的双卤代甲酸酯组分的组合物，其量足以降低在40℃下浸入去离子水中2周后在水中发现的平均未结合双酚化合物水平。 的组成小于约20ppb。 还提供了增加聚碳酸酯组合物的耐水性的方法。 该方法包括向聚碳酸酯组合物中加入有效量的双卤代甲酸酯组分，使得聚碳酸酯组合物在40℃下浸入去离子水中两周后，在水中发现的平均未结合双酚化合物水平小于约20ppb。

公开(公告)号：US07041732B2

公开(公告)日：2006-05-09

申请号：US10730518

申请日：2003-12-08

申请人： Daniel H. Bolton ,  Pierre Moulinie ,  David M. Derikart ,  Nicanor Kohncke

发明人： Daniel H. Bolton ,  Pierre Moulinie ,  David M. Derikart ,  Nicanor Kohncke

IPC分类号： C08L69/00

CPC分类号： C08L69/00 ,  C08L2666/04

摘要： A compatible blend of polycarbonate resin with a vinyl (co)polymer blending partner is disclosed. The preparation of inventive blend comprise reactive blending of polycarbonate, a vinyl (co)polymer and a novel compatibilizer in the presence of a transesterification catalyst and under conditions of time and temperature designed to promote transesterification. The compatibilizer is the polymerized reaction product of at least one vinyl monomer that contains no hydroxy groups and a hydroxyl containing monomer conforming to (I) where R denotes H or C1–C4 alkyl, R1 denotes H, Cl, Br, C1–C4 alkyl, cyclohexyl, or C1–C4 alkoxy, a is 0 or 1, b is 0 or 1, c is 0 or 1, n is an integer of 0 to 4 and X is an OH group. The compatible blends of the invention are characterized by their improved properties.

摘要翻译： 公开了聚碳酸酯树脂与乙烯基（共）聚合物共混配合物的相容共混物。 本发明共混物的制备包括聚碳酸酯，乙烯基（共）聚合物和新型增容剂在酯交换催化剂存在下和设计用于促进酯交换的时间和温度的条件下的反应性共混。 增容剂是至少一种不含羟基的乙烯基单体和符合（I）的含羟基单体的聚合反应产物，其中R表示H或C 1 -C 4 - 其中R 1表示H，Cl，Br，C 1 -C 4烷基，环己基或C 1〜 烷氧基，a为0或1，b为0或1，c为0或1，n为0〜4的整数，X为OH基。 本发明的相容共混物的特征在于其改进的性能。

公开(公告)号：US20090247673A1

公开(公告)日：2009-10-01

申请号：US12408050

申请日：2009-03-20

申请人： Pierre MOULINIE ,  Ralf Hufen ,  Stephan Konrad ,  Dieter Wittmann

发明人： Pierre MOULINIE ,  Ralf Hufen ,  Stephan Konrad ,  Dieter Wittmann

IPC分类号： C08K5/1575 ,  C08K3/32 ,  C08K5/5313 ,  C08K5/5317 ,  C08K5/524

CPC分类号： C08L69/00 ,  C08K3/32 ,  C08K5/51 ,  C08L51/04 ,  C08L67/02 ,  C08L2666/18 ,  C08L2666/02

摘要： The present invention relates to compositions comprising A) aromatic polycarbonate, B) polyalkylene terephthalate and C) a concentrate comprising polyalkylene terephthalate and at least one compound selected from the group consisting of ortho-phosphoric acid, phosphorous acid, carboxylic acid esters of ortho-phosphoric acid and carboxylic acid esters of phosphorous acid, Compositions of the present invention are distinguished by high melt stability. The present invention also relates to a process for the preparation of impact-modified polyalkylene terephthalate/polycarbonate compositions, wherein a concentrate of polyalkylene terephthalate with a phosphorus-containing additive is used.

摘要翻译： 本发明涉及包含A）芳族聚碳酸酯，B）聚对苯二甲酸亚烷基酯和C）包含聚对苯二甲酸亚烷基酯和至少一种选自正磷酸，亚磷酸，正磷酸的羧酸酯的化合物 亚酸的酸和羧酸酯，本发明的组合物的特征在于高熔体稳定性。 本发明还涉及一种制备冲击改性聚对苯二甲酸亚烷基酯/聚碳酸酯组合物的方法，其中使用聚对苯二甲酸亚烷基酯与含磷添加剂的浓缩物。

公开(公告)号：US20080214723A1

公开(公告)日：2008-09-04

申请号：US11818389

申请日：2007-06-14

申请人： Pierre Moulinie

发明人： Pierre Moulinie

IPC分类号： C08L67/00

CPC分类号： C08L67/02 ,  C08L23/0884 ,  C08L69/00 ,  C08L2666/02

摘要： A process for the production of impact-modified composition that contains polyalkylene terephthalate and polycarbonate resins is disclosed. The process includes (i) in a first step combining in the melt at 90 to 175° C. glycidyl ester with at least one member selected from the first group consisting of polyalkylene terephthalate and polycarbonate to obtain a molten mixture, said member in powder form, and (ii) in a subsequent step combining the molten mixture with at least one component selected from the second group consisting of polyalkylene terephthalate and polycarbonate to obtain a composition. The composition is characterized in high gloss value.

摘要翻译： 公开了一种制备包含聚对苯二甲酸亚烷基酯和聚碳酸酯树脂的冲击改性组合物的方法。 该方法包括（i）第一步，在90至175℃的熔体中将缩水甘油酯与至少一种选自由聚对苯二甲酸亚烷基酯和聚碳酸酯组成的第一组中的组分混合以获得熔融混合物，所述的粉末形式的组分 ，和（ii）在随后的步骤中，将熔融混合物与选自聚对苯二甲酸亚烷基酯和聚碳酸酯的第二组中的至少一种组分混合以获得组合物。 该组合物的特征在于高光泽度。

公开(公告)号：US20070060678A1

公开(公告)日：2007-03-15

申请号：US11226636

申请日：2005-09-14

申请人： Eckhard Wenz ,  Pierre Moulinie ,  Thomas Eckel ,  Vera Buchholz ,  Dieter Wittmann ,  Bruce Hager ,  Fred Zaganiacz

发明人： Eckhard Wenz ,  Pierre Moulinie ,  Thomas Eckel ,  Vera Buchholz ,  Dieter Wittmann ,  Bruce Hager ,  Fred Zaganiacz

IPC分类号： C08K5/49

CPC分类号： C08L69/005 ,  C08K3/346 ,  C08K5/521 ,  C08K5/5333 ,  C08K5/5353 ,  C08K5/5399 ,  C08L51/00 ,  C08L67/02 ,  C08L69/00 ,  C08L2666/02 ,  C08L2666/24

摘要： A thermoplastic molding composition suitable for preparing articles by thermoforming is disclosed. The molding composition that comprise A) branched, aromatic poly(ester)carbonate, B) graft polymer, C) an optional vinyl(co)polymer and or polyalkylene terephthalate, D) at least one flame retarding phosphorous compound selected from the group consisting of mono- and oligomeric phosphorus and phosphonic acid esters, phosphonate amines and phosphazenes and E) talc, is characterized in that its flexural modulus at room temperature is at least 3000 N/mm2 and that its falling dart energy at break, at −30° C., is at least 40.0 J. Sheets extruded of the composition are suitable for making useful articles by thermoforming.

摘要翻译： 公开了一种适于通过热成型制备制品的热塑性模塑组合物。 包含A）支链，芳族聚（酯）碳酸酯，B）接枝聚合物，C）任选的乙烯基（共）聚合物和/或聚对苯二甲酸亚烷基酯的模塑组合物，D）至少一种选自以下的阻燃磷化合物： 单和低聚磷和膦酸酯，膦酸酯胺和磷腈以及E）滑石，其特征在于其在室温下的挠曲模量为至少3000N / mm 2，并且其落镖能量 在-30℃下断裂至少为40.0J。该组合物的片材挤压适用于通过热成型制备有用的制品。

公开(公告)号：US20110230595A1

公开(公告)日：2011-09-22

申请号：US13104079

申请日：2011-05-10

申请人： Pierre MOULINIE

发明人： Pierre MOULINIE

IPC分类号： C08L63/00 ,  C08L67/03

CPC分类号： C08L67/02 ,  C08L23/0884 ,  C08L69/00 ,  C08L2666/02

摘要： A process for the production of impact-modified composition that contains polyalkylene terephthalate and polycarbonate resins is disclosed. The process includes (i) in a first step combining in the melt at 90 to 175° C. glycidyl ester with at least one member selected from the first group consisting of polyalkylene terephthalate and polycarbonate to obtain a molten mixture, said member in powder form, and (ii) in a subsequent step combining the molten mixture with at least one component selected from the second group consisting of polyalkylene terephthalate and polycarbonate to obtain a composition. The composition is characterized in high gloss value.

摘要翻译： 公开了一种制备包含聚对苯二甲酸亚烷基酯和聚碳酸酯树脂的冲击改性组合物的方法。 该方法包括（i）第一步，在90至175℃的熔体中将缩水甘油酯与至少一种选自由聚对苯二甲酸亚烷基酯和聚碳酸酯组成的第一组中的组分混合以获得熔融混合物，所述的粉末形式的组分 ，和（ii）在随后的步骤中，将熔融混合物与选自聚对苯二甲酸亚烷基酯和聚碳酸酯的第二组中的至少一种组分混合以获得组合物。 该组合物的特征在于高光泽度。

公开(公告)号：US08013066B2

公开(公告)日：2011-09-06

申请号：US11818389

申请日：2007-06-14

申请人： Pierre Moulinie

发明人： Pierre Moulinie

IPC分类号： C08L69/00 ,  C08L67/02

CPC分类号： C08L67/02 ,  C08L23/0884 ,  C08L69/00 ,  C08L2666/02

摘要： A process for the production of impact-modified composition that contains polyalkylene terephthalate and polycarbonate resins is disclosed. The process includes (i) in a first step combining in the melt at 90 to 175° C. glycidyl ester with at least one member selected from the first group consisting of polyalkylene terephthalate and polycarbonate to obtain a molten mixture, said member in powder form, and (ii) in a subsequent step combining the molten mixture with at least one component selected from the second group consisting of polyalkylene terephthalate and polycarbonate to obtain a composition. The composition is characterized in high gloss value.

摘要翻译： 公开了一种制备包含聚对苯二甲酸亚烷基酯和聚碳酸酯树脂的冲击改性组合物的方法。 该方法包括（i）第一步，在90至175℃的熔体中将缩水甘油酯与至少一种选自由聚对苯二甲酸亚烷基酯和聚碳酸酯组成的第一组中的组分混合以获得熔融混合物，所述的粉末形式的组分 ，和（ii）在随后的步骤中，将熔融混合物与选自聚对苯二甲酸亚烷基酯和聚碳酸酯的第二组中的至少一种组分混合以获得组合物。 该组合物的特征在于高光泽度。

公开(公告)号：US07893135B2

公开(公告)日：2011-02-22

申请号：US12408050

申请日：2009-03-20

申请人： Pierre Moulinie ,  Ralf Hufen ,  Stephan Konrad ,  Dieter Wittmann

发明人： Pierre Moulinie ,  Ralf Hufen ,  Stephan Konrad ,  Dieter Wittmann

IPC分类号： C08J3/20

CPC分类号： C08L69/00 ,  C08K3/32 ,  C08K5/51 ,  C08L51/04 ,  C08L67/02 ,  C08L2666/18 ,  C08L2666/02

摘要： The present invention relates to compositions comprising A) aromatic polycarbonate, B) polyalkylene terephthalate and C) a concentrate comprising polyalkylene terephthalate and at least one compound selected from the group consisting of ortho-phosphoric acid, phosphorous acid, carboxylic acid esters of ortho-phosphoric acid and carboxylic acid esters of phosphorous acid, Compositions of the present invention are distinguished by high melt stability. The present invention also relates to a process for the preparation of impact-modified polyalkylene terephthalate/polycarbonate compositions, wherein a concentrate of polyalkylene terephthalate with a phosphorus-containing additive is used.

摘要翻译： 本发明涉及包含A）芳族聚碳酸酯，B）聚对苯二甲酸亚烷基酯和C）包含聚对苯二甲酸亚烷基酯和至少一种选自正磷酸，亚磷酸，正磷酸的羧酸酯的化合物 亚酸的酸和羧酸酯，本发明的组合物的特征在于高熔体稳定性。 本发明还涉及一种制备冲击改性聚对苯二甲酸亚烷基酯/聚碳酸酯组合物的方法，其中使用聚对苯二甲酸亚烷基酯与含磷添加剂的浓缩物。

公开(公告)号：US20090215945A1

公开(公告)日：2009-08-27

申请号：US12338270

申请日：2008-12-18

申请人： Pierre MOULINIE ,  Vera BUCHHOLZ ,  Eckhard WENZ ,  Dieter WITTMANN

发明人： Pierre MOULINIE ,  Vera BUCHHOLZ ,  Eckhard WENZ ,  Dieter WITTMANN

IPC分类号： C08K3/32

CPC分类号： C08L67/02 ,  C08K3/24 ,  C08K3/32 ,  C08K5/5313 ,  C08L51/04 ,  C08L55/02 ,  C08L69/00 ,  C08L2666/18 ,  C08L2666/02

摘要： The present invention relates to an impact-modified polyalkylene terephthalate/polycarbonate composition comprising A) 41 to 97 parts by wt. (in each case based on the sum of the parts by weight of components A+B+C+D) of aromatic polycarbonate, B) 2 to 19 parts by wt. (in each case based on the sum of the parts by weight of components A+B+C+D) of polyalkylene terephthalate, C) 0.5 to 15 parts by wt. (in each case based on the sum of the parts by weight of components A+B+C+D) of rubber-modified graft polymer, D) 0.5 to 25 parts by wt. (in each case based on the sum of the parts by weight of components A+B+C+D) of a salt of a phosphinic acid, A composition of the present invention is distinguished by an optimum combination of high heat distortion temperature, good flameproofing and excellent mechanical properties (in particular high E modulus), the use of the polycarbonate compositions for the production of shaped articles and the shaped articles themselves.

摘要翻译： 本发明涉及一种冲击改性聚对苯二甲酸亚烷基酯/聚碳酸酯组合物，其包含A）41-97重量份 （在每种情况下基于组分A + B + C + D的重量份之和），B）2至19份（重量） （在每种情况下，基于组分A + B + C + D的重量份的总和），聚对苯二甲酸亚烷基酯，C）0.5〜15重量份。 （在每种情况下基于橡胶改性接枝聚合物的组分A + B + C + D的重量份数之和），D）0.5〜25重量份。 （在每种情况下基于组分A + B + C + D的重量份之和）次膦酸的盐，本发明的组合物的特征在于高热变形温度，良好的 防火性和优异的机械性能（特别是高E模量），聚碳酸酯组合物用于生产成型制品和成型制品本身的用途。

公开(公告)号：US06670420B2

公开(公告)日：2003-12-30

申请号：US10053261

申请日：2002-01-18

申请人： Daniel H. Bolton ,  Pierre Moulinie ,  David M. Derikart ,  Nicanor Kohncke

发明人： Daniel H. Bolton ,  Pierre Moulinie ,  David M. Derikart ,  Nicanor Kohncke

IPC分类号： C08L6900

CPC分类号： C08L69/00 ,  C08L2666/04

摘要： A compatible blend of polycarbonate resin with a vinyl (co)polymer blending partner is disclosed. The preparation of inventive blend comprise reactive blending of polycarbonate, a vinyl (co)polymer and a novel compatibilizer in the presence of a transesterification catalyst and under conditions of time and temperature designed to promote transesterification. The compatibilizer is the polymerized reaction product of at least one vinyl monomer that contains no hydroxy groups and a hydroxyl containing monomer conforming to (I) where R denotes H or C1-C4 alkyl, R1 denotes H, Cl, Br, C1-C4 alkyl, cyclohexyl, or C1-C4 alkoxy, a is 0 or 1, b is 0 or 1, c is 0 or 1, n is an integer of 0 to 4 and X is an OH group. The compatible blends of the invention are characterized by their improved properties.

摘要翻译： 公开了聚碳酸酯树脂与乙烯基（共）聚合物共混配合物的相容共混物。 本发明共混物的制备包括聚酯，乙烯基（共）聚合物和新型增容剂在酯交换催化剂存在下和在设计用于促进酯交换反应的时间和温度的条件下的反应性共混。 增容剂是至少一种不含羟基的乙烯基单体和符合（I）的含羟基单体的聚合反应产物，其中R表示H或C1-C4烷基，R1表示H，Cl，Br，C1-C4烷基 ，环己基或C 1 -C 4烷氧基，a为0或1，b为0或1，c为0或1，n为0〜4的整数，X为OH基。 本发明的相容共混物的特征在于其改进的性能。