公开(公告)号：US20090156751A1

公开(公告)日：2009-06-18

申请号：US12254505

申请日：2008-10-20

申请人： Gwang Hoon Kwag ,  Pil Sung Kim ,  Seung Hwon Lee ,  Hyung Kyu Choi ,  Hyun Jin Kim

发明人： Gwang Hoon Kwag ,  Pil Sung Kim ,  Seung Hwon Lee ,  Hyung Kyu Choi ,  Hyun Jin Kim

IPC分类号： C08F36/06

CPC分类号： C08C19/44 ,  C08C19/20 ,  C08C19/22

摘要： The present invention relates to a preparation method of aromatic organosulfur functionalized 1,4-cis polybutadiene comprising: polymerizing 1,3-butadiene or butadiene derivative in the presence of a specific catalyst in a nonpolar solvent to prepare 1,4-cis polybutadiene; and reacting the resultant polybutadiene with an aromatic organosulfur compound. Such prepared aromatic organosulfur functionalized 1,4-cis polybutadiene is without ultrahigh molecular weight region and, thus, has narrow molecular weight distribution.

摘要翻译： 本发明涉及芳香族有机硫官能化1,4-顺式聚丁二烯的制备方法，其特征在于，在特定催化剂存在下，在非极性溶剂中聚合1,3-丁二烯或丁二烯衍生物，制备1,4-顺式聚丁二烯; 并使所得聚丁二烯与芳族有机硫化合物反应。 这种制备的芳族有机硫官能化1,4-顺式聚丁二烯不具有超高分子量区域，因此分子量分布窄。

公开(公告)号：US08198378B2

公开(公告)日：2012-06-12

申请号：US12254505

申请日：2008-10-20

申请人： Gwang Hoon Kwag ,  Pil Sung Kim ,  Seung Hwon Lee ,  Hyung Kyu Choi ,  Hyun Jin Kim

发明人： Gwang Hoon Kwag ,  Pil Sung Kim ,  Seung Hwon Lee ,  Hyung Kyu Choi ,  Hyun Jin Kim

IPC分类号： C08C19/20 ,  C08C19/22

CPC分类号： C08C19/44 ,  C08C19/20 ,  C08C19/22

摘要： The present invention relates to a preparation method of aromatic organosulfur functionalized 1,4-cis polybutadiene comprising: polymerizing 1,3-butadiene or butadiene derivative in the presence of a specific catalyst in a nonpolar solvent to prepare 1,4-cis polybutadiene; and reacting the resultant polybutadiene with an aromatic organosulfur compound. Such prepared aromatic organosulfur functionalized 1,4-cis polybutadiene is without ultrahigh molecular weight region and, thus, has narrow molecular weight distribution.

摘要翻译： 本发明涉及芳香族有机硫官能化1,4-顺式聚丁二烯的制备方法，其特征在于，在特定催化剂存在下，在非极性溶剂中聚合1,3-丁二烯或丁二烯衍生物，制备1,4-顺式聚丁二烯; 并使所得聚丁二烯与芳族有机硫化合物反应。 这种制备的芳族有机硫官能化1,4-顺式聚丁二烯不具有超高分子量区域，因此分子量分布窄。

公开(公告)号：US06586542B2

公开(公告)日：2003-07-01

申请号：US09817997

申请日：2001-03-27

申请人： Young-Chan Jang ,  Pil-Sung Kim ,  Gwang-Hoon Kwag ,  A-Ju Kim ,  Seung-Hwon Lee

发明人： Young-Chan Jang ,  Pil-Sung Kim ,  Gwang-Hoon Kwag ,  A-Ju Kim ,  Seung-Hwon Lee

IPC分类号： C08F470

CPC分类号： C08F136/06 ,  C08F4/7098

摘要： Disclosed is a process of controlling the degree of branch of high 1,4-cis polybutadiene without any alternation in the 1,4-cis content and the polymerization yield, in which a dialkylzinc compound represented by the following formula I is added in a controlled amount as an agent for controlling the degree of branch of high 1,4-cis polybutadiene, thus guaranteeing the optimum processability and physical properties of polymer according to the use purpose. R1—Zn—R2  Formula I wherein R1 and R2 are same or different and include an alkyl group containing 1 to 5 carbon atoms.

摘要翻译： 公开了一种控制高顺式1,4-顺式聚丁二烯的分支程度的方法，其中1,4-顺式含量和聚合产率没有任何变化，其中将下式I表示的二烷基锌化合物加入受控的 作为用于控制高1,4-顺式聚丁二烯分支度的试剂，因此根据用途保证了聚合物的最佳加工性能和物理性能。其中R1和R2相同或不同，并且包括含1个 至5个碳原子。

公开(公告)号：US06562917B2

公开(公告)日：2003-05-13

申请号：US09882824

申请日：2001-06-14

申请人： Young-Chan Jang ,  Pil-Sung Kim ,  Gwang-Hoon Kwag ,  A-Ju Kim ,  Seung-Hwon Lee

发明人： Young-Chan Jang ,  Pil-Sung Kim ,  Gwang-Hoon Kwag ,  A-Ju Kim ,  Seung-Hwon Lee

IPC分类号： C08F470

CPC分类号： C08F136/06 ,  C08F4/7098

摘要： A method for preparing polybutadiene having controlled molecular weight and high 1,4-cis content over 95% in the presence of a diethylzinc compound as a cocatalyst (i.e., alkylating agent) and molecular-weight-controlling agent, in which the molecular weight of the polybutadiene is controlled by variating the added amount of the diethylzinc compound without deterioration of 1,4-cis content nor polymerization yield, thus guaranteeing the optimum processability and physical properties of polymer according to the use purpose.

摘要翻译： 在二乙基锌化合物作为助催化剂（即烷基化剂）和分子量控制剂的存在下，制备具有受控分子量和高顺式含量超过95％的聚丁二烯的方法，其中分子量 通过改变二乙基锌化合物的添加量而不降低1,4-顺式含量而不降低聚合产率来控制聚丁二烯，从而根据用途保证聚合物的最佳加工性能和物理性能。

公开(公告)号：US06319806B1

公开(公告)日：2001-11-20

申请号：US09730811

申请日：2000-12-07

申请人： Pil-Sung Kim

发明人： Pil-Sung Kim

IPC分类号： H01L213205

CPC分类号： H01L29/66545 ,  H01L21/28061 ,  H01L21/32053 ,  H01L23/5226 ,  H01L27/10885 ,  H01L27/10891 ,  H01L2924/0002 ,  H01L2924/00

摘要： The present invention relates to an integrated circuit wiring capable of reducing the contact resistance between lines and a fabricating method thereof. The wiring in accordance with the present invention includes a gate oxide film formed on the upper surface of a semiconductor device. A first line including a first silicon film pattern that is formed on an upper surface of the gate oxide film and has a certain width; and a silicide film pattern that is formed on the upper surface of the first silicon film and has a smaller width than that of the first silicon film pattern to thereby expose a certain region of the first silicon film pattern. A second line is formed to contact the silicide film pattern and the exposed certain region of the silicon film pattern.

公开(公告)号：US07247695B2

公开(公告)日：2007-07-24

申请号：US10827001

申请日：2004-04-19

申请人： Gwang Hoon Kwag ,  Sam Min Kim ,  Young Chan Jang ,  Pil Sung Kim ,  Seung Hwon Lee ,  Seung Hwa Lee ,  A Ju Kim

发明人： Gwang Hoon Kwag ,  Sam Min Kim ,  Young Chan Jang ,  Pil Sung Kim ,  Seung Hwon Lee ,  Seung Hwa Lee ,  A Ju Kim

IPC分类号： C08F36/06 ,  C08F136/06

CPC分类号： C08L19/006 ,  C08C19/22 ,  C08C19/44 ,  C08F36/04 ,  C08L9/00 ,  C08L15/00 ,  C08F4/545

摘要： Disclosed is a novel high 1,4-cis polybutadiene-polyurethane copolymer and a preparation method thereof. The present invention provides a high 1,4-cis polybutadiene-polyurethane copolymer represented by the following formula 1 and having an average molecular weight of at least 100,000, and a method for preparing the high 1,4-cis polybutadiene-polyurethane copolymer that includes polymerizing 1,3-butadiene or butadiene derivatives with a catalyst comprising a rare earth compound, a halogen-containing compound and an organoaluminum compound in the presence of a non-polar solvent, to prepare a polybutadiene having a high 1,4-cis content of at least 95%; and then introducing a polyurethane group to the polybutadiene. The high 1,4-cis polybutadiene-polyurethane copolymer thus obtained exhibits low cold flow and high affinity to silica or carbon black in admixture as well as excellent in elasticity and abrasion resistance: where l, m, n and o represent the number of repeating unit, 1 is 94 to 99%, m is 0 to 5%, n is 0 to 5%, l+m+n=100%, l/(m+n) is 15 to 100, o is 1 to 100%; and A and Y are C1-C20 alkyl or aryl, respectively.

摘要翻译： 公开了一种新型高1,4-顺式聚丁二烯 - 聚氨酯共聚物及其制备方法。 本发明提供由下式1表示的平均分子量至少为100,000的高1,4-顺式聚丁二烯 - 聚氨酯共聚物，以及制备高1,4-顺式聚丁二烯 - 聚氨酯共聚物的方法，其包括 在非极性溶剂的存在下，用含有稀土类化合物，含卤素化合物和有机铝化合物的催化剂聚合1,3-丁二烯或丁二烯衍生物，制备具有高1,4-顺式含量的聚丁二烯 至少95％; 然后将聚氨酯基团引入聚丁二烯。 由此获得的高1,4-顺式聚丁二烯 - 聚氨酯共聚物表现出低的冷流和对二氧化硅或炭黑的高亲和性，并且具有优异的弹性和耐磨性：其中l，m，n和o表示重复的数目 单元，1为94〜99％，m为0〜5％，n为0〜5％，l + m + n = 100％，l /（m + n）为15〜100，o为1〜100％ ; A和Y分别为C 1 -C 20烷基或芳基。

公开(公告)号：US06908975B2

公开(公告)日：2005-06-21

申请号：US10653542

申请日：2003-09-02

申请人： Young Chan Jang ,  Pil Sung Kim ,  Shin Han ,  Gwang Hoon Kwag ,  Seung Hwon Lee

发明人： Young Chan Jang ,  Pil Sung Kim ,  Shin Han ,  Gwang Hoon Kwag ,  Seung Hwon Lee

IPC分类号： C08F36/06 ,  C08F136/06

CPC分类号： C08F136/06 ,  C08F4/545

摘要： The present invention relates to a method for preparing a high 1,4-cis polybutadiene having a controlled cold flow and, more particularly, to a novel method for preparing a high 1,4-cis polybutadiene having a controlled cold flow that involves initiating polymerization of a 1,3-butadiene in the presence of a non-polar solvent using, as a polymerization catalyst, a complex prepared by mixing a neodymium compound with or without a conjugated diene compound, a halogenated organoaluminum compound or a halogenated organic compound, and an organoaluminum compound irrespective of the addition order of the catalyst; and adding an organoborane compound as a cold flow controller of 1,4-cis polybutadiene after a predetermined time of the polymerization. Accordingly, a high 1,4-cis polybutadiene having an efficiently controlled cold flow can be prepared without causing a significant increase in the Mooney viscosity (molecular weight), an odor (bad smell), and a reduction in 1,4-cis content and polymerization yield.

摘要翻译： 本发明涉及一种制备具有受控冷流的高1,4-顺式聚丁二烯的方法，更具体地说，涉及一种制备具有控制冷流的高1,4-顺式聚丁二烯的新方法，其涉及引发聚合 使用作为聚合催化剂的非极性溶剂存在下的1,3-丁二烯，通过将钕化合物与或不与共轭二烯化合物，卤化有机铝化合物或卤化有机化合物混合制备的络合物和 有机铝化合物，而不考虑催化剂的加成顺序; 并在预定的聚合时间之后加入有机硼烷化合物作为1,4-顺式聚丁二烯的冷流控制器。 因此，可以制备具有有效控制的冷流的高的1,4-顺式聚丁二烯，而不会导致门尼粘度（分子量），气味（难闻气味）的显着增加和1,4-顺式含量的降低 和聚合产率。

公开(公告)号：US06252021B1

公开(公告)日：2001-06-26

申请号：US09447866

申请日：1999-11-23

申请人： Kwanyoung Lee ,  Pil Sung Kim ,  IL Sang Maeng ,  Jong Mok Kim

发明人： Kwanyoung Lee ,  Pil Sung Kim ,  IL Sang Maeng ,  Jong Mok Kim

IPC分类号： C08F4649

CPC分类号： C08F110/10 ,  C08F10/00 ,  C08F4/6428 ,  C08F4/6494 ,  C08F4/20 ,  C08F4/6495 ,  C08F4/16 ,  C08F4/651 ,  C08F4/00 ,  C08F2500/03 ,  C08F2500/04

摘要： This invention relates to a process for polymerizing isobutene using a catalytic system comprising a transition metal compound, a benzene derivative compound, and methylaluminoxane, and the catalytic system applied to the polymerization of isobutene, (1) the added benzene derivative compound and methyl aluminoxane to the transition metal species provides higher stability of cation active site so that polyisobutene with a high molecular weight can be produced even at a higher reaction temperature than the conventional cationic polymerization temperature; (2) nonhalogen solvent such as toluene can be employed as a polymerization solvent instead of halogenated solvents such as methyl chloride; and (3) under the stable catalytic system, a final product with a high yield can be ensured for its long-term use.

摘要翻译： 本发明涉及使用包含过渡金属化合物，苯衍生物化合物和甲基铝氧烷的催化体系以及应用于异丁烯聚合的催化体系来聚合异丁烯的方法，（1）所添加的苯衍生物化合物和甲基铝氧烷， 过渡金属物质提供更高的阳离子活性位点的稳定性，使得即使在比常规阳离子聚合温度更高的反应温度下也可以产生高分子量的聚异丁烯; （2）非卤素溶剂如甲苯可用作聚合溶剂而不是卤代溶剂如氯甲烷; 和（3）在稳定的催化体系下，长期使用可以保证高产率的最终产品。