公开(公告)号：US08580702B2

公开(公告)日：2013-11-12

申请号：US12513261

申请日：2007-11-02

Applicant: Zaiku Xie ,  Dejin Kong ,  Zhirong Zhu ,  Wei Li ,  Qingling Chen ,  Rong Zhang

Inventor： Zaiku Xie ,  Dejin Kong ,  Zhirong Zhu ,  Wei Li ,  Qingling Chen ,  Rong Zhang

IPC: B01J29/06 ,  C07C5/22

CPC classification number: B01J37/0009 ,  B01J21/063 ,  B01J21/08 ,  B01J29/405 ,  B01J29/46 ,  B01J29/48 ,  B01J35/023 ,  B01J37/0207 ,  B01J37/08 ,  B01J37/30 ,  B01J2229/12 ,  B01J2229/32 ,  B01J2229/42 ,  C07C6/12 ,  C07C2529/46 ,  Y02P20/52 ,  C07C15/08

Abstract: The present invention discloses a catalyst for toluene shape selective disproportionation, comprising: a) 45 to 95 wt % of ZSM-5 molecular sieve having an average particle size of from 0.3 to 6 μm and a molar ratio of SiO2 to Al2O3 of from 20 to 120; b) 0.01 to 30 wt % of at least one metal selected from the group consisting of Group IIB metals, Group IIIB metals, rare earth elements and Group VIII metals other than nickel, or oxide(s) thereof; c) 0 to 20 wt % of at least one metal selected from the group consisting of Group VA metals, Group VIB metals and alkaline earth metals, or oxide(s) thereof; d) 1 to 25 wt % of a silica inert surface coating derived from an organopolysiloxane; and e) 1 to 50 wt % of a binder. The present invention further discloses a process for shape selectively disproportionating toluene into p-xylene, comprising contacting a reaction stream containing toluene with the catalyst for toluene shape selective disproportionation under toluene disproportionation conditions.

Abstract translation: 本发明公开了一种用于甲苯形状选择性歧化的催化剂，其包含：a）45〜95重量％的平均粒径为0.3〜6μm的ZSM-5分子筛，SiO 2与Al 2 O 3的摩尔比为20〜 120; b）0.01〜30重量％的选自由IIB族金属，IIIB族金属，稀土元素和第Ⅷ族金属以外的至少一种金属，或其氧化物; c）0至20重量％的至少一种选自第VA族金属，VIB族金属和碱土金属或其氧化物的金属; d）1至25重量％的衍生自有机聚硅氧烷的二氧化硅惰性表面涂层; 和e）1〜50重量％的粘合剂。 本发明还公开了一种将甲苯选择性歧化成对二甲苯的方法，包括在甲苯歧化条件下使含有甲苯的反应物流与用于甲苯形状选择性歧化的催化剂接触。

公开(公告)号：US20100048382A1

公开(公告)日：2010-02-25

申请号：US12513261

申请日：2007-11-02

Applicant: Zaiku Xie ,  Dejin Kong ,  Zhirong Zhu ,  Wei Li ,  Qingling Chen ,  Rong Zhang

Inventor： Zaiku Xie ,  Dejin Kong ,  Zhirong Zhu ,  Wei Li ,  Qingling Chen ,  Rong Zhang

IPC: B01J29/04

CPC classification number: B01J37/0009 ,  B01J21/063 ,  B01J21/08 ,  B01J29/405 ,  B01J29/46 ,  B01J29/48 ,  B01J35/023 ,  B01J37/0207 ,  B01J37/08 ,  B01J37/30 ,  B01J2229/12 ,  B01J2229/32 ,  B01J2229/42 ,  C07C6/12 ,  C07C2529/46 ,  Y02P20/52 ,  C07C15/08

Abstract: The present invention discloses a catalyst for toluene shape selective disproportionation, comprising: a) 45 to 95 wt % of ZSM-5 molecular sieve having an average particle size of from 0.3 to 6 μm and a molar ratio of SiO2 to Al2O3 of from 20 to 120; b) 0.01 to 30 wt % of at least one metal selected from the group consisting of Group IIB metals, Group IIIB metals, rare earth elements and Group VIII metals other than nickel, or oxide(s) thereof; c) 0 to 20 wt % of at least one metal selected from the group consisting of Group VA metals, Group VIB metals and alkaline earth metals, or oxide(s) thereof; d) 1 to 25 wt % of a silica inert surface coating derived from an organopolysiloxane; and e) 1 to 50 wt % of a binder. The present invention further discloses a process for shape selectively disproportionating toluene into p-xylene, comprising contacting a reaction stream containing toluene with the catalyst for toluene shape selective disproportionation under toluene disproportionation conditions.

Abstract translation: 本发明公开了一种用于甲苯形状选择性歧化的催化剂，其包含：a）45〜95重量％的ZSM-5分子筛，其平均粒度为0.3〜6μm，SiO 2与Al 2 O 3的摩尔比为20〜 120; b）0.01〜30重量％的选自由IIB族金属，IIIB族金属，稀土元素和第Ⅷ族金属以外的至少一种金属，或其氧化物; c）0至20重量％的至少一种选自第VA族金属，VIB族金属和碱土金属或其氧化物的金属; d）1至25重量％的衍生自有机聚硅氧烷的二氧化硅惰性表面涂层; 和e）1〜50重量％的粘合剂。 本发明还公开了一种将甲苯选择性歧化成对二甲苯的方法，包括在甲苯歧化条件下使含有甲苯的反应物流与用于甲苯形状选择性歧化的催化剂接触。

公开(公告)号：US07494951B2

公开(公告)日：2009-02-24

申请号：US11503184

申请日：2006-08-14

Applicant: Zhirong Zhu ,  Dejin Kong ,  Weimin Yang ,  Qingling Chen ,  Wei Zou ,  Wei Li ,  Min Hou ,  Deqin Yang

Inventor： Zhirong Zhu ,  Dejin Kong ,  Weimin Yang ,  Qingling Chen ,  Wei Zou ,  Wei Li ,  Min Hou ,  Deqin Yang

IPC: B01J29/06

CPC classification number: B01J29/40 ,  B01J31/0274 ,  B01J37/0209 ,  B01J2229/12 ,  B01J2229/32 ,  B01J2229/42

Abstract: The present invention relates to a process for the manufacture of catalysts used for producing para-xylene by toluene shape selective alkylation. The invention is primarily used for solving the problems in the old technology, e.g., high requirements on the environment and great treatment of waste water containing organic amines when synthesizing ZSM-5 molecular sieves by using an organic amine as the template agent; small and non-homogeneous particles of the molecular sieves when synthesizing ZSM-5 molecular sieves by using an alcohol or ether as the template agent, such that the catalyst prepared thereby has low catalytic selectivity and low toluene conversion rate, etc. Said problems are better solved in the present invention by synthesizing ZSM-5 molecular sieves using the combination of organic amines and alcohols or ethers as the template agents (having a weight ratio of organic amines/alcohols=0.05-150, and organic amines/ethers=0.05-150), and modifying with organosilicon so as to obtain the catalysts. Said catalysts can be used in the industrial production of para-xylene manufactured by toluene shape selective alkylation.

Abstract translation: 本发明涉及制备用于通过甲苯选择性烷基化生产对二甲苯的催化剂的方法。 本发明主要用于解决老技术中的问题，例如对于通过使用有机胺作为模板剂合成ZSM-5分子筛时对环境的高要求和含有有机胺的废水的大量处理; 通过使用醇或醚作为模板剂合成ZSM-5分子筛时，分子筛的小而非均匀的颗粒，使得由此制备的催化剂具有低催化选择性和低甲苯转化率等。所述问题更好 通过使用有机胺和醇或醚的组合作为模板剂（具有有机胺/醇的重量比= 0.05-150，有机胺/醚= 0.05-150）合成ZSM-5分子筛来解决本发明 ），并用有机硅改性以获得催化剂。 所述催化剂可用于通过甲苯选择性烷基化制造的对二甲苯的工业生产。

公开(公告)号：US20070037693A1

公开(公告)日：2007-02-15

申请号：US11503184

申请日：2006-08-14

Applicant: Zhirong Zhu ,  Dejin Kong ,  Weimin Yang ,  Qingling Chen ,  Wei Zou ,  Wei Li ,  Min Hou ,  Deqin Yang

Inventor： Zhirong Zhu ,  Dejin Kong ,  Weimin Yang ,  Qingling Chen ,  Wei Zou ,  Wei Li ,  Min Hou ,  Deqin Yang

IPC: B01J29/04

CPC classification number: B01J29/40 ,  B01J31/0274 ,  B01J37/0209 ,  B01J2229/12 ,  B01J2229/32 ,  B01J2229/42

Abstract: The present invention relates to a process for the manufacture of catalysts used for producing para-xylene by toluene shape selective alkylation. The invention is primarily used for solving the problems in the old technology, e.g., high requirements on the environment and great treatment of waste water containing organic amines when synthesizing ZSM-5 molecular sieves by using an organic amine as the template agent; small and non-homogeneous particles of the molecular sieves when synthesizing ZSM-5 molecular sieves by using an alcohol or ether as the template agent, such that the catalyst prepared thereby has low catalytic selectivity and low toluene conversion rate, etc. Said problems are better solved in the present invention by synthesizing ZSM-5 molecular sieves using the combination of organic amines and alcohols or ethers as the template agents (having a weight ratio of organic amines/alcohols=0.05-150, and organic amines/ethers=0.05-150), and modifying with organosilicon so as to obtain the catalysts. Said catalysts can be used in the industrial production of para-xylene manufactured by toluene shape selective alkylation.

Abstract translation: 本发明涉及制备用于通过甲苯选择性烷基化生产对二甲苯的催化剂的方法。 本发明主要用于解决老技术中的问题，例如对于通过使用有机胺作为模板剂合成ZSM-5分子筛时对环境的高要求和含有有机胺的废水的大量处理; 通过使用醇或醚作为模板剂合成ZSM-5分子筛时，分子筛的小而非均匀的颗粒，使得由此制备的催化剂具有低催化选择性和低甲苯转化率等。所述问题更好 通过使用有机胺和醇或醚的组合作为模板剂（具有有机胺/醇的重量比= 0.05-150，有机胺/醚= 0.05-150）合成ZSM-5分子筛来解决本发明 ），并用有机硅改性以获得催化剂。 所述催化剂可用于通过甲苯选择性烷基化制造的对二甲苯的工业生产。

公开(公告)号：US09221039B2

公开(公告)日：2015-12-29

申请号：US13878662

申请日：2011-10-11

Applicant: Min Lin ,  Hua Li ,  Wei Wang ,  Chijian He ,  Xiaoju Wu ,  Jizao Gao ,  Xichun She ,  Jun Long ,  Qingling Chen

Inventor： Min Lin ,  Hua Li ,  Wei Wang ,  Chijian He ,  Xiaoju Wu ,  Jizao Gao ,  Xichun She ,  Jun Long ,  Qingling Chen

IPC: B01J29/89 ,  C07D301/12 ,  B01J35/00

CPC classification number: B01J29/89 ,  B01J35/002 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/42 ,  C07D301/12

Abstract: Disclosed herein are a catalyst, a preparation process thereof, and a process of epoxidizing olefin using the catalyst. The catalyst contains a binder and a titanium silicate as specified. The catalyst disclosed herein has high strength, and shows high catalytic activity in the epoxidation of olefins.

Abstract translation: 本文公开了催化剂，其制备方法和使用该催化剂使烯烃环氧化的方法。 催化剂含有粘合剂和钛硅酸盐。 本文公开的催化剂具有高强度，并且在烯烃的环氧化中显示出高的催化活性。

公开(公告)号：US20130253208A1

公开(公告)日：2013-09-26

申请号：US13878662

申请日：2011-10-11

Applicant: Min Lin ,  Hua Li ,  Wei Wang ,  Chijian He ,  Xiaoju Wu ,  Jizao Gao ,  Xichun She ,  Jun Long ,  Qingling Chen

Inventor： Min Lin ,  Hua Li ,  Wei Wang ,  Chijian He ,  Xiaoju Wu ,  Jizao Gao ,  Xichun She ,  Jun Long ,  Qingling Chen

IPC: B01J29/89 ,  C07D301/12

CPC classification number: B01J29/89 ,  B01J35/002 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/42 ,  C07D301/12

Abstract: The present invention provides a catalyst and the preparation process thereof and a process of epoxidising olefin using the catalyst. The catalyst contains a binder and a titanium silicate, the binder being an amorphous silica, the titanium silicate having a MFI structure, and the crystal grain of the titanium silicate having a hollow structure, with a radial length of 5-300 nm for the cavity portion of the hollow structure, wherein the adsorption capacity of benzene measured for the titanium silicate under the conditions of 25 degrees C., P/P0=0.10 and 1 h of adsorption time is at least 70 mg/g, and there is a hysteresis loop between the adsorption isotherm and the desorption isotherm for nitrogen adsorption by the molecular sieve at a low temperature; wherein based on the total amount of the catalyst, the content of the binder is 3-15 wt %, and the content of the titanium silicate is 85-97 wt %; and the catalyst has a crushing strength value of not less than 60 N/cm measured according to GB3635-1983 standard method. The catalyst according to the present invention has high strength, and shows high catalytic activity in the epoxidation of olefins.

Abstract translation: 本发明提供一种催化剂及其制备方法以及使用该催化剂使烯烃环氧化的方法。 催化剂含有粘合剂和钛硅酸盐，粘合剂是无定形二氧化硅，具有MFI结构的硅酸钛和具有中空结构的硅酸钛的晶粒，其中腔的径向长度为5-300nm 部分中空结构，其中在25℃，P / P0 = 0.10和1小时的吸附时间条件下测量的硅酸钛的苯的吸附能力为至少70mg / g，并且存在滞后 吸附等温线和分子筛在低温下氮吸附的解吸等温线之间的循环; 其中，基于催化剂的总量，粘合剂的含量为3〜15重量％，硅酸钛的含量为85〜97重量％。 催化剂的破碎强度值按照GB3635-1983标准方法测定，不小于60N / cm。 根据本发明的催化剂具有高强度，并且在烯烃的环氧化中显示出高的催化活性。