公开(公告)号：US20110094627A1

公开(公告)日：2011-04-28

申请号：US12912505

申请日：2010-10-26

申请人： John R. Peterson ,  Narasimha-Rao V. Bangaru ,  Robert Lee Antram ,  Christopher John Fowler ,  Neeraj S. Thirumalai ,  ChangMin Chun ,  Emery B. Lendvai-Lintner

发明人： John R. Peterson ,  Narasimha-Rao V. Bangaru ,  Robert Lee Antram ,  Christopher John Fowler ,  Neeraj S. Thirumalai ,  ChangMin Chun ,  Emery B. Lendvai-Lintner

IPC分类号： C23C8/30 ,  C23C8/20 ,  C23C8/28 ,  C23C8/24 ,  C23C8/08 ,  C23C8/12

CPC分类号： C22C29/04 ,  C22C29/12 ,  C22C29/14 ,  C22C29/16 ,  Y10T29/49826

摘要： The present invention is directed to a method for protecting metal surfaces in oil & gas exploration and production, refinery and petrochemical process applications subject to solid particulate erosion at temperatures of up to 1000° C. The method includes the step of providing the metal surfaces in such applications with a hot erosion resistant cermet lining or insert, wherein the cermet lining or insert includes a) about 30 to about 95 vol % of a ceramic phase, and b) a metal binder phase, wherein the cermet lining or insert has a HEAT erosion resistance index of at least 5.0 and a K1C fracture toughness of at least 7.0 MPa-m1/2. The metal surfaces may also be provided with a hot erosion resistant cermet coating having a HEAT erosion resistance index of at least 5.0. Advantages provided by the method include, inter alia, outstanding high temperature erosion and corrosion resistance in combination with outstanding fracture toughness, as well as outstanding thermal expansion compatibility to the base metal of process units. The method finds particular application for protecting process vessels, transfer lines and process piping, heat exchangers, cyclones, slide valve gates and guides, feed nozzles, aeration nozzles, thermo wells, valve bodies, internal risers, deflection shields, sand screen, and oil sand mining equipment.

摘要翻译： 本发明涉及一种用于在高达1000℃的温度下保护固体颗粒物侵蚀的石油和天然气勘探和生产，炼油和石化工艺应用中的金属表面的保护方法。该方法包括以下步骤： 具有耐热蚀金属陶瓷衬里或插入物的这种应用，其中金属陶瓷衬里或插入物包括a）约30至约95体积％的陶瓷相，和b）金属粘合剂相，其中金属陶瓷衬里或插入物具有热 耐蚀性指数至少为5.0，K1C断裂韧度至少为7.0MPa-m1 / 2。 金属表面还可以具有耐热腐蚀金属陶瓷涂层，其耐热侵蚀性指数至少为5.0。 该方法提供的优点尤其包括优异的耐高温侵蚀和耐腐蚀性以及突出的断裂韧性，以及与处理单元的母材的突出的热膨胀相容性。 该方法特别适用于保护过程容器，输送管线和过程管道，热交换器，旋风分离器，滑阀门和引导件，进料嘴，曝气喷嘴，热阱，阀体，内部立管，偏转屏蔽，砂筛和油 采砂设备。

公开(公告)号：US20080276757A1

公开(公告)日：2008-11-13

申请号：US10829823

申请日：2004-04-22

申请人： Narasimha-Rao Venkata Bangaru ,  ChangMin Chun ,  Neeraj Srinivas Thirumalai ,  Shiun Ling ,  Hyun-Woo Jin ,  Jayoung Koo ,  John Roger Peterson ,  Robert Lee Antram ,  Christopher John Fowler

发明人： Narasimha-Rao Venkata Bangaru ,  ChangMin Chun ,  Neeraj Srinivas Thirumalai ,  Shiun Ling ,  Hyun-Woo Jin ,  Jayoung Koo ,  John Roger Peterson ,  Robert Lee Antram ,  Christopher John Fowler

IPC分类号： C22C29/08

CPC分类号： C22C29/067

摘要： Cermets are provided in which the ceramic phase is selected from the group consisting of Cr23C6, Cr7C3, Cr3C2 and mixtures thereof. The binder phase is selected from certain specified Ni/Cr alloys and certain Fe/Ni/Cr alloys. These cermets are particularly useful in protecting surfaces from erosion at high temperatures.

摘要翻译： 提供了金属陶瓷，其中陶瓷相选自Cr 23 C 6 C 6 C 6 C 7 C 6， SUB 3，Cr 3 3 C 2和它们的混合物。 粘结相选自某些特定的Ni / Cr合金和某些Fe / Ni / Cr合金。 这些金属陶瓷特别适用于在高温下保护表面免受侵蚀。

公开(公告)号：US20080003125A1

公开(公告)日：2008-01-03

申请号：US11479680

申请日：2006-06-30

申请人： John R. Peterson ,  Narasimha-Rao V. Bangaru ,  Robert Lee Antram ,  Christopher John Fowler ,  Neeraj S. Thirumalai ,  ChangMin Chun ,  Emery B. Lendvai-Lintner

发明人： John R. Peterson ,  Narasimha-Rao V. Bangaru ,  Robert Lee Antram ,  Christopher John Fowler ,  Neeraj S. Thirumalai ,  ChangMin Chun ,  Emery B. Lendvai-Lintner

IPC分类号： B22F7/00

CPC分类号： C22C29/04 ,  C22C29/12 ,  C22C29/14 ,  C22C29/16 ,  Y10T29/49826

摘要： The present invention is directed to a method for protecting metal surfaces in oil & gas exploration and production, refinery and petrochemical process applications subject to solid particulate erosion at temperatures of up to 1000° C. The method includes the step of providing the metal surfaces in such applications with a hot erosion resistant cermet lining or insert, wherein the cermet lining or insert includes a) about 30 to about 95 vol % of a ceramic phase, and b) a metal binder phase, wherein the cermet lining or insert has a HEAT erosion resistance index of at least 5.0 and a K1C fracture toughness of at least 7.0 MPa-m 1/2. The metal surfaces may also be provided with a hot erosion resistant cermet coating having a HEAT erosion resistance index of at least 5.0. Advantages provided by the method include, inter alia, outstanding high temperature erosion and corrosion resistance in combination with outstanding fracture toughness, as well as outstanding thermal expansion compatibility to the base metal of process units. The method finds particular application for protecting process vessels, transfer lines and process piping, heat exchangers, cyclones, slide valve gates and guides, feed nozzles, aeration nozzles, thermo wells, valve bodies, internal risers, deflection shields, sand screen, and oil sand mining equipment.

摘要翻译： 本发明涉及一种用于在高达1000℃的温度下保护固体颗粒物侵蚀的石油和天然气勘探和生产，炼油和石化工艺应用中的金属表面的保护方法。该方法包括以下步骤： 具有耐热侵蚀金属陶瓷衬里或插入物的这种应用，其中金属陶瓷衬里或插入物包括a）约30至约95体积％的陶瓷相，和b）金属粘合剂相，其中金属陶瓷衬里或插入物具有热 至少5.0的耐冲击性指数和至少7.0MPa-m 1/2的K 1C断裂韧性。 金属表面还可以具有耐热腐蚀金属陶瓷涂层，其耐热侵蚀性指数至少为5.0。 该方法提供的优点尤其包括优异的耐高温侵蚀和耐腐蚀性以及突出的断裂韧性，以及与处理单元的母材的突出的热膨胀相容性。 该方法特别适用于保护过程容器，输送管线和过程管道，热交换器，旋风分离器，滑阀门和引导件，进料嘴，曝气喷嘴，热阱，阀体，内部立管，偏转屏蔽，砂筛和油 采砂设备。

公开(公告)号：US07247186B1

公开(公告)日：2007-07-24

申请号：US10829820

申请日：2004-04-22

申请人： ChangMin Chun ,  Narasimha-Rao Venkata Bangaru ,  Hyun-Woo Jin ,  Jayoung Koo ,  John Roger Peterson ,  Robert Lee Antram ,  Christopher John Fowler

发明人： ChangMin Chun ,  Narasimha-Rao Venkata Bangaru ,  Hyun-Woo Jin ,  Jayoung Koo ,  John Roger Peterson ,  Robert Lee Antram ,  Christopher John Fowler

IPC分类号： C22C29/04

CPC分类号： C23C30/00 ,  C22C29/04

摘要： The invention includes a cermet composition represented by the formula (PQ) (RS) comprising: a ceramic phase (PQ) and a binder phase (RS) wherein, P is a metal selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Fe, Mn and mixtures thereof, Q is carbonitride, R is a metal selected from the group consisting of Fe, Ni, Co, Mn and mixtures thereof, S comprises at least one element selected from Cr, Al, Si and Y.

摘要翻译： 本发明包括由式（PQ）（RS）表示的金属陶瓷组合物，其包含：陶瓷相（PQ）和粘结相（RS），其中P是选自Ti，Zr，Hf，V ，Nb，Ta，Cr，Mo，W，Fe，Mn及其混合物，Q为碳氮化物，R为选自Fe，Ni，Co，Mn及其混合物的金属，S包含至少一种选自 来自Cr，Al，Si和Y.

公开(公告)号：US08323423B2

公开(公告)日：2012-12-04

申请号：US12912505

申请日：2010-10-26

申请人： John Roger Peterson ,  Narasimha-Rao Venkata Bangaru ,  Robert Lee Antram ,  Christopher John Fowler ,  Neeraj Srinivas Thirumalai ,  ChangMin Chun ,  Emery Bela Lendvai-Lintner

发明人： John Roger Peterson ,  Narasimha-Rao Venkata Bangaru ,  Robert Lee Antram ,  Christopher John Fowler ,  Neeraj Srinivas Thirumalai ,  ChangMin Chun ,  Emery Bela Lendvai-Lintner

IPC分类号： C23C8/30 ,  C23C8/04

CPC分类号： C22C29/04 ,  C22C29/12 ,  C22C29/14 ,  C22C29/16 ,  Y10T29/49826

摘要： The present invention is directed to a method for protecting metal surfaces in oil & gas exploration and production, refinery and petrochemical process applications subject to solid particulate erosion at temperatures of up to 1000° C. The method includes the step of providing the metal surfaces in such applications with a hot erosion resistant cermet lining or insert, wherein the cermet lining or insert includes a) about 30 to about 95 vol % of a ceramic phase, and b) a metal binder phase, wherein the cermet lining or insert has a HEAT erosion resistance index of at least 5.0 and a K1C fracture toughness of at least 7.0 MPa-m1/2. The metal surfaces may also be provided with a hot erosion resistant cermet coating having a HEAT erosion resistance index of at least 5.0.

公开(公告)号：US20110104383A1

公开(公告)日：2011-05-05

申请号：US12912577

申请日：2010-10-26

申请人： JOHN ROGER PETERSON ,  NARASIMHA-RAO V. BANGARU ,  ROBERT LEE ANTRAM ,  CHRISTOPHER JOHN FOWLER ,  NEERAJ S. THIRUMALAI ,  CHANGMIN CHUN ,  EMERY B. LENDVAI-LINTNER

发明人： JOHN ROGER PETERSON ,  NARASIMHA-RAO V. BANGARU ,  ROBERT LEE ANTRAM ,  CHRISTOPHER JOHN FOWLER ,  NEERAJ S. THIRUMALAI ,  CHANGMIN CHUN ,  EMERY B. LENDVAI-LINTNER

IPC分类号： C23C4/10 ,  C23C4/12 ,  H05H1/48 ,  B05D7/22 ,  B05D5/00 ,  B05D1/02 ,  B23P11/00

CPC分类号： C22C29/04 ,  C22C29/12 ,  C22C29/14 ,  C22C29/16 ,  Y10T29/49826

摘要： The present invention is directed to a method for protecting metal surfaces in oil & gas exploration and production, refinery and petrochemical process applications subject to solid particulate erosion at temperatures of up to 1000° C. The method includes the step of providing the metal surfaces in such applications with a hot erosion resistant cermet lining or insert, wherein the cermet lining or insert includes a) about 30 to about 95 vol % of a ceramic phase, and b) a metal binder phase, wherein the cermet lining or insert has a HEAT erosion resistance index of at least 5.0 and a K1C fracture toughness of at least 7.0 MPa-m1/2. The metal surfaces may also be provided with a hot erosion resistant cermet coating having a HEAT erosion resistance index of at least 5.0. Advantages provided by the method include, inter alia, outstanding high temperature erosion and corrosion resistance in combination with outstanding fracture toughness, as well as outstanding thermal expansion compatibility to the base metal of process units. The method finds particular application for protecting process vessels, transfer lines and process piping, heat exchangers, cyclones, slide valve gates and guides, feed nozzles, aeration nozzles, thermo wells, valve bodies, internal risers, deflection shields, sand screen, and oil sand mining equipment.

公开(公告)号：US20080257454A1

公开(公告)日：2008-10-23

申请号：US10829818

申请日：2004-04-22

申请人： ChangMin Chun ,  Narasimha-Rao Venkata Bangaru ,  Hyun-Woo Jin ,  Jayoung Koo ,  John Roger Peterson ,  Robert Lee Antram ,  Christopher John Fowler

发明人： ChangMin Chun ,  Narasimha-Rao Venkata Bangaru ,  Hyun-Woo Jin ,  Jayoung Koo ,  John Roger Peterson ,  Robert Lee Antram ,  Christopher John Fowler

IPC分类号： C23C8/00

CPC分类号： C23C8/22

摘要： Cermets, particularly composition gradient cermets can be prepared starting with suitable bulk metal alloys by a reactive heat treatment process involving a reactive environment selected from the group consisting of reactive carbon, reactive nitrogen, reactive boron, reactive oxygen and mixtures thereof.

摘要翻译： 金属陶瓷，特别是组成梯度金属陶瓷可以通过涉及选自反应性碳，活性氮，活性硼，活性氧及其混合物的反应性环境的反应性热处理方法从合适的块状金属合金开始制备。

公开(公告)号：US10047298B2

公开(公告)日：2018-08-14

申请号：US14641903

申请日：2015-03-09

申请人： Christopher S. Hinson ,  Christopher John Fowler ,  David Scott Sinclair ,  Adam Garrett Susong ,  Robert Lee Antram ,  John Roger Peterson

发明人： Christopher S. Hinson ,  Christopher John Fowler ,  David Scott Sinclair ,  Adam Garrett Susong ,  Robert Lee Antram ,  John Roger Peterson

IPC分类号： C10G9/18 ,  C10G9/00 ,  C10B1/04 ,  C10G9/04 ,  C10B55/00 ,  C10B39/06 ,  C10B43/14 ,  C10B57/04 ,  C10B57/08

摘要： A delayed coking unit has a thermal shock-resistant, erosion-resistant internal lining to reduce thermally-induced mechanical stresses in the pressure boundary of the coke drum. The lining is effective to reduce or mitigate the transient thermal stress that occurs in the pressure boundary of the coke drum and to reduce or minimize the high thermal stress resulting from temperature differentials at the skirt-to-shell junction.

公开(公告)号：US08317940B2

公开(公告)日：2012-11-27

申请号：US12912577

申请日：2010-10-26

申请人： John Roger Peterson ,  Narasimha-Rao Venkata Bangaru ,  Robert Lee Antram ,  Christopher John Fowler ,  Neeraj Srinivas Thirumalai ,  ChangMin Chun ,  Emery Bela Lendvai-Lintner

发明人： John Roger Peterson ,  Narasimha-Rao Venkata Bangaru ,  Robert Lee Antram ,  Christopher John Fowler ,  Neeraj Srinivas Thirumalai ,  ChangMin Chun ,  Emery Bela Lendvai-Lintner

IPC分类号： C23C8/30 ,  C23C8/04

CPC分类号： C22C29/04 ,  C22C29/12 ,  C22C29/14 ,  C22C29/16 ,  Y10T29/49826

摘要： The present invention is directed to a method for protecting metal surfaces in oil & gas exploration and production, refinery and petrochemical process applications subject to solid particulate erosion at temperatures of up to 1000° C. The method includes the step of providing the metal surfaces in such applications with a hot erosion resistant cermet lining or insert, wherein the cermet lining or insert includes a) about 30 to about 95 vol % of a ceramic phase, and b) a metal binder phase, wherein the cermet lining or insert has a HEAT erosion resistance index of at least 5.0 and a K1C fracture toughness of at least 7.0 MPa-m1/2. The metal surfaces may also be provided with a hot erosion resistant cermet coating having a HEAT erosion resistance index of at least 5.0.

摘要翻译： 本发明涉及一种用于在高达1000℃的温度下保护固体颗粒物侵蚀的石油和天然气勘探和生产，炼油和石化工艺应用中的金属表面的保护方法。该方法包括以下步骤： 具有耐热蚀金属陶瓷衬里或插入物的这种应用，其中金属陶瓷衬里或插入物包括a）约30至约95体积％的陶瓷相，和b）金属粘合剂相，其中金属陶瓷衬里或插入物具有热 耐蚀性指数至少为5.0，K1C断裂韧度至少为7.0MPa-m1 / 2。 金属表面还可以具有耐热腐蚀金属陶瓷涂层，其耐热侵蚀性指数至少为5.0。

公开(公告)号：US20120177933A1

公开(公告)日：2012-07-12

申请号：US11879354

申请日：2007-07-17

申请人： Narasimha-Rao Venkata Bangaru ,  Jayoung Koo ,  ChangMin Chun ,  Hyun-Woo Jin ,  John Roger Peterson ,  Robert Lee Antram ,  Christopher John Fowler

发明人： Narasimha-Rao Venkata Bangaru ,  Jayoung Koo ,  ChangMin Chun ,  Hyun-Woo Jin ,  John Roger Peterson ,  Robert Lee Antram ,  Christopher John Fowler

IPC分类号： B32B15/04 ,  B32B15/02

CPC分类号： C22C29/14 ,  C22C29/00 ,  C23C30/00 ,  Y10T428/31678

摘要： A cermet composition represented by the formula (PQ)(RS)X comprising: a ceramic phase (PQ), a binder phase (RS) and X wherein X is at least one member selected from the group consisting of an oxide dispersoid E, an intermetallic compound F and a derivative compound G wherein said ceramic phase (PQ) is dispersed in the binder phase (RS) as particles of diameter in the range of about 0.5 to 3000 microns, and said X is dispersed in the binder phase (RS) as particles in the size range of about 1 nm to 400 nm.

摘要翻译： 由式（PQ）（RS）X表示的金属陶瓷组合物包括：陶瓷相（PQ），粘结相（RS）和X，其中X是选自氧化物分散相E， 金属间化合物F和衍生化合物G，其中所述陶瓷相（PQ）作为直径在约0.5至3000微米范围内的颗粒分散在粘结相（RS）中，并且所述X分散在粘结相（RS）中， 作为大小范围为约1nm至400nm的颗粒。