公开(公告)号：US20080300387A1

公开(公告)日：2008-12-04

申请号：US12093961

申请日：2006-11-14

Applicant: Markus Schubert ,  Ulrich Muller ,  Stefan Marx ,  Rainer Senk

Inventor： Markus Schubert ,  Ulrich Muller ,  Stefan Marx ,  Rainer Senk

IPC: C07F19/00

CPC classification number: B01J31/1691 ,  B01J23/10 ,  B01J31/223 ,  B01J31/226 ,  B01J35/002 ,  B01J2531/35 ,  B01J2531/36 ,  B01J2531/38 ,  C01B3/0015 ,  C01B3/0026 ,  C07C51/418 ,  C07F5/003 ,  Y02C20/20 ,  Y02E60/327 ,  Y02E60/328 ,  C07C63/28

Abstract: The present invention relates to a process for preparing a porous metal organic framework, which comprises the step:Reaction of at least one metal compound with at least one at least bidentate organic compound which can coordinate to the metal, where the metal is ScIII, YIII or a trivalent lanthanide and the organic compound has at least two atoms which are selected independently from the group consisting of oxygen, sulfur and nitrogen and via which the organic compound can coordinate to the metal, in the presence of a nonaqueous organic solvent, with the reaction being carried out with stirring and at a pressure of not more than 2 bar (absolute).The invention further relates to porous metal organic frameworks which have been prepared by this process and their use.

Abstract translation: 本发明涉及一种制备多孔金属有机骨架的方法，其包括以下步骤：使至少一种金属化合物与至少一种至少二齿有机化合物反应，所述至少二齿有机化合物可与金属配位，其中金属为ScIII，YIII 或三价镧系元素，所述有机化合物具有至少两个独立地选自氧，硫和氮的原子，并且有机化合物可以在非水有机溶剂的存在下与金属配位， 反应在搅拌下和不超过2巴（绝对）的压力下进行。 本发明还涉及通过该方法制备的多孔金属有机骨架及其用途。

公开(公告)号：US07309380B2

公开(公告)日：2007-12-18

申请号：US10608146

申请日：2003-06-30

Applicant: Ulrich Müller ,  Michael Hesse ,  Reinhard Heβ ,  Rainer Senk ,  Markus Hölzle ,  Omar M. Yaghi

Inventor： Ulrich Müller ,  Michael Hesse ,  Reinhard Heβ ,  Rainer Senk ,  Markus Hölzle ,  Omar M. Yaghi

IPC: H01M8/04 ,  F17C11/00

CPC classification number: H01M8/04216 ,  B01J20/226 ,  C01B3/0015 ,  F17C11/005 ,  F17C2221/033 ,  F17C2223/035 ,  F17C2223/036 ,  F17C2270/0763 ,  H01M8/04208 ,  Y02C10/08 ,  Y02E60/321 ,  Y02E60/327 ,  Y02E60/328 ,  Y10S502/526

Abstract: A container for uptaking, or storing, or releasing, or uptaking and storing, or uptaking and releasing, or storing and releasing, or uptaking, storing and releasing at least one gas, comprising a metal-organic framework material comprising pores and at least one metal ion and at least one at least bidentate organic compound which is bound to said metal ion, as well as to a fuel cell comprising said container, and to a method of using said container or said fuel cell for supplying power to power plants, cars, trucks, busses, cell phones, and laptops.

Abstract translation: 用于吸收或储存或释放，吸收和储存，吸收和释放，或储存和释放或吸收至少一种气体的容器，其包括包含孔和至少一个的金属 - 有机骨架材料 金属离子和与所述金属离子结合的至少一种至少二齿的有机化合物，以及包含所述容器的燃料电池，以及使用所述容器或所述燃料电池向发电厂，汽车供电的方法 ，卡车，公共汽车，手机和笔记本电脑。

公开(公告)号：US09302257B2

公开(公告)日：2016-04-05

申请号：US12954802

申请日：2010-11-26

Applicant: Ulrich Müller ,  Peter Rudolf ,  Georg Krug ,  Rainer Senk

Inventor： Ulrich Müller ,  Peter Rudolf ,  Georg Krug ,  Rainer Senk

IPC: B01J29/04 ,  B01J29/89 ,  B01J37/00 ,  B01J37/08 ,  C07D301/12

CPC classification number: B01J29/89 ,  B01J37/0018 ,  B01J37/084 ,  B01J2229/42 ,  C07D301/12

Abstract: A process for the preparation of a catalyst for the use in a hydrocarbon conversion reaction, said catalyst containing a titanium zeolite and carbonaceous material, the catalyst containing said carbonaceous material in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst, the process comprising (i) preparing a catalyst containing the titanium zeolite and (ii) depositing carbonaceous material on the catalyst according to (i) in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst by contacting said catalyst, prior to using the catalyst in said hydrocarbon conversion reaction, with a fluid containing at least one hydrocarbon in an inert atmosphere, to obtain the carbonaceous material containing catalyst, wherein in (ii), the catalyst is not contacted with an oxygen containing gas.

Abstract translation: 一种用于制备用于烃转化反应的催化剂的方法，所述催化剂含有钛沸石和含碳材料，所述含碳材料的催化剂的含量为基于总重量的0.01-0.5重量％ 包含在催化剂中的钛沸石，该方法包括（i）制备含有钛沸石的催化剂和（ii）根据（i）在催化剂上沉积含碳材料，其量为基于总计的0.01至0.5重量％ 催化剂中含有的钛沸石的重量，在使用所述烃转化反应中的催化剂之前，使所述催化剂与在惰性气氛中含有至少一种烃的流体接触，得到含碳材料的催化剂，其中在（ii） ，催化剂不与含氧气体接触。

公开(公告)号：US20110130579A1

公开(公告)日：2011-06-02

申请号：US12954802

申请日：2010-11-26

Applicant: Ulrich MÜLLER ,  Peter Rudolf ,  Georg Krug ,  Rainer Senk

Inventor： Ulrich MÜLLER ,  Peter Rudolf ,  Georg Krug ,  Rainer Senk

IPC: C07D301/02 ,  B01J29/04 ,  B01J29/18 ,  B01J29/06

CPC classification number: B01J29/89 ,  B01J37/0018 ,  B01J37/084 ,  B01J2229/42 ,  C07D301/12

Abstract: A process for the preparation of a catalyst for the use in a hydrocarbon conversion reaction, said catalyst containing a titanium zeolite and carbonaceous material, the catalyst containing said carbonaceous material in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst, the process comprising (i) preparing a catalyst containing the titanium zeolite and (ii) depositing carbonaceous material on the catalyst according to (i) in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst by contacting said catalyst, prior to using the catalyst in said hydrocarbon conversion reaction, with a fluid containing at least one hydrocarbon in an inert atmosphere, to obtain the carbonaceous material containing catalyst, wherein in (ii), the catalyst is not contacted with an oxygen containing gas.

Abstract translation: 一种用于制备用于烃转化反应的催化剂的方法，所述催化剂含有钛沸石和含碳材料，所述含碳材料的催化剂的含量为基于总重量的0.01-0.5重量％ 包含在催化剂中的钛沸石，该方法包括（i）制备含有钛沸石的催化剂和（ii）根据（i）在催化剂上沉积含碳材料，其量为基于总计的0.01至0.5重量％ 催化剂中含有的钛沸石的重量，在使用所述烃转化反应中的催化剂之前，使所述催化剂与在惰性气氛中含有至少一种烃的流体接触，得到含碳材料的催化剂，其中在（ii） ，催化剂不与含氧气体接触。