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    CYCLOPENTADIENYLIDENE-PHOSPHORANE CONSTRAINED GEOMETRY COMPLEXES OF RARE EARTH METALS
    1.
    发明申请
    CYCLOPENTADIENYLIDENE-PHOSPHORANE CONSTRAINED GEOMETRY COMPLEXES OF RARE EARTH METALS 审中-公开
    稀土金属的环烯二烯基磷光体约束几何复合物

    公开(公告)号：US20140163187A1

    公开(公告)日：2014-06-12

    申请号：US14235259

    申请日：2012-08-02

    Applicant: Nina Hillesheim ,  Jörg Sundermeyer

    Inventor： Nina Hillesheim ,  Jörg Sundermeyer

    IPC: C08F4/52 ,  C08G63/84 ,  C07F9/54

    CPC classification number: C08F4/52 ,  B01J31/0235 ,  B01J31/2265 ,  B01J31/2295 ,  B01J2531/0205 ,  B01J2531/36 ,  B01J2531/37 ,  B01J2531/38 ,  C07F9/5352 ,  C07F9/54 ,  C07F17/00 ,  C08F36/08 ,  C08F2420/02 ,  C08G63/823 ,  C08G63/84 ,  C08F136/08 ,  C08F4/545

    Abstract: The invention relates to η5:η1-cyclopentadienylidene-phosphorane constrained geometry complexes of rare earth metals, abbreviated to η5:η1-CpPC-CGC, method for production and use of same. The η5:η1-CpPC-CGCs correspond to the general formula (1), wherein SE=Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb or Lu; X=independently of one another, a mono-anionic diorganoamido-, bistrimethylsilylamido-, halogenido-, alkyl-, aryl-, alkoxo-, aryloxo- or alkylaluminate (AlR4−) substituent; L=neutral ligand (PR3, NR3, pyridine), solvent molecule (THF, ether, DMF, DMSO, HMPT, tetrahydropyran THP, tetrahydrothiofuran THT); R=alkyl with up to 1-10 C atoms or mono- or polycyclical aryl with 6 to 20 C atoms; R1, R4=independently of one another H or methyl; R2, R3=independently of one another, H or methyl or tertiary butyl or together a substituted cycloalkyl group; R5, R6=methyl, n-butyl, tertiary butyl or phenyl; R7, R8=independently of one another H, trimethylsilyl, alkyl with 1-10 C atoms or mono- or polycyclical aryl with 6 to 20 C atoms, and m=0, 1, 2 or 3.

    Abstract translation: 本发明涉及＆amp; 5＆gt;稀土金属的1-环戊二烯基 - 正磷烷约束几何配合物，缩写为＆amp; e＆gt; 1-CpPC-CGC，其生产和使用方法。 其中SE = Sc，Y，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd，Tb，Dy，Ho等于通式（1） Er，Tm，Yb或Lu; X =彼此独立，单阴离子二有机基酰胺基，双三甲基甲硅烷基氨基 - ，卤代 - ，烷基 - ，芳基 - ，烷氧基 - ，芳氧基 - 或烷基铝酸盐（AlR 4 - ）取代基; L =中性配体（PR3，NR3，吡啶），溶剂分子（THF，醚，DMF，DMSO，HMPT，四氢吡喃THP，四氢噻呋喃THT）; R =具有至多1-10个C原子的烷基或具有6至20个C原子的单环或多环芳基; R1，R4 =彼此独立地为H或甲基; R2，R3彼此独立地为H或甲基或叔丁基或一起取代的环烷基; R 5，R 6 =甲基，正丁基，叔丁基或苯基; R 7，R 8彼此独立地为H，三甲基甲硅烷基，具有1-10个C原子的烷基或具有6至20个C原子的单环或多环芳基，m = 0,1,2或3。

    MULTINUCLEAR METALLOCENE CATALYST COMPLEXES FOR OLEFIN POLYMERISATION AND COPOLYMERISATION AND METHOD OF PREPARING THEREOF
    4.
    发明申请
    MULTINUCLEAR METALLOCENE CATALYST COMPLEXES FOR OLEFIN POLYMERISATION AND COPOLYMERISATION AND METHOD OF PREPARING THEREOF 审中-公开

    公开(公告)号：US20140024790A1

    公开(公告)日：2014-01-23

    申请号：US14002910

    申请日：2012-02-14

    Applicant: Haif Al-Shammari ,  Helmut Alt

    Inventor： Haif Al-Shammari ,  Helmut Alt

    IPC: C08F110/02

    CPC classification number: C07F17/00 ,  B01J31/143 ,  B01J31/1805 ,  B01J31/2295 ,  B01J2531/0205 ,  B01J2531/35 ,  B01J2531/36 ,  B01J2531/37 ,  B01J2531/38 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  B01J2531/56 ,  B01J2531/57 ,  B01J2531/58 ,  C08F4/62013 ,  C08F4/6423 ,  C08F4/65912 ,  C08F4/6592 ,  C08F110/02 ,  C08F2410/03 ,  C08F4/64013 ,  C08F2500/04

    Abstract: The invention relates to a multinuclear metallocene catalyst of general formula (1); wherein Y and Y′ are the same or different and independently selected from a C1-20 linear hydrocarbyl group; C1-20 branched hydrocarbyl group; C1-20 cyclic hydrocarbyl group; a C1-30 aryl group and a C1-30 substituted aryl group; L and L′ are the same or different and each is an electron-donating group independently selected from the elements of Group 15 of the Periodic Table; Q and Q′ are the same or different and independently selected from hydrogen, a C1-30 alkyl group and a C1-30 aryl group; M″ is a metal selected from Group 3, 4, 5, 6, 7, 8, 9 and 10 elements and from lanthanide series elements of the Periodic Table; Z is selected from the group consisting of hydrogen; a halogen element; a C1-20 hydrocarbyl group; C1-20 alkoxy group and a C1-20 aryloxy group; B and B′ are the same or different and each is a half sandwich metallocene compound, with B being represented by Formula 2 and B′ being represented by Formula 3: W-M-Xx (Formula 2), W′-M′-X′x′, (Formula 3) wherein: W and W′ are the same or different and independently a ligand compound having a cyclo pentadienyl skeleton selected from the group consisting of cyclopentadienyl, substituted cyclopentadienyl, indenyl, substituted indenyl, fluorenyl and substituted fluorenyl; M and M′ are the same and each is independently selected from the group consisting of scandium; yttrium; lanthanoid series elements; titanium; zirconium; hafnium; vanadium; niobium; and tantalum; X and X′ are the same or different and each is selected from the group consisting of hydrogen; a halogen element; a C 1-20 hydrocarbyl group, C1-20 alkoxy group; and C1-20 aryloxy group; x and x′ are independently integers from 0 to 3; z is an integer from 1 to 5; n, n′ are independently 0 or 1, with 1≦(n+n′)≦2. The invention further relates to a method to prepare said multinuclear metallocene catalyst compound. The invention further relates to a catalyst system and to a process for the polymerisation of olefins.

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