公开(公告)号：US20110245435A1

公开(公告)日：2011-10-06

申请号：US13139133

申请日：2009-12-09

Applicant: Christoph Plachetta ,  Achim Gerstlauer ,  Reinhard Lang ,  Thomas Sauer ,  Jens Becker

Inventor： Christoph Plachetta ,  Achim Gerstlauer ,  Reinhard Lang ,  Thomas Sauer ,  Jens Becker

IPC: C08F2/01 ,  C08G69/14

CPC classification number: C08G69/36 ,  C08G69/08 ,  C08G69/28 ,  C08L77/00

Abstract: A process for continuously preparing copolyamides from lactams and salts of diamines and dicarboxylic acids, in which lactams together with salts of diamines and dicarboxylic acids are passed from the top downward through a vertical polymerization tube at polyamide-forming temperatures, which comprises a) intensively mixing an aqueous solution of lactams with salts of diamines and dicarboxylic acids under elevated pressure which is greater than the vapor pressure of the mixture which arises in a mixing apparatus at a temperature of from 80 to 300° C., b) feeding the mixture thus obtained to a heated helical tube evaporator in which a liquid phase and a vapor phase form at a temperature of from 140 to 300° C., a stream of water vapor and/or inert gas also being introduced into the mixture if appropriate upstream of the helical tube, c) removing the vapor phase formed in stage b) from the liquid phase and separating it in a column into water vapor and into organic components comprising diamines, dicarboxylic acids and lactams, and recycling the organic components into the polymerization, d) passing the liquid phase from the helical tube of stage b) mixed with the organic components of stage c) from the top downward through a vertical polymerization tube at polyamide-forming temperatures to obtain a copolyamide.

Abstract translation: 其中内酰胺和二胺和二羧酸的盐连续制备共聚酰胺和二胺和二羧酸的盐的方法，其中内酰胺与二胺和二羧酸的盐在聚酰胺形成温度下从顶部向下通过垂直聚合管，其包括a）浓缩混合 在升高的压力下具有二胺和二羧酸的盐的内酰胺的水溶液，其大于在混合装置中在80至300℃的温度下产生的混合物的蒸气压，b）将如此获得的混合物 到一个加热的螺旋管式蒸发器，其中液相和气相在140-300℃的温度下形成，如果合适的话，水蒸气和/或惰性气体也被引入到混合物的上游 管，c）从液相中除去阶段b）中形成的气相，并将其在塔中分离成水蒸汽，并加入有机组分，包括 二胺，二羧酸和内酰胺，并将有机组分再循环到聚合中，d）将来自与步骤c）的有机组分混合的阶段b）的螺旋管的液相从顶部向下通过垂直聚合管在聚酰胺 得到共聚酰胺。

公开(公告)号：US5242531A

公开(公告)日：1993-09-07

申请号：US829402

申请日：1992-02-03

Applicant: Herbert Klingshirn ,  Reinhard Lang

Inventor： Herbert Klingshirn ,  Reinhard Lang

IPC: C30B15/02 ,  C30B15/04 ,  C30B15/12 ,  C30B29/06 ,  H01L21/208

CPC classification number: C30B15/02 ,  C30B15/04 ,  Y10T117/1052 ,  Y10T117/1056

Abstract: In the Czochralski crucible pulling of crystal ingots, in particular those of silicon and having particularly large crystal diameters, the degree of filling of the crucible is kept approximately constant during the pulling process by continuously adding solid or liquid recharging material. According to the invention, the known disadvantages of thermal disturbances and the introduction of impurities and particles are overcome by a recharging system with a gas-tight seal, comprising additional crucible, stock container for semiconductor material and dopant having the appropriate feedlines and an exhaust gas line. In addition, the process makes possible a regulatable and separate recharging of dopant via the additional crucible.

Abstract translation: 在Czochralski坩埚中拉晶晶锭，尤其是具有特别大的晶体直径的晶锭，通过连续添加固体或液体补充材料，坩埚的填充程度在拉拔过程中保持大致恒定。 根据本发明，通过具有气密密封的再充电系统克服了热扰动和引入杂质和颗粒的已知缺点，其包括另外的坩埚，用于半导体材料的储料容器和具有适当馈线的掺杂剂和排气 线。 此外，该方法可以通过另外的坩埚对掺杂剂进行可调节和分离的再充电。

公开(公告)号：US09200115B2

公开(公告)日：2015-12-01

申请号：US13139133

申请日：2009-12-09

Applicant: Christoph Plachetta ,  Achim Gerstlauer ,  Reinhard Lang ,  Thomas Sauer ,  Jens Becker

Inventor： Christoph Plachetta ,  Achim Gerstlauer ,  Reinhard Lang ,  Thomas Sauer ,  Jens Becker

IPC: C08G69/36 ,  C08L77/00 ,  C08G69/28 ,  C08G69/08

CPC classification number: C08G69/36 ,  C08G69/08 ,  C08G69/28 ,  C08L77/00

Abstract: A process for continuously preparing copolyamides from lactams and salts of diamines and dicarboxylic acids, in which lactams together with salts of diamines and dicarboxylic acids are passed from the top downward through a vertical polymerization tube at polyamide-forming temperatures, which comprises a) intensively mixing an aqueous solution of lactams with salts of diamines and dicarboxylic acids under elevated pressure which is greater than the vapor pressure of the mixture which arises in a mixing apparatus at a temperature of from 80 to 300° C., b) feeding the mixture thus obtained to a heated helical tube evaporator in which a liquid phase and a vapor phase form at a temperature of from 140 to 300° C., a stream of water vapor and/or inert gas also being introduced into the mixture if appropriate upstream of the helical tube, c) removing the vapor phase formed in stage b) from the liquid phase and separating it in a column into water vapor and into organic components comprising diamines, dicarboxylic acids and lactams, and recycling the organic components into the polymerization, d) passing the liquid phase from the helical tube of stage b) mixed with the organic components of stage c) from the top downward through a vertical polymerization tube at polyamide-forming temperatures to obtain a copolyamide.

Abstract translation: 其中内酰胺和二胺和二羧酸的盐连续制备共聚酰胺和二胺和二羧酸的盐，其中内酰胺与二胺和二羧酸的盐在聚酰胺形成温度下从顶部向下通过垂直聚合管，其包括a）浓缩混合 在升高的压力下具有二胺和二羧酸的盐的内酰胺的水溶液，其大于在混合装置中在80至300℃的温度下产生的混合物的蒸气压，b）将如此获得的混合物 到一个加热的螺旋管式蒸发器，其中液相和气相在140-300℃的温度下形成，如果合适的话，水蒸气和/或惰性气体也被引入到混合物的上游 管，c）从液相中除去阶段b）中形成的气相，并将其在塔中分离成水蒸汽，并加入有机组分，包括 二胺，二羧酸和内酰胺，并将有机组分再循环到聚合中，d）将来自与阶段c）的有机组分混合的阶段b）的螺旋管的液相从顶部向下通过垂直聚合管在聚酰胺 得到共聚酰胺。

公开(公告)号：US5496591A

公开(公告)日：1996-03-05

申请号：US239860

申请日：1994-05-09

Applicant: Reinhard Lang ,  Erich Beck ,  Edmund Keil ,  Adolf Nuber ,  Harro Petersen ,  Hans Renz ,  Horst Schmidt ,  Wolfram Weiss

Inventor： Reinhard Lang ,  Erich Beck ,  Edmund Keil ,  Adolf Nuber ,  Harro Petersen ,  Hans Renz ,  Horst Schmidt ,  Wolfram Weiss

IPC: C08F299/02 ,  C08F290/00 ,  C08F290/14 ,  C08G12/40 ,  C08G12/42 ,  C08G14/12 ,  C09D161/34 ,  C08J7/04

CPC classification number: C08G14/12 ,  C08F290/14 ,  C09D161/34

Abstract: Radiation-curable binders which are obtained by reactingA) an amine/formaldehyde condensate having a molar ratio of formaldehyde to amino groups of from 1:1 to 2:1 withB) one or more esters, having a free hydroxyl group, of acrylic acid or of methacrylic acid with polyalcohols which contain from two to four alcoholic hydroxyl groups, from 0.1 to 0.3 hydroxyl equivalent of component B) being used per methylol equivalent of component A),in the presence of a strong acid are suitable for use in coating materials.

Abstract translation: 通过使A）甲醛与氨基的摩尔比为1：1至2：1的胺/甲醛缩合物与B）一种或多种具有游离羟基的丙烯酸酯反应得到的可辐射固化粘合剂 酸或甲基丙烯酸与含有2至4个醇羟基的多元醇，0.1至0.3个羟基当量的组分B）相对于组分A）的羟甲基当量）在强酸存在下使用适用于涂层 材料

公开(公告)号：US06320021B1

公开(公告)日：2001-11-20

申请号：US09554217

申请日：2000-05-11

Applicant: Peter Hildenbrand ,  Reinhard Lang ,  Alfons Ludwig ,  Gunter Pipper

Inventor： Peter Hildenbrand ,  Reinhard Lang ,  Alfons Ludwig ,  Gunter Pipper

IPC: C08G6916

CPC classification number: C08G69/16 ,  C08G69/46

Abstract: A process for continuous extraction of polyamide particles in an essentially vertical extraction column using an aqueous extractant comprises using an extraction column that is divided into two zones and performing an extraction with a recirculating 15-40% strength by weight aqueous &egr;-caprolactam solution in the first zone and then with countercurrent water at a from 5 to 40° C. lower temperature in the second zone. The process provides for economical extraction of polyamides with a low level of monomers and oligomers.

Abstract translation: 使用含水萃取剂在基本垂直的萃取塔中连续提取聚酰胺颗粒的方法包括使用分离成两个区域的提取塔，并用15-40重量％的重量百分比的ε-己内酰胺水溶液萃取 然后在5至40℃的逆流水中，在第二区域中的较低温度。 该方法提供了用低水平的单体和低聚物经济地提取聚酰胺。

公开(公告)号：US5324488A

公开(公告)日：1994-06-28

申请号：US73351

申请日：1993-06-07

Applicant: Herbert Klingshirn ,  Reinhard Lang

Inventor： Herbert Klingshirn ,  Reinhard Lang

IPC: C30B15/02 ,  C30B15/04 ,  C30B15/12 ,  C30B29/06 ,  H01L21/208 ,  B01D9/00

CPC classification number: C30B15/02 ,  C30B15/04 ,  Y10T117/1052 ,  Y10T117/1056

Abstract: In the Czochralski crucible pulling of crystal ingots, in particular those of silicon and having particularly large crystal diameters, the degree of filling of the crucible is kept approximately constant during the pulling process by continuously adding solid or liquid recharging material. According to the invention, the known disadvantages of thermal disturbances and the introduction of impurities and particles are overcome by a recharging system with a gas-tight seal, comprising additional crucible, stock container for semiconductor material and dopant having the appropriate feedlines and an exhaust gas line. In addition, the process makes possible a regulatable and separate recharging of dopant via the additional crucible.

Abstract translation: 在Czochralski坩埚中拉晶晶锭，尤其是具有特别大的晶体直径的晶锭，通过连续添加固体或液体补充材料，坩埚的填充程度在拉拔过程中保持大致恒定。 根据本发明，通过具有气密密封的再充电系统克服了热扰动和引入杂质和颗粒的已知缺点，其包括另外的坩埚，用于半导体材料的储料容器和具有适当馈线的掺杂剂和排气 线。 此外，该方法可以通过另外的坩埚对掺杂剂进行可调节和分离的再充电。