摘要:
Methods of producing thermoplastic poly(amide-urethane) block copolymers having excellent flexibility at low temperatures are provided. The methods comprise reacting substantially linear polyamides, the polyamides being based on dimerized fatty acids and terminated by carboxyl and/or amino groups and aliphatic or cyloaliphatic polyethers and/or reaction products thereof with 2,3-epoxypropanol. The reaction products contain substantially no free isocyanate groups or epoxide groups. The invention also relates to the use of these products as adhesives and corrosion inhibitors for metallic and/or wooden materials.
摘要:
Thermoplastic polyamide mixtures of polyamides based on dimerized fatty acids in which at least one polyamide contains as an incorporated unit (a) a C.sub.2 -C.sub.10 aliphatic diamine capable of diamide formation, which is N-substituted with C.sub.10 -C.sub.25 -alkyl, and (b) a C.sub.2 -C.sub.40 -diamine capable of diamide formation comprising a diprimary amine, a heterocyclic amine, or a diomine containing one or two secondary amino groups and which is N-C.sub.1 -C.sub.8 -alkyl-substituted on at least one side.
摘要:
Thermoplastic polyamide resins showing improved substrate adhesion and consisting essentially of polycondensates of the following components:(a) from 10 to 50 mole percent dimer fatty acids, having a trimer fatty acid content of from 10 to 20 mol percent;(b) from 25 to 45 mole percent of one or more aliphatic, aromatic and/or cyclic C.sub.2 -C.sub.40 diamines which are diprimary diamines, diamines containing secondary amino groups and alkyl substituents with no more than 8 carbon atoms on the N-atom, or heterocyclic diamines capable of diamide formation,(c) from 5 to 25 mole percent of aliphatic diamines capable of diamide formation and N-alkyl-substituted on at least one N-atom, containing from 2 to 10 C-atoms and from 10 to 25 carbon atoms in the N-alkyl group, and(d) from 0 to 40 mole percent aliphatic C.sub.6 -C.sub.22 dicarboxylic acids.
摘要:
The object of the invention are adhesion promoters for plastisols of polyvinylchloride polymers or copolymers, characterized in that they are constituted by polyaminoamidic resins obtained by means of the condensation of:1 equivalent of carboxylic acids, obtained by polymerization of unsaturated fatty acids, of composition comprised within the following ranges: 0-2% monomers, 10-50% dimers, 50-90% trimers, withfrom 1.0 to 2.2 equivalents of an heterocyclic amine of general formula ##STR1## wherein R can be H or an alkylamino group --R'--NH.sub.2, wherein R' is a saturated alifatic chain.
摘要:
The present invention relates to a modular upright for building structures and a sliding safety grille which can be obtained by assembling these uprights. In a preferred embodiment, the modular upright (10) comprises a pair of anti-cutting reinforcing elements (1) which are lined by U-shaped modular elements (3) alternating with joining elements (2) and fastened together by at least one anti-pulling element (6) sliding vertically between two joining elements (2), in the space between the surface of the reinforcing elements (1) and the U-shaped modular elements (3).
摘要:
Thermoplastic polyamide resins with improved low-temperature flexibility and improved bonding properties consisting essentially of polycondensates of the following components:(a) 10 to 50 mol-% of a dimer fatty acid or mixture of such acids,(b) 5 to 45 mol-% of polyoxyalkylene urea diamine,(c) 0 to 25 mol-% of an aliphatic C.sub.6 -C.sub.22 dicarboxylic acid or mixture of such acids,(d) 0 to 45 mol-% of an aliphatic, aromatic or cyclic C.sub.2 -C.sub.40 diamine or a mixture of such diamines selected from the group comprising diprimary diamines, diamines containing secondary amino groups and alkyl substituents with no more than 8 carbon atoms at the nitrogen atom, and heterocyclic diamines capable of double amide formation.Preferred resins are base-terminated resins having amine values of up to 50 and acid-terminated resins having acid values of up to 20 and a molecular weight within the range from 5000 to 20,000 and preferably from 8000 to 15,000. The polyamide resins may be applied in as a melt between surfaces to be bonded and subsequently left to set for fixing and may be used either on their own or with other auxiliaries as hotmelt adhesives.
摘要:
Thermoplastic polyamide mixtures of polyamides based on dimerized fatty acids in which at least one polyamide contains as an incorporated unit (a) a C.sub.2 -C.sub.10 aliphatic diamine capable of diamide formation, which is N-substituted with C.sub.10 -C.sub.25 -alkyl, and (b) a C.sub.2 -C.sub.40 -diamine capable of diamide formation comprising a diprimary amine, a heterocyclic amine, or a diomine containing one or two secondary amino groups and which is N-C.sub.1 -C.sub.8 -alkyl-substituted on at least one side.
摘要:
A process for the preparation of regenerated cellulose shaped bodies from inning dopes comprising solutions of methylol derivatives of cellulose in organic solvent selected from dimethylformamide, dimethylacetamide, dimethylsulphoxide and N-methyl-pyrrolidone is described. The cellulose derivative is coagulated from the spinning dope in a coagulating bath, the main component of which is a high-boiling alcohol capable of reacting with the free (para)formaldehyde and with the bound (para)formaldehyde of the methylol derivative to a degree varying with the temperature. It is possible to prepare filaments and yarns having excellent characteristics by starting from solutions having high CH.sub.2 O and cellulose concentrations and high MS ratios.
摘要:
A process for the dissolution of cellulose in organic solvents such as dihylformamide, dimethylacetamide, and N-methylpyrrolidone is described which comprises contacting the cellulose with an excess of paraformaldehyde and with the solvent at elevated temperatures, preferably higher than 115.degree. C. The amount of paraformaldehyde used preferably corresponds to at least 13 CH.sub.2 O units per anhydroglucosidic unit of the cellulose. The solution obtained can be rendered stable at room temperature by heating it under stirring to lower the paraformaldehyde content, preferably to not less than 8 CH.sub.2 O units per anhydroglucosidic unit. Formed bodies of regenerated cellulose can be obtained from said solutions by coagulating them in an aqueous bath, which may be alkaline or may be a mixture of water and the solvent of the solution, or even by evaporating the solvent.
摘要:
A process for the preparation of regenerated cellulose formed bodies from lutions of cellulose derivatives in organic solvents is disclosed. The cellulose derivatives is firstly precipitated in a coagulating bath constituted of a cellulose non-solvent, non-regenerating organic liquid, then the coagulated body is drawn in subsequent baths and the cellulose is regenerated. The drawing and the regeneration occur, at least in part, concurrently.