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    Polymerisation and Oligomerisation Catalysts
    1.
    发明申请
    Polymerisation and Oligomerisation Catalysts 有权
    聚合和低聚催化剂

    公开(公告)号：US20070207918A1

    公开(公告)日：2007-09-06

    申请号：US11660050

    申请日：2005-07-25

    申请人： Vernon Gibson ,  Atanas Tomov ,  Grant Jacobsen

    发明人： Vernon Gibson ,  Atanas Tomov ,  Grant Jacobsen

    IPC分类号： B01J21/00

    CPC分类号： C08F10/02 ,  C08F10/00 ,  C08F110/02 ,  C08F4/022 ,  C08F4/69224 ,  C08F2500/01 ,  C08F4/64099 ,  C08F4/64089 ,  C08F4/68224 ,  C08F4/6825 ,  C08F4/68215 ,  C08F4/69275 ,  C08F4/6925 ,  C08F4/69215 ,  C08F4/69034 ,  C08F4/69146

    摘要： A polymerisation catalyst composition comprising (1) a transition metal compound of Formula (A), Z being 5-membered heterocyclic containing at least one carbon, at least one nitrogen and at least one of nitrogen, sulphur and oxygen, the others being nitrogen or carbon; M is a Group 3 to 11 metal or a lanthamide metal; E1 and E2 are divalent groups of aliphatic, alicyclic, aromatic or alkyl substituted aromatic hydrocarbon, or heterocyclic; D1 and D2 are donor atoms or groups; X is an anionic group, L is a neutral donor group; n=m=zero or 1; y and z are zero or integer such that X and L satisfy valency/oxidation state of M, (2) a catalyst-activating support which is a solid particulate substance, insoluble in hydrocarbons, comprising at least magnesium and aluminum atoms and hydrocarbyloxy groups containing 1 to 20 carbon atoms, the molar ration of Mg/Al being in the range 1.0 to 300 and the molar ratio of hydrocarbyloxy groups to aluminium atoms being in the range 0.5 to 2.0, and optionally, (3) an additional activator selected from aluminium alkyl and boron compounds.

    摘要翻译： 一种聚合催化剂组合物，其包含（1）式（A）的过渡金属化合物，Z为含有至少一个碳，至少一个氮和氮，硫和氧中的至少一个的5元杂环，其余为氮或 碳; M是第3至11族金属或花生苷金属; E 1和E 2是脂族，脂环族，芳族或烷基取代的芳族烃或杂环的二价基团; D 1和D 2是供体原子或基团; X是阴离子基团，L是中性给体基团; n = m =零或1; y和z为零或整数，使得X和L满足M的化合价/氧化态，（2）催化剂活化载体，其是固体颗粒物质，不溶于烃，包含至少镁和铝原子和含有烃氧基的烃氧基 1〜20个碳原子，Mg / Al的摩尔比在1.0〜300范围内，烃氧基与铝原子的摩尔比在0.5〜2.0的范围内，任选地，（3）另外的活化剂，选自铝 烷基和硼化合物。

    Supported olefin polymerization catalyst
    3.
    发明申请
    Supported olefin polymerization catalyst 审中-公开
    负载型烯烃聚合催化剂

    公开(公告)号：US20060247397A1

    公开(公告)日：2006-11-02

    申请号：US10539573

    申请日：2003-12-03

    申请人： Grant Jacobsen ,  Brian Kimberley ,  Sergio Mastroianni

    发明人： Grant Jacobsen ,  Brian Kimberley ,  Sergio Mastroianni

    IPC分类号： C08F4/44

    CPC分类号： C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65916 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/04

    摘要： A supported catalyst system comprises (a) a dehydrated support material, (b) a transition metal compound, and (c) an activator and is characterised in that the support material has been pretreated with at least two different organoaluminum compounds prior to contact with either or both the transition metal compound or the activator. The preferr transition metal compound is a metallocene and the supported catalyst systems are suitable for the preparation of polymers having broad molecular weight distributions and improved melt strength.

    摘要翻译： 负载的催化剂体系包括（a）脱水的载体材料，（b）过渡金属化合物和（c）活化剂，其特征在于，在与二种不同的有机铝化合物接触之前，用至少两种不同的有机铝化合物预处理 或过渡金属化合物或活化剂两者。 优选的过渡金属化合物是茂金属，并且负载的催化剂体系适用于制备具有宽分子量分布和改善的熔体强度的聚合物。

    Supported polymerisation catalysts
    4.
    发明申请
    Supported polymerisation catalysts 有权
    负载型聚合催化剂

    公开(公告)号：US20060223695A1

    公开(公告)日：2006-10-05

    申请号：US10568954

    申请日：2004-08-04

    申请人： Grant Jacobsen ,  Brian Kimberley ,  Sergio Mastroianni

    发明人： Grant Jacobsen ,  Brian Kimberley ,  Sergio Mastroianni

    IPC分类号： B01J31/00

    CPC分类号： C08F210/16 ,  C08F4/65908 ,  C08F4/65916 ,  C08F4/6592 ,  C08F2420/02 ,  C08F4/65912 ,  C08F210/14

    摘要： A supported polymerization catalyst system is prepared by a method comprising the following steps: (i) addition of a cocatalyst to a porous support, (ii) mixing a polymerisation catalyst with a polymerisable monomer, and (iii) contacting together the components resulting from steps (i) and (ii). The porous support is preferably silica and the polymerisation catalyst is preferably a metallocene. The polymerisable monomer is typically 1-hexene and the supported catalyst system provides advantages a slowly decaying activity profile particularly when operating in the gas phase.

    摘要翻译： 通过包括以下步骤的方法制备负载型聚合催化剂体系：（i）向多孔载体中加入助催化剂，（ii）将聚合催化剂与可聚合单体混合，和（iii）将由步骤 （i）和（ii）。 多孔载体优选为二氧化硅，聚合催化剂优选为金属茂。 可聚合单体通常是1-己烯，并且负载的催化剂体系特别是当在气相中操作时，具有缓慢衰变的活性分布的优点。

    Supported olefin polymerization catalyst
    5.
    发明申请
    Supported olefin polymerization catalyst 失效
    负载型烯烃聚合催化剂

    公开(公告)号：US20060100091A1

    公开(公告)日：2006-05-11

    申请号：US10539518

    申请日：2003-12-03

    申请人： Grant Jacobsen ,  Brian Kimberley ,  Claudine Lalanne-Magne ,  Sergio Mastroianni

    发明人： Grant Jacobsen ,  Brian Kimberley ,  Claudine Lalanne-Magne ,  Sergio Mastroianni

    IPC分类号： B01J31/00

    CPC分类号： C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65916 ,  C08F210/14 ,  C08F2500/12

    摘要： Supported catalyst systems are provided comprising (a) a transition metal compound, (b) a non aluminoxane activator comprising, and (c) a support material comprising an inorganic metal oxide, inorganic metal halide or polymeric material or mixtures thereof characterised in that the support material has been pretreated with an SO4 contianing compound. The preferred transition metal compounds are metallocenes and the SO4 containing compound is typically sulphuric acid. The supported catalyst systems show improved activity and also may reduce fouling in gas phase fluidised bed processes.

    摘要翻译： 提供了负载型催化剂体系，其包括（a）过渡金属化合物，（b）非铝氧烷活化剂，其包含和（c）包含无机金属氧化物，无机金属卤化物或聚合物材料或其混合物的载体材料或其混合物，其特征在于， 材料已经用SO 4 SO 4化合物预处理。 优选的过渡金属化合物是金属茂，含SO 4的化合物通常是硫酸。 负载型催化剂体系显示出改善的活性，并且还可以减少气相流化床方法中的结垢。

    Olefin polymerisation process
    6.
    发明申请
    Olefin polymerisation process 失效
    烯烃聚合方法

    公开(公告)号：US20050245699A1

    公开(公告)日：2005-11-03

    申请号：US10525730

    申请日：2003-08-06

    申请人： Grant Jacobsen ,  Brian Kimberley ,  Sergio Mastroianni

    发明人： Grant Jacobsen ,  Brian Kimberley ,  Sergio Mastroianni

    IPC分类号： C08F210/00 ,  C08F2/34 ,  C08F4/658 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/02 ,  C08F210/16 ,  C08F4/44

    CPC分类号： C08F210/16 ,  C08F4/65916 ,  C08F4/6592 ,  C08F110/06 ,  C08F4/65908 ,  C08F4/65912 ,  C08F210/14

    摘要： A process for the homopolymerisation of ethylene or the copolymerisation of ethylene and (a-olefins in a polymeristation reactor, said process carried out in the presence of a catalyst system comprising (a) a polymerisation catalyst and (b) an ionic activator is characterised in that an organometallic compound of a Group IIIB metal having at least one unit of formula: Mç0çR or Mç0çM where M is the Group IIIB metal and R is a hydrocarbyl group is added to the reactor. Preferred organometallic compounds include aluminoxanes and the process results in improved poison scavenging as well as advantages in activity profiles, catalyst activity and product characteristics. The process is particularly suitable for use with supported metallocene catalyst systems in the slurry or gas phase.

    摘要翻译： 乙烯均聚或乙烯与聚合反应器中的（α-烯烃）共聚合的方法，所述方法是在包含（a）聚合催化剂和（b）离子活化剂的催化剂体系存在的情况下进行的，其特征在于 具有至少一个式：Mç0çR或Mç0çM的单元的IIIB族金属的有机金属化合物，其中M是IIIB族金属，R是烃基，优选的有机金属化合物包括铝氧烷，并且该方法得到改进 毒物清除以及活性特性，催化剂活性和产品特性的优点，该方法特别适用于在浆液或气相中负载的茂金属催化剂体系。

    Supported polymerisation catalysts
    7.
    发明申请
    Supported polymerisation catalysts 失效
    负载型聚合催化剂

    公开(公告)号：US20070135296A1

    公开(公告)日：2007-06-14

    申请号：US10568822

    申请日：2004-08-04

    申请人： Grant Jacobsen ,  Brian Kimberley ,  Sergio Mastroianni

    发明人： Grant Jacobsen ,  Brian Kimberley ,  Sergio Mastroianni

    IPC分类号： B01J31/00 ,  C08F4/44

    CPC分类号： C08F210/16 ,  C08F4/65908 ,  C08F4/65916 ,  C08F4/6592 ,  C08F2420/02 ,  C08F4/65912 ,  C08F210/14

    摘要： A supported polymerisation catalyst system comprises a porous support, a polymerisation catalyst and a cocatalyst wherein the support has been treated with an inert material such as polyisobutene. The support is preferably silica and is preferably treated with the inert material prior to contact with the other components. Preferably the polymerisation catalyst is a metallocene and the polymerisation catalyst system reduces the initial peak isotherm allowing for a smoother activity increase in particular for polymerisations carried out in the gas phase.

    摘要翻译： 负载型聚合催化剂体系包括多孔载体，聚合催化剂和助催化剂，其中载体已用惰性材料如聚异丁烯处理。 载体优选为二氧化硅，并且优选在与其它组分接触之前用惰性材料处理。 优选地，聚合催化剂是茂金属，并且聚合催化剂体系降低了初始峰值等温线，从而允许更平滑的活性增加，特别是对于在气相中进行的聚合反应。

    Supported polymerisation catalysts
    10.
    发明申请
    Supported polymerisation catalysts 审中-公开
    负载型聚合催化剂

    公开(公告)号：US20050209096A1

    公开(公告)日：2005-09-22

    申请号：US10524730

    申请日：2003-08-14

    申请人： Grant Jacobsen ,  Brian Kimberley ,  Sergio Mastroianni ,  Michael Taylor ,  Eliane Garcia ,  Gerard Lacane

    发明人： Grant Jacobsen ,  Brian Kimberley ,  Sergio Mastroianni ,  Michael Taylor ,  Eliane Garcia ,  Gerard Lacane

    IPC分类号： C08F4/64 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  B01J31/00 ,  C08F4/44

    CPC分类号： C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65916 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/11

    摘要： A novel process for the preparation of a supported transition metal catalyst system said method comprises the steps of: (i) mixing together in a suitable solvent (a) an organometallic compound, and (b) an ionic activator comprising a cation and an anion, (ii) addition of the mixture from step (i) to a support material, and (iii) addition of a transition metal compound in a suitable solvent, characterised in that the molar ratio of organometallic compound (a) to ionic activator (b) in step (i) is in the range 0.1 to 2.0. By use of the reduced molar ratio of the organometallic compound to the ionic activator in step (i) better reproducibilty of the catalyst may be achieved as well as higher activities. In addition polymer properties may be improved for example higher melt strength resulting in better product performance. The preferred transition metal compounds are metallocenes.

    摘要翻译： 一种制备负载型过渡金属催化剂体系的新方法，所述方法包括以下步骤：（i）在合适的溶剂（a）有机金属化合物中混合在一起，和（b）包含阳离子和阴离子的离子活化剂， （ii）将步骤（i）的混合物加入到载体材料中，和（iii）在合适的溶剂中加入过渡金属化合物，其特征在于有机金属化合物（a）与离子活化剂（b）的摩尔比 在步骤（i）中为0.1〜2.0。 通过在步骤（i）中通过使用有机金属化合物与离子型活化剂的摩尔比降低，可以实现更好的催化剂的再现性以及更高的活性。 此外，聚合物性能可以被改善，例如更高的熔体强度导致更好的产品性能。 优选的过渡金属化合物是金属茂。