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公开(公告)号：US20230131312A1
公开(公告)日：2023-04-27
申请号：US17782670
申请日：2020-06-29
申请人： Zhejiang Huangma Technology Co., Ltd. , Zhejiang Huangma Shangyi New Material Co., Ltd. , Zhejiang Lukean Chemical Co., Ltd. , Shangyu Huangma Surface Activated Reagent Research Institute Co., Ltd.
发明人： Weisong Wang , Yifeng Jin , Ran Kou , Majishi Wang , Xingjun Zhao
摘要： The present disclosure discloses a synthesis method of polyether for a low-modulus sealant, belonging to the technical field of organic compound synthesis. In the synthesis method of the present disclosure, a reaction is performed by using a mixture of monohydric alcohol polyoxypropylene ether and polyhydric alcohol polyoxypropylene ether as a starter, using epoxypropane as a chain extender and adding a metal complex catalyst, so as to obtain the polyether for the low-modulus sealant after the reaction is ended. The polyether prepared in the present disclosure can not only well enhance the rigid strength of the sealant but also reduce the elasticity modulus of the sealant, overcoming the problem that the existing polyether silane modified sealant is high in modulus. The synthesis method of the present disclosure is simple in synthesis process, easy to produce and control, short in production period and low in energy consumption.
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公开(公告)号：US20230303769A1
公开(公告)日：2023-09-28
申请号：US18076365
申请日：2022-12-06
申请人： Zhejiang Huangma Technology Co., Ltd. , Zhejiang Lukean Chemical Co., Ltd. , Zhejiang Huangma Shangyi New Material Co., Ltd. , Shangyu Huangma Surface Activated Reagent Research Institute Co., Ltd.
发明人： Weisong Wang , Majishi Wang , Jiang Yu , Shengli Wang , Yifeng Jin , Shicong Zhao , Minggui Song
IPC分类号： C08G65/26 , B01J21/04 , B01J21/18 , B01J23/72 , B01J23/74 , B01J37/08 , B01J37/16 , B01J37/02
CPC分类号： C08G65/269 , B01J21/04 , B01J21/18 , B01J23/72 , B01J23/74 , B01J37/08 , B01J37/16 , B01J37/0205 , B01J2523/847 , B01J2523/845 , B01J2523/17 , B01J2523/31 , B01J2231/10
摘要： The present invention relates to a method for preparing a polyether amine catalyst, and polyether amine. A polyether amine catalyst is a supported metal catalyst; γ-Al2O3 is used as a carrier; basic cupric carbonate, basic nickel carbonate and basic cobalt carbonate are used as precursors of supported metals; and the polyether amine catalyst is prepared by performing twice adsorption roasting and once reduction by means of an equivalent-volumetric impregnation method. Easier decomposition is achieved by using basic carbonate, and only water and carbon dioxide are generated, such that processes and costs for treating waste gases can be saved. By using the polyether amine catalyst to prepare polyether amine, a conversion rate and primary amine selectivity can be improved, and the color of products can be reduced. Therefore, the obtained polyether amine can have higher activity and wider application.
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3.发明公开公开(公告)号：US20230303768A1
公开(公告)日：2023-09-28
申请号：US18075424
申请日：2022-12-06
申请人： Zhejiang Huangma Technology Co., Ltd. , Zhejiang Huangma Shangyi New Material Co., Ltd. , Zhejiang Lukean Chemical Co., Ltd. , Shangyu Huangma Surface Activated Reagent Research Institute Co., Ltd.
发明人： Weisong Wang , Yifeng Jin , Majishi Wang , Dinglian Ma , Ran Kou , Hongjun Gao , Qingmei Wan
IPC分类号： C08G65/26
CPC分类号： C08G65/2609 , C08G65/2648 , C08G65/2693 , C08G65/2696
摘要： Related are a high-molecular weight allyl alcohol polyoxyethylene polyoxypropylene ether and a preparation method. During preparation, an allyl alcohol raw material and a supported catalyst Rb-NHPA are firstly added into a high-pressure reaction kettle, and it is heated after being replaced with a nitrogen gas; then after the internal temperature of the reaction kettle is raised to a reaction temperature, an ethylene oxide (EO) and propylene oxide (PO) mixture is continuously fed for a reaction; and finally, after the internal temperature of the reaction kettle is reduced, an acetic acid is dropwise added into the reaction kettle so that the crude product of the high-molecular weight allyl alcohol polyoxyethylene polyoxypropylene ether is neutralized to be neutral. The refining process of a polyether is omitted, the process flow is greatly simplified, and the process time is effectively saved. In addition, the supported catalyst Rb-NHP may be recycled.
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4.发明公开公开(公告)号：US20230174714A1
公开(公告)日：2023-06-08
申请号：US18071656
申请日：2022-11-30
申请人： Zhejiang Huangma Technology Co., Ltd. , Zhejiang Lukean Chemical Co., Ltd. , Zhejiang Huangma Shangyi New Material Co., Ltd. , Shangyu Huangma Surface Activated Reagent Research Institute Co., Ltd.
发明人： Weisong Wang , Xinrong Wang , Yifeng Jin , Shengli Wang , Jiang Yu , Shicong Zhao , Baocheng Qiu
CPC分类号： C08G65/269 , B01J23/885 , B01J23/10 , B01J21/04 , B01J21/06 , B01J21/10 , B01J2523/3712 , B01J2523/31 , B01J2523/17 , B01J2523/68 , B01J2523/47 , B01J2523/22 , B01J2523/41
摘要： The present invention relates to a supported catalyst used for synthesizing polyether amine, a preparation method, and an application. The supported catalyst introduces Mo and CeO2 into Ni and Cu active components. By means of the cooperation of Ni, Cu and Mo, CeO2 and Ni form more active sites, such that the supported catalyst can have high reaction activity and selectivity. By using the supported catalyst to synthesize polyether amine, the amination efficiency and selectivity of polyether polyol can be greatly enhanced, thereby preparing the polyether amine with light color and narrow molecular weight distribution. In addition, the cost of the catalyst can be reduced, a process condition is relatively mild, and the disadvantage of low reaction activity of a nickel-based catalyst in synthesizing small molecule polyether amine can be overcome, such that the supported catalyst has a desirable industrial application prospect.
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5.发明公开公开(公告)号：US20230167239A1
公开(公告)日：2023-06-01
申请号：US18071608
申请日：2022-11-29
申请人： Zhejiang Huangma Technology Co., Ltd. , Zhejiang Lukean Chemical Co., Ltd. , Shangyu Huangma Surface Activated Reagent Research Institute Co., Ltd. , Zhejiang Huangma Shangyi New Material Co., Ltd.
发明人： Weisong Wang , Jiang Yu , Xinrong Wang , Yifeng Jin , Majishi Wang , Minggui Song , Jiongfeng Zhao
IPC分类号： C08G65/00
CPC分类号： C08G65/00
摘要： Provided are a system and a method for preparing a polyether amine by catalytic amination of a polyether diol. The preparation method includes: filling a catalyst into the fixed bed reactor; pressurizing the internal pressure of the fixed bed reactor to 10˜13 MPa by a hydrogen gas, and raising the temperature of the fixed bed reactor to 150˜185° C.; adjusting the temperature of the multi-stage preheater so that the feeding temperature of a raw material reaches 125˜135° C.; and simultaneously feeding a polyether diol, liquid ammonia and the hydrogen gas into the multi-stage preheater, and after mixing and preheating, introducing into the fixed bed reactor from the feed inlet of the fixed bed reactor for a continuous catalytic amination reaction. The total amine value of the polyether amine finally obtained by the present invention reaches 28˜32 mgKOH/g, the color reaches 10˜20, and it is colorless transparent liquid.
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6.发明授权公开(公告)号：US12030989B2
公开(公告)日：2024-07-09
申请号：US18071656
申请日：2022-11-30
申请人： Zhejiang Huangma Technology Co., Ltd. , Zhejiang Lukean Chemical Co., Ltd. , Zhejiang Huangma Shangyi New Material Co., Ltd. , Shangyu Huangma Surface Activated Reagent Research Institute Co., Ltd.
发明人： Weisong Wang , Xinrong Wang , Yifeng Jin , Shengli Wang , Jiang Yu , Shicong Zhao , Baocheng Qiu
IPC分类号： B01J21/04 , B01J21/06 , B01J21/08 , B01J21/10 , B01J23/10 , B01J23/28 , B01J23/72 , B01J23/755 , B01J23/83 , B01J23/883 , B01J23/885 , C08G65/26
CPC分类号： C08G65/269 , B01J21/04 , B01J21/06 , B01J21/10 , B01J23/10 , B01J23/885 , B01J2523/17 , B01J2523/22 , B01J2523/31 , B01J2523/3712 , B01J2523/41 , B01J2523/47 , B01J2523/68
摘要： Disclosed are to a supported catalyst used for synthesizing polyether amine, and a preparation method and use thereof. The supported catalyst introduces Mo and CeO2 into Ni and Cu active components. By means of the cooperation of Ni, Cu and Mo, CeO2 and Ni form more active sites, such that the supported catalyst can have high reaction activity and selectivity. By using the supported catalyst to synthesize polyether amine, the amination efficiency and selectivity of polyether polyol can be greatly enhanced, thereby preparing the polyether amine with light color and narrow molecular weight distribution. In addition, the cost of the catalyst can be reduced, a process condition is relatively mild, and the disadvantage of low reaction activity of a nickel-based catalyst in synthesizing small molecule polyether amine can be overcome, such that the supported catalyst has a desirable industrial application prospect.
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7.发明授权公开(公告)号：US11845831B2
公开(公告)日：2023-12-19
申请号：US18075424
申请日：2022-12-06
申请人： Zhejiang Huangma Technology Co., Ltd. , Zhejiang Huangma Shangyi New Material Co., Ltd. , Zhejiang Lukean Chemical Co., Ltd. , Shangyu Huangma Surface Activated Reagent Research Institute Co., Ltd.
发明人： Weisong Wang , Yifeng Jin , Majishi Wang , Dinglian Ma , Ran Kou , Hongjun Gao , Qingmei Wan
IPC分类号： C08G65/26
CPC分类号： C08G65/2609 , C08G65/2648 , C08G65/2693 , C08G65/2696
摘要： Related are a high-molecular weight allyl alcohol polyoxyethylene polyoxypropylene ether and a preparation method. During preparation, an allyl alcohol raw material and a supported catalyst Rb-NHPA are firstly added into a high-pressure reaction kettle, and it is heated after being replaced with a nitrogen gas; then after the internal temperature of the reaction kettle is raised to a reaction temperature, an ethylene oxide (EO) and propylene oxide (PO) mixture is continuously fed for a reaction; and finally, after the internal temperature of the reaction kettle is reduced, an acetic acid is dropwise added into the reaction kettle so that the crude product of the high-molecular weight allyl alcohol polyoxyethylene polyoxypropylene ether is neutralized to be neutral. The refining process of a polyether is omitted, the process flow is greatly simplified, and the process time is effectively saved. In addition, the supported catalyst Rb-NHP may be recycled.
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公开(公告)号：US20230054287A1
公开(公告)日：2023-02-23
申请号：US17792717
申请日：2021-07-16
申请人： Zhejiang Huangma Technology Co., Ltd. , Zhejiang Lukean Chemical Co., Ltd. , Zhejiang Huangma Shangyi New Material Co., Ltd. , Shangyu Huangma Surface Activated Reagent Research Institute Co., Ltd.
发明人： Weisong Wang , Yifeng Jin , Xinrong Wang , Majishi Wang , Jiongfeng Zhao
摘要： The disclosure provides a preparation process of an allyl alcohol polyether with a low potassium and sodium content, comprising the following steps: reacting allyl alcohol with a mixture of epoxypropane and oxacyclopropane to prepare an allyl alcohol oligomer crude product with a molecular weight of 150-1500; reducing the total content of potassium and sodium ions in the allyl alcohol oligomer crude product prepared in step S1 to 2 ppm or less through a cation exchange resin; and reacting the allyl alcohol oligomer product treated in step S2 with the mixture of epoxypropane and oxacyclopropane to prepare allyl alcohol high-molecular-weight polyether with a molecular weight of 2000-5000. According to the present disclosure, the total content of potassium and sodium ions in the product is reduced to 2 ppm or less, and the product has a good double bond protection rate.
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