公开(公告)号：US4818575A

公开(公告)日：1989-04-04

申请号：US20998

申请日：1987-03-02

申请人： Shunsaku Hirata ,  Shigezo Nohara ,  Sadao Hirata

发明人： Shunsaku Hirata ,  Shigezo Nohara ,  Sadao Hirata

IPC分类号： B29C49/06 ,  B29C49/12 ,  B29C49/22 ,  B29C49/64 ,  B29C49/66 ,  B32B27/08 ,  B65D1/02 ,  B65D90/02

CPC分类号： B65D1/0215 ,  B29C49/22 ,  B29C49/6472 ,  B29C49/66 ,  B32B27/08 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/14033 ,  B29B2911/1404 ,  B29B2911/14053 ,  B29B2911/14066 ,  B29B2911/1408 ,  B29B2911/14093 ,  B29B2911/1412 ,  B29B2911/14126 ,  B29B2911/14146 ,  B29B2911/14153 ,  B29B2911/14173 ,  B29B2911/1418 ,  B29B2911/14313 ,  B29C49/06 ,  B29C49/12 ,  B29K2067/00 ,  B29K2077/00 ,  B29K2995/0017 ,  B29K2995/0043 ,  B29K2995/0067 ,  B29K2995/0069 ,  Y10T428/1383

摘要： The present invention is based on the finding that when a multi-layer blow-formed body is heat-treated, cooled and taken out, an intermediate layer of a gas-barrier resin in the multi-layer blow-formed body acts as a heat-insulating layer and if the blow-formed body is cooled from the interior by a cooling fluid, a shape-retaining property necessary for taking out the blow-formed body from the mold can be promptly obtained. A biaxially drawn polyester vessel excellent in the resistance to thermal contraction and gas-barrier properties can be prepared at a high manufacturing speed with a reduced number of steps by preheating or temeprature-adjusting a multi-layer preform comprising inner and outer layers of a polyester composed mainly of ethylene terephthalate units and at least one intermediate layer composed of a gas-barrier resin to a temperature suitable for drawing, carrying out the biaxial draw-blow forming of the preform and the heat treatment of the blow-formed body in a mold maintained at a heat-setting temperature, changing over a compressed fluid for the blow-forming to a fluid for internal cooling, cooling the blow-formed body to a temperature at which deformation is not caused when the blow-formed body is taken out from the mold, while contacting the blow-formed body with the surface of the mold cavity, and taking out the formed body from the mold.

摘要翻译： 本发明基于以下发现：当多层吹塑体被热处理，冷却和取出时，多层吹塑体中的阻气性树脂的中间层作为热 并且如果吹塑体通过冷却流体从内部冷却，则可以迅速地获得从模具取出吹塑成形体所需的形状保持性。 通过预热或温度调节包含聚酯的内层和外层的多层预成型件，可以以高制造速度制备具有优异耐热收缩性和阻气性的双轴拉伸聚酯容器 主要由对苯二甲酸乙二醇酯单元组成的至少一层中间层，至少一层由气体阻隔性树脂组成的中间层，以适于拉伸的温度，进行预成型体的双轴拉伸吹塑成型和吹塑成形体在模具中的热处理 保持在热定形温度，将用于吹塑的压缩流体切换成用于内部冷却的流体，将吹塑成形体冷却到当吹塑体被取出时不会发生变形的温度 模具，同时使吹塑体与模腔的表面接触，并从模具中取出成形体。

公开(公告)号：US4217161A

公开(公告)日：1980-08-12

申请号：US955614

申请日：1978-10-30

申请人： Muneki Yamada ,  Sadao Hirata ,  Jinichi Yazaki ,  Yoshitsugu Maruhashi ,  Kozaburo Sakano ,  Akira Kishimoto ,  Shunsaku Hirata ,  Toru Suzuki ,  Fumio Kano

发明人： Muneki Yamada ,  Sadao Hirata ,  Jinichi Yazaki ,  Yoshitsugu Maruhashi ,  Kozaburo Sakano ,  Akira Kishimoto ,  Shunsaku Hirata ,  Toru Suzuki ,  Fumio Kano

IPC分类号： B29C47/06 ,  B29C51/14 ,  B32B27/08 ,  B65D65/40 ,  B29D7/02

CPC分类号： B32B27/08 ,  B29C47/0023 ,  B29C47/065 ,  B29C47/145 ,  B29C47/26 ,  B29C51/14 ,  B29C47/0019 ,  B29C47/0021

摘要： A transparent multi-layer container comprising a co-extrudate of an oxygen-barrier resin layer and an orienting resin layer which is monoaxially or biaxially oriented is disclosed. An adhesive resin layer is preferably interposed between the oxygen-barrier layer and the orienting resin layer, and this co-extrudate is drawn and molded at a specific temperature determined relatively to the melting points and softening points of the respective resins. This container is excellent in the combination of transparency, rigidity, mechanical strength, gas-barrier property and interlaminar peel strength.

摘要翻译： 公开了一种透明的多层容器，其包含氧阻隔树脂层和单轴或双轴取向的取向树脂层的共挤出物。 粘合树脂层优选插入在氧阻隔层和定向树脂层之间，并且该共挤出物在相对于各树脂的熔点和软化点确定的特定温度下拉伸和模制。 该容器在透明度，刚性，机械强度，阻气性和层间剥离强度的组合方面优异。

公开(公告)号：US4261473A

公开(公告)日：1981-04-14

申请号：US750376

申请日：1976-12-14

申请人： Muneki Yamada ,  Sadao Hirata ,  Shunsaku Hirata ,  Akira Kishimoto ,  Fumio Kano ,  Jinichi Yazaki ,  Toru Suzuki

发明人： Muneki Yamada ,  Sadao Hirata ,  Shunsaku Hirata ,  Akira Kishimoto ,  Fumio Kano ,  Jinichi Yazaki ,  Toru Suzuki

IPC分类号： B29C49/00 ,  B29C49/22 ,  B65D1/00 ,  B65D23/00 ,  B32B27/08 ,  B32B27/30 ,  B32B27/36

CPC分类号： B29C49/22 ,  B29C49/0005 ,  B65D1/00 ,  B29B2911/1402 ,  B29B2911/14026 ,  B29B2911/14033 ,  B29B2911/1404 ,  B29B2911/14053 ,  B29B2911/14066 ,  B29B2911/1408 ,  B29B2911/14093 ,  B29B2911/14106 ,  B29B2911/14113 ,  B29B2911/1412 ,  B29B2911/14126 ,  B29B2911/14133 ,  B29B2911/1414 ,  B29B2911/1416 ,  B29B2911/14166 ,  B29B2911/14173 ,  B29B2911/14313 ,  B29B2911/14593 ,  B29B2911/14653 ,  B29B2911/14713 ,  B29C2049/1219 ,  B29C2049/4647 ,  Y10S428/91 ,  Y10T428/1379 ,  Y10T428/31507 ,  Y10T428/31511 ,  Y10T428/31725 ,  Y10T428/31728 ,  Y10T428/31736 ,  Y10T428/3175 ,  Y10T428/31757 ,  Y10T428/31761 ,  Y10T428/31786 ,  Y10T428/31797 ,  Y10T428/31855 ,  Y10T428/31859 ,  Y10T428/31909 ,  Y10T428/31917 ,  Y10T428/3192 ,  Y10T428/31924 ,  Y10T428/31928 ,  Y10T428/31931 ,  Y10T428/31935 ,  Y10T428/31938

摘要： A molded container having a wall composed of a thermoplastic resin oriented in at least one direction on the wall face, wherein the container wall has a layer of a blend composed mainly of a plurality of melt-extrudable thermoplastic resins, each of which has a solubility parameter (Sp) of at least 9.5, at least one of said thermoplastic resins has an oxygen permeability lower than 5.times.10.sup.-11 cc.multidot.cm/cm.sup.2 .multidot.sec.multidot.cmHg, said thermoplastic resins are chosen so that the difference (.DELTA.Sp) of the solubility parameter in said thermoplastic resins is not greater than 4.5, the elongation of said resin blend is higher than the arithmetic mean (.epsilon.) of elongations of the respective thermoplastic resins, and wherein the container has a thermal shrinkability (.delta.) of at least 5% in the orientation direction of said container wall.

摘要翻译： 一种成型容器，其具有由在壁面上至少一个方向取向的热塑性树脂构成的壁，其中所述容器壁具有主要由多个可熔融挤出的热塑性树脂组成的共混物层，每个所述共混物具有溶解度 参数（Sp）至少为9.5，所述热塑性树脂中的至少一种具有低于5×10-11cc×cm / cm2×sec×cmHg的氧气渗透性，所述热塑性树脂被选择为使得所述热塑性树脂中的溶解度参数的差（ΔDTASp） 不大于4.5，所述树脂共混物的伸长率高于各热塑性树脂的伸长率的算术平均值（ε），并且其中容器的热收缩性（δ）在取向方向上至少为5％ 说容器墙。

公开(公告)号：US4182457A

公开(公告)日：1980-01-08

申请号：US821484

申请日：1977-08-03

申请人： Muneki Yamada ,  Sadao Hirata ,  Jinichi Yazaki ,  Yoshitsugu Maruhashi ,  Kozaburo Sakano ,  Akira Kishimoto ,  Shunsaku Hirata ,  Toru Suzuki ,  Fumio Kano

发明人： Muneki Yamada ,  Sadao Hirata ,  Jinichi Yazaki ,  Yoshitsugu Maruhashi ,  Kozaburo Sakano ,  Akira Kishimoto ,  Shunsaku Hirata ,  Toru Suzuki ,  Fumio Kano

IPC分类号： B29C51/14 ,  B32B27/00 ,  B32B27/08 ,  B65D65/40 ,  B32B15/08

CPC分类号： B32B27/08 ,  B29C51/14 ,  B32B2272/00 ,  Y10S428/91 ,  Y10T428/1379

摘要： A transparent multi-layer container comprising a co-extrudate of an oxygen-barrier resin layer and an orienting resin layer which is monoaxially or biaxially oriented is disclosed. An adhesive resin layer is preferably interposed between the oxygen-barrier layer and the orienting resin layer, and this co-extrudate is drawn and molded at a specific temperature determined relatively to the melting points and softening points of the respective resins. This container is excellent in the combination of transparency, rigidity, mechanical strength, gas-barrier property and interlaminar peel strength.

摘要翻译： 公开了一种透明的多层容器，其包含氧阻隔树脂层和单轴或双轴取向的取向树脂层的共挤出物。 粘合树脂层优选插入在氧阻隔层和定向树脂层之间，并且该共挤出物在相对于各树脂的熔点和软化点确定的特定温度下拉伸和模制。 该容器在透明度，刚性，机械强度，阻气性和层间剥离强度的组合方面优异。

公开(公告)号：US4082854A

公开(公告)日：1978-04-04

申请号：US660003

申请日：1976-02-23

申请人： Muneki Yamada ,  Sadao Hirata ,  Akira Kishimoto ,  Shunsaku Hirata ,  Toru Suzuki ,  Fumio Kano

发明人： Muneki Yamada ,  Sadao Hirata ,  Akira Kishimoto ,  Shunsaku Hirata ,  Toru Suzuki ,  Fumio Kano

IPC分类号： C08L23/00 ,  A22C13/00 ,  A23B4/00 ,  A23B7/00 ,  A23B7/12 ,  A23D9/06 ,  A23L3/00 ,  A23L27/60 ,  B29C49/22 ,  B29C63/00 ,  B29C71/00 ,  B29C71/02 ,  B32B27/28 ,  B32B27/30 ,  B32B27/32 ,  B32B37/00 ,  B32B37/06 ,  B32B37/15 ,  B65B55/02 ,  B65D1/00 ,  B65D65/00 ,  B65D65/38 ,  B65D65/40 ,  B65D81/24 ,  B65D85/72 ,  C08J5/18 ,  C08L7/00 ,  C08L21/00 ,  C08L29/04 ,  C08L33/00 ,  C08L33/02 ,  C08L51/00 ,  C08L51/02 ,  C08L67/00 ,  C08L77/00 ,  C08L101/00 ,  B65D85/00 ,  B32B27/08 ,  C08G41/04

CPC分类号： B29C49/22 ,  B32B27/30 ,  B65D65/38 ,  Y10T428/1379 ,  Y10T428/31743 ,  Y10T428/31746 ,  Y10T428/31797 ,  Y10T428/3192 ,  Y10T428/31924 ,  Y10T428/31928 ,  Y10T428/31931 ,  Y10T428/31935

摘要： A packaging material having an improved gas permeation resistance, which comprises at least one layer composed of (A) an ethylene-vinyl alcohol copolymer having a vinyl alcohol content of 50 to 75 mole % and a residual vinyl ester content of up to 4 mole % based on the sum of the vinyl alcohol and vinyl ester or (B) a blend of said ethylene-vinyl alcohol copolymer with up to 150% by weight, based on said copolymer, of at least one thermoplastic polymer other than said copolymer, said ethylenevinyl alcohol copolymer having a main endothermic peak satisfying substantially the following requirement:Y.sub.1 = 1.64X + 68.0wherein Y.sub.1 stands for the main endothermic peak temperature (.degree. C.) in the differential thermal analysis, and X stands for the vinyl alcohol content (mole %) in the ethylene-vinyl alcohol copolymer,And at least one subsidary endothermic peak satisfying substantially the following requirement:0.67 X + 76.7 .gtoreq. Y.sub.2 .gtoreq. 0.40 X + 40.0preferably0.67 X + 76.7 .gtoreq. Y.sub.2 .gtoreq. 0.34 X + 88.0wherein Y.sub.2 stands for the subsidary endothermic peak temperature (.degree. C.) in the differential thermal analysis, and X is as defined above,The ratio (Rs) of the subsidary endothermic peak area to the main endothermic peak area being at least 2.5%.

公开(公告)号：US4079850A

公开(公告)日：1978-03-21

申请号：US551388

申请日：1975-02-21

申请人： Toru Suzuki ,  Shunsaku Hirata ,  Jinichi Yazaki ,  Shinichi Miyazaki ,  Shigezo Nohara

发明人： Toru Suzuki ,  Shunsaku Hirata ,  Jinichi Yazaki ,  Shinichi Miyazaki ,  Shigezo Nohara

IPC分类号： B29C49/22 ,  B65D1/02 ,  B65D23/00 ,  B29C17/06

CPC分类号： B29C49/22 ,  B65D1/0215 ,  B29B2911/14653 ,  B29B2911/14713 ,  B29B2911/1478 ,  Y10S220/14 ,  Y10T428/1383 ,  Y10T428/24628 ,  Y10T428/31746 ,  Y10T428/31797 ,  Y10T428/31913

摘要： In a multi-layer blow molded container having a joint portion at least in the bottom portion thereof, barrier characteristics to gases such as oxygen and water vapor and liquids such as water, solvents, aqueous ammonia and salt water and interlaminar strength characteristics such as interlaminar adhesion strength, peel strength and impact strength in the content-filled state can be highly improved by blow molding a parison of a laminate structure of two or more polymer layers in which the polymer composition is different with respect to the thickness direction of the container wall but substantially identical with respect to the plane direction and each of the polymer layers is continuous with respect to the plane direction, in such a manner that a tapered projection protruding outwardly in the thickness direction of the container wall is formed in the joint portion so that each of the polymer layers is substantially continuous in this joint portion. This improved container can easily be prepared according to the customary blow molding technique by using a pair of split molds having such a configuration that a tapered concave groove is formed in the section pinching off the parison when the molds are registered with each other.

摘要翻译： 在具有至少在其底部的接合部分的多层吹塑容器中，气体如氧气和水蒸气的阻挡特性以及水，溶剂，氨水和盐水等液体和层间强度特性如层间 通过将聚合物组合物相对于容器壁的厚度方向不同的两个或更多个聚合物层的叠层结构的型坯吹塑成型，可以大大提高填充内容物中的粘合强度，剥离强度和冲击强度 但是相对于平面方向基本上相同，并且每个聚合物层相对于平面方向是连续的，使得在接合部分中形成在容器壁的厚度方向上向外突出的锥形突起，使得 每个聚合物层在该接合部分中基本连续。 这种改进的容器可以根据传统的吹塑技术容易地通过使用一对分开模具来制备，所述分开模具具有这样的构造，即当模具彼此登记时，在挤压型坯的截面中形成锥形凹槽。