Synthesis of pentafluorosulfuranyl substituted alkanes
    1.
    发明授权
    Synthesis of pentafluorosulfuranyl substituted alkanes 失效
    五氟硫烷基取代烷烃的合成

    公开(公告)号:US06870068B1

    公开(公告)日:2005-03-22

    申请号:US10713230

    申请日:2003-11-14

    IPC分类号: C07C381/00 C07C309/00

    CPC分类号: C07C381/00

    摘要: Addition of an SF5 group to organic compounds such as alkyl-substituted terminal alkenes, internal alkenes and cycloalkenes via the reaction with SF5Br is effected under liquid phase conditions and generally in the presence of a free radical initiator, preferably triethyl borane.

    摘要翻译: 通过与SF5Br的反应将SF5基团与有机化合物如烷基取代的末端烯烃,内部烯烃和环烯烃相加,在液相条件下通常在自由基引发剂,优选三乙基硼烷的存在下进行。

    Alkylated aminoether surfactants
    2.
    发明授权
    Alkylated aminoether surfactants 失效
    烷基化氨基醚表面活性剂

    公开(公告)号:US06492559B1

    公开(公告)日:2002-12-10

    申请号:US09477342

    申请日:2000-01-04

    IPC分类号: C07C21300

    摘要: This invention provides water-based compositions, particularly coating, ink, and agricultural compositions, manifesting reduced equilibrium and dynamic surface tension by the incorporation of a surface tension reducing amount of certain alkylated aminoether compounds of the structure R—HN(CH2)p[O(CH2)n]mO(CH2)qNH—R′ where n is 2-6, m is 0-4, and p and q are 2-6, and R and R′ independently are an alkyl group comprising 5 to 18 carbons, preferably which is branched or in which the point of attachment to nitrogen is on a nonterminal carbon.

    摘要翻译: 本发明提供水基组合物,特别是涂料,油墨和农业组合物,通过结合表面张力降低量的某些烷基化氨基醚化合物,其中n为2-6,m为0,表现出减少的平衡和动态表面张力 -4,p和q是2-6,R和R'独立地是包含5至18个碳的烷基,优选是支链的,或者其中氮的连接点在非末端碳上。

    Alkylated aminoether surfactants
    4.
    发明授权
    Alkylated aminoether surfactants 失效
    烷基化氨基醚表面活性剂

    公开(公告)号:US06190733B1

    公开(公告)日:2001-02-20

    申请号:US09327068

    申请日:1999-06-07

    IPC分类号: B05D500

    摘要: This invention provides water-based compositions, particularly coating, ink, and agricultural compositions, manifesting reduced equilibrium and dynamic surface tension by the incorporation of a surface tension reducing amount of certain alkylated aminoether compounds of the structure R—HN(CH2)p[O(CH2)n]mO(CH2)qNH—R′ where n is 2-6, m is 0-4, and p and q are 2-6, and R and R′ independently are an alkyl group comprising 5 to 18 carbons, preferably which is branched or in which the point of attachment to nitrogen is on a nonterminal carbon.

    摘要翻译: 本发明提供水基组合物,特别是涂料,油墨和农业组合物,通过结合表面张力降低量的某些烷基化氨基醚化合物,其中n为2-6,m为0,表现出减少的平衡和动态表面张力 -4,p和q是2-6,R和R'独立地是包含5至18个碳的烷基,优选是支链的,或者其中氮的连接点在非末端碳上。

    Synthesis of pentafluorosulfuranyl arylenes
    6.
    发明授权
    Synthesis of pentafluorosulfuranyl arylenes 有权
    五氟硫烷基亚芳基的合成

    公开(公告)号:US06958415B2

    公开(公告)日:2005-10-25

    申请号:US10713231

    申请日:2003-11-14

    IPC分类号: C07B61/00 C07C381/00

    CPC分类号: C07C381/00

    摘要: A new route has been found leading to the formation of pentafluorosulfuranyl arylenes. In its broadest aspect the process comprises: effecting dehydrohalogenation or dehydrogenation of a pentafluorosulfuranyl cycloaliphatic compound represented by either of the structures: wherein R1-5 are H, halogen, C1-10 alkyl, C1-10 alkoxy, C1-10 thionyl, C1-10 alkyl ether, aryl and substituted aryl, thioether, sulfonyl, carboalkoxy, alkylamino, arylamino, alkylphosphoryl, alkylphosphonyl, arylphosphonyl, arylphosphoryl, and mixtures thereof and X is a halogen atom to form the pentafluorosufuranyl arylene represented by the structures: wherein R1-R5 are as represented above.

    摘要翻译: 已经发现导致形成五氟硫烷基亚芳基的新途径。 在其最广泛的方面,该方法包括:进行由以下任一结构表示的五氟硫烷基环脂族化合物的脱卤化氢或脱氢:其中R 1-5是H,卤素,C 1-10 - 亚烷基,C 1-10烷氧基,C 1-10亚硫酰基,C 1-10烷基醚,芳基和取代的芳基,硫醚 磺酰基,烷氧基羰基,烷基氨基,芳基氨基,烷基磷酰基,烷基膦酰基,芳基膦酰基,芳基磷酰基及其混合物,X是卤素原子,形成由以下结构表示的五氟呋喃基亚芳基:其中R 1 -R < > 5 如上所示。

    Process for the production of cyclic N,N'-dialkylureas
    7.
    发明授权
    Process for the production of cyclic N,N'-dialkylureas 失效
    制备环状N,N'-二烷基脲的方法

    公开(公告)号:US6096891A

    公开(公告)日:2000-08-01

    申请号:US457787

    申请日:1999-12-09

    IPC分类号: C07D239/46 C07D239/22

    CPC分类号: C07D239/47

    摘要: N,N'-dialkylurea and an .alpha.,.beta.-unsaturated nitrile are reacted to form a cyclic N,N'-dialkylurea containing an imine group on a ring carbon. This compound is useful as an intermediate in the formation of N,N'-dialkylpropyleneureas by hydrogenation followed by hydrogenolysis to remove the imine group. Using N,N'-dimethylurea and acrylonitrile as the starting materials one can arrive at N,N'-dimethylpropyleneurea which is a compound useful as an organic solvent and known by its acronym, DMPU.

    摘要翻译: N,N'-二烷基脲和α,β-不饱和腈反应以在环碳上形成含有亚胺基团的环状N,N'-二烷基脲。 该化合物可用作通过氢化形成N,N'-二烷基丙烯脲的中间体,然后氢解除去亚胺基。 使用N,N'-二甲基脲和丙烯腈作为起始原料,可以得到N,N'-二甲基亚丙基脲,它是一种可用作有机溶剂的化合物,并以其简称DMPU公知。

    Pentafluorosulfanyl-substituted thienothiophene monomers and conducting polymers
    10.
    发明授权
    Pentafluorosulfanyl-substituted thienothiophene monomers and conducting polymers 失效
    五氟硫烷基取代的噻吩并噻吩单体和导电聚合物

    公开(公告)号:US07094365B2

    公开(公告)日:2006-08-22

    申请号:US10958054

    申请日:2004-10-04

    IPC分类号: H01B1/12 C07D333/00

    CPC分类号: C08G61/126 H01B1/127

    摘要: Thienothiophene monomers having an SF5 group and conducting oligomers and polymers formed by the polymerization of such monomers and their use as hole injection materials, charge transport materials, or as semiconductors. The compound may be of the formula: where X and X′ are independently H, halogen atoms (e.g., F, Cl, Br, and I), MgCl, MgBr, MgI, Sn(R′)3, where R′ is C1-6 alkyl or —OC1-6 alkyl, boronic acid, boronic ester, —CH═CHR″ (where R″ is H or C1-6 alkyl), —OC1-6 alkyl, —COOC1-6 alkyl, —S—COR′″ and —COR′″ (where R′″ is H or C1-6 alkyl), —C≡CH, or polymerizable aromatic rings (such as phenyl, naphthalene, pyrrole, dithiophene, thienothiophene, thiophene and so forth.

    摘要翻译: 具有SF 5 N基团的噻吩并噻吩单体和通过这些单体的聚合形成的导电低聚物和聚合物及其作为空穴注入材料,电荷传输材料或半导体的用途。 化合物可以具有下式:其中X和X'独立地为H,卤素原子(例如F,Cl,Br和I),MgCl,MgBr,MgI,Sn(R')3 >,其中R'是C 1-6烷基或-OC 1-6 - 烷基,硼酸,硼酸酯,-CH-CHR“(其中R” 是H或C 1-6烷基),-OC 1-6烷基,-COOC 1-6烷基,-S-COR' '和-COR''(其中R“'是H或C 1-6烷基),-C≡CH或可聚合的芳环(例如苯基,萘,吡咯,二噻吩 噻吩并噻吩,噻吩等。