公开(公告)号：US07432340B2

公开(公告)日：2008-10-07

申请号：US11128538

申请日：2005-05-13

申请人： Steffen Zahn ,  Gauri Sankar Lal ,  William Franklin Burgoyne, Jr. ,  Kristen Elaine Minnich ,  Andrew Francis Nordquist ,  Lloyd Mahlon Robeson ,  Francis Joseph Waller

发明人： Steffen Zahn ,  Gauri Sankar Lal ,  William Franklin Burgoyne, Jr. ,  Kristen Elaine Minnich ,  Andrew Francis Nordquist ,  Lloyd Mahlon Robeson ,  Francis Joseph Waller

IPC分类号： C08G73/24 ,  C08F4/80 ,  C08G75/00

CPC分类号： C08G61/123 ,  C08G61/126

摘要： Partially and fully fluorinated alkyl substituted thienothiophene monomers (and polymers thereof) wherein the monomers are represented by the formula: wherein R is a partially or fully fluorinated primary, secondary or tertiary alkyl having from 1 to 8 carbon atoms; and X and X′ are independently selected from the group consisting of H, F, Cl, Br, I, MgCl, MgBr, Mgl, Sn(R′)3, CH═CHR″, —OR″, —COOR″, —S—COR″, —B(OR″)2, —COR″, —C≡CH, and a polymerizable cyclic pi-conjugated carbon-ring structure optionally comprising S, N or O heteroatoms; wherein R′ is a primary, secondary or tertiary alkyl having from 1 to 6 carbon atoms, and R″ is H or a primary, secondary or tertiary alkyl having from 1 to 6 carbon atoms.

摘要翻译： 部分和完全氟化的烷基取代的噻吩并噻吩单体（及其聚合物），其中单体由下式表示：其中R是具有1至8个碳原子的部分或完全氟化的伯，仲或叔烷基; 并且X和X'独立地选自H，F，Cl，Br，I，MgCl，MgBr，MgI，Sn（R'）3，CH-CHR“， - OR“，-COOR”，-S-COR“，-B（OR”）2，-COR“，-C≡CH和可聚合的环状π-共轭碳 任选地包含S，N或O杂原子的环结构; 其中R'是具有1至6个碳原子的伯，仲或叔烷基，R“是H或具有1至6个碳原子的伯，仲或叔烷基。

公开(公告)号：US07572879B2

公开(公告)日：2009-08-11

申请号：US11418317

申请日：2006-05-05

申请人： Steffen Zahn ,  Gauri Sankar Lal ,  William Franklin Burgoyne, Jr. ,  Kristen Elaine Minnich ,  Andrew Francis Nordquist ,  Lloyd Mahlon Robeson ,  Francis Joseph Waller

发明人： Steffen Zahn ,  Gauri Sankar Lal ,  William Franklin Burgoyne, Jr. ,  Kristen Elaine Minnich ,  Andrew Francis Nordquist ,  Lloyd Mahlon Robeson ,  Francis Joseph Waller

IPC分类号： C08G73/24 ,  C08G75/00 ,  C08F4/80

CPC分类号： C07D495/04 ,  C08G61/126 ,  C08G2261/146 ,  C08G2261/3243 ,  C08L25/12 ,  C08L25/18 ,  C08L27/12 ,  C08L33/02 ,  C08L35/00 ,  C08L65/00 ,  H01B1/127 ,  H01G11/48 ,  H01L51/0036 ,  Y02E60/13 ,  C08L2666/06 ,  C08L2666/04

摘要： Partially and fully fluorinated alkyl substituted thienothiophene monomers (and polymers thereof) wherein the monomers are represented by the formula: wherein R is a partially or fully fluorinated primary, secondary or tertiary alkyl having from 1 to 8 carbon atoms; and X and X′ are independently selected from the group consisting of H, F, Cl, Br, I, MgCl,  —COR″, —C≡CH, and a polymerizable cyclic pi-conjugated carbon-ring structure optionally comprising S, N or O heteroatoms; wherein R′ is a primary, secondary or tertiary alkyl having from 1 to 6 carbon atoms, and R″ is H or a primary, or tertiary alkyl having from 1 to 6 carbon atoms.

摘要翻译： 部分和完全氟化的烷基取代的噻吩并噻吩单体（及其聚合物），其中单体由下式表示：其中R是具有1至8个碳原子的部分或完全氟化的伯，仲或叔烷基; 并且X和X'独立地选自H，F，Cl，Br，I，MgCl，-COR“，-C≡CH，以及任选地包含S的可聚合环状π-共轭碳环结构， N或O杂原子; 其中R'是具有1至6个碳原子的伯，仲或叔烷基，R“是H或具有1至6个碳原子的伯或叔烷基。

公开(公告)号：US07115430B2

公开(公告)日：2006-10-03

申请号：US10987723

申请日：2004-11-12

申请人： Lloyd Mahlon Robeson ,  Gary L. Johnson ,  William Franklin Burgoyne, Jr. ,  Xuezhong Jiang

发明人： Lloyd Mahlon Robeson ,  Gary L. Johnson ,  William Franklin Burgoyne, Jr. ,  Xuezhong Jiang

IPC分类号： H01L21/00

CPC分类号： H01L51/0043 ,  H01L51/0035 ,  H01L51/0037 ,  H01L51/0073 ,  H01L51/0097 ,  H01L51/5012 ,  H01L2251/308 ,  Y02E10/549 ,  Y02P70/521

摘要： A light emitting device includes: (a) a light emitting layer including an electroluminescent organic material dispersed in a matrix, wherein the matrix contains a non-electroluminescent organic polymer having a Tg of at least 170° C., and each of the organic polymer and the electroluminescent organic material constitutes at least 20 percent by weight of the light emitting layer; and (b) electrodes in electrical communication with the light emitting layer and configured to conduct an electric charge through the light emitting layer such that the light emitting layer emits light. A method for manufacturing a flexible organic light emitting device, includes providing the light emitting layer and providing electrodes above and below the light emitting layer, wherein the electrodes are in electrical communication with the light emitting layer.

摘要翻译： 发光器件包括：（a）包含分散在基质中的电致发光有机材料的发光层，其中所述基质含有具有至少170℃的T 的非电致发光有机聚合物 有机聚合物和电致发光有机材料中的每一种构成至少20重量％的发光层; 和（b）与发光层电连通并且被配置为通过发光层传导电荷使得发光层发光的电极。 一种制造柔性有机发光器件的方法，包括提供发光层并在发光层之上和之下提供电极，其中电极与发光层电连通。

公开(公告)号：US5658994A

公开(公告)日：1997-08-19

申请号：US502511

申请日：1995-07-13

申请人： William Franklin Burgoyne, Jr. ,  Lloyd Mahlon Robeson ,  Raymond Nicholas Vrtis

发明人： William Franklin Burgoyne, Jr. ,  Lloyd Mahlon Robeson ,  Raymond Nicholas Vrtis

IPC分类号： C08G65/34 ,  C08G65/40 ,  C08L71/00 ,  H01L21/312 ,  H01L23/498 ,  H01L23/532 ,  C08G63/00

CPC分类号： C08L71/00 ,  C08G65/40 ,  H01L23/49894 ,  H01L23/5329 ,  C08L2203/20 ,  H01L2924/0002 ,  H01L2924/09701 ,  Y10T428/31504 ,  Y10T428/31533 ,  Y10T428/31645 ,  Y10T428/31667

摘要： An article of manufacture comprising a dielectric material on a microelectronic device, such as an integrated circuit, wherein the dielectric material contains a poly(arylene ether) polymer comprising a repeat unit of the structure: ##STR1## wherein m=0 to 1.0; and n=1.0-m; and Ar.sub.1, Ar.sub.2, Ar.sub.3 and Ar.sub.4 are individually divalent arylene radicals, but Ar.sub.1, Ar.sub.2, Ar.sub.3 and Ar.sub.4, other than a diradical 9,9-diphenylfluorene, cannot be isomeric equivalents.

摘要翻译： 包括在诸如集成电路的微电子器件上的电介质材料的制品，其中所述电介质材料包含聚（亚芳基醚）聚合物，所述聚（亚芳基醚）聚合物包含以下结构的重复单元：其中m = 0至1.0; 并且n = 1.0-m; Ar1，Ar2，Ar3和Ar4分别为二价亚芳基，但除双价9,9-二苯基芴以外的Ar1，Ar2，Ar3和Ar4不能为异构体。

公开(公告)号：US5874516A

公开(公告)日：1999-02-23

申请号：US502508

申请日：1995-07-13

申请人： William Franklin Burgoyne, Jr. ,  Lloyd Mahlon Robeson ,  Raymond Nicholas Vrtis

发明人： William Franklin Burgoyne, Jr. ,  Lloyd Mahlon Robeson ,  Raymond Nicholas Vrtis

IPC分类号： C08G65/34 ,  C08G65/40 ,  C08G65/48 ,  H01L23/498 ,  H01L23/532 ,  H05K3/46 ,  B32B27/04 ,  B32B27/28 ,  C08G65/00

CPC分类号： C08G65/40 ,  H01L23/49894 ,  H01L23/5329 ,  C08L2203/20 ,  H01L2924/0002 ,  H01L2924/09701

摘要： The present invention is directed to novel poly(arylene ethers), their synthesis and use in electronics applications as low dielectric insulating layers such as spin-on materials in integrated circuits. The polymers have repeating units of the structure: ##STR1## wherein m=0.2 to 1.0; and n=1.0-m; and Ar.sub.1, Ar.sub.2 and Ar.sub.3 are individually divalent arylene radicals selected from the group consisting of; ##STR2##

摘要翻译： 本发明涉及新颖的聚（亚芳基醚），它们在电子应用中的合成和应用，作为低介电绝缘层，例如集成电路中的旋涂材料。 聚合物具有以下结构的重复单元：其中m = 0.2至1.0; 并且n = 1.0-m; Ar 1，Ar 2和Ar 3分别是选自以下的二价亚芳基：

公开(公告)号：US07309833B2

公开(公告)日：2007-12-18

申请号：US10630279

申请日：2003-07-29

申请人： Lloyd Mahlon Robeson ,  Xuezhong Jiang ,  William Franklin Burgoyne, Jr.

发明人： Lloyd Mahlon Robeson ,  Xuezhong Jiang ,  William Franklin Burgoyne, Jr.

IPC分类号： H01L31/0256

CPC分类号： H01L51/4253 ,  H01L51/0035 ,  H01L51/0037 ,  H01L51/0053 ,  H01L51/0059 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L2251/308 ,  Y02E10/549 ,  Y02P70/521

摘要： A photovoltaic device having an anode, a cathode, and at least one photoactive layer between the anode and the cathode, wherein the at least one photoactive layer includes a composition containing a polymer having a glass transition temperature of at least 125° C.; and a photoactive material, wherein: (a) the photoactive material is a hole transporting organic material, an electron transporting organic material, and/or a light harvesting organic material, (b) the polymer and the photoactive material are in a single phase (c) the photoactive material constitutes at least 20% by weight of the composition, and (d) the at least one photoactive layer is in electrical communication with the anode and the cathode, the anode and the cathode are configured to conduct an electric charge from the at least one photoactive layer produced by the at least one photoactive layer absorbing light.

摘要翻译： 一种在阳极和阴极之间具有阳极，阴极和至少一个光活性层的光伏器件，其中所述至少一个光活性层包括含有玻璃化转变温度至少为125℃的聚合物的组合物; 和光活性材料，其中：（a）光活性材料是空穴传输有机材料，电子传输有机材料和/或光收集有机材料，（b）聚合物和光活性材料是单相 c）光活性材料构成组合物的至少20重量％，和（d）至少一个光活性层与阳极和阴极电连通，阳极和阴极构造成从 由所述至少一个光活性层产生的至少一个光活性层吸收光。

公开(公告)号：US06818919B2

公开(公告)日：2004-11-16

申请号：US10253108

申请日：2002-09-23

申请人： Lloyd Mahlon Robeson ,  Gary L. Johnson ,  William Franklin Burgoyne, Jr. ,  Xuezhong Jiang

发明人： Lloyd Mahlon Robeson ,  Gary L. Johnson ,  William Franklin Burgoyne, Jr. ,  Xuezhong Jiang

IPC分类号： H01L3524

CPC分类号： H01L51/0043 ,  H01L51/0035 ,  H01L51/0037 ,  H01L51/0073 ,  H01L51/0097 ,  H01L51/5012 ,  H01L2251/308 ,  Y02E10/549 ,  Y02P70/521

摘要： A light emitting device includes: (a) a light emitting layer including an electroluminescent organic material dispersed in a matrix, wherein the matrix contains a non-electroluminescent organic polymer having a Tg of at least 170° C., and each of the organic polymer and the electroluminescent organic material constitutes at least 20 percent by weight of the light emitting layer; and (b) electrodes in electrical communication with the light emitting layer and configured to conduct an electric charge through the light emitting layer such that the light emitting layer emits light. A method for manufacturing a flexible organic light emitting device, includes providing the light emitting layer and providing electrodes above and below the light emitting layer, wherein the electrodes are in electrical communication with the light emitting layer.

摘要翻译： 发光器件包括：（a）包含分散在基质中的电致发光有机材料的发光层，其中所述基质含有Tg为至少170℃的非电致发光有机聚合物，并且每种有机聚合物 并且所述电致发光有机材料占所述发光层的至少20重量％; 和（b）与发光层电连通并且被配置为通过发光层传导电荷使得发光层发光的电极。 一种制造柔性有机发光器件的方法，包括提供发光层并在发光层之上和之下提供电极，其中电极与发光层电连通。

公开(公告)号：US06187248B1

公开(公告)日：2001-02-13

申请号：US09196452

申请日：1998-11-19

申请人： Mark Leonard O'Neill ,  Lloyd Mahlon Robeson ,  William Franklin Burgoyne, Jr. ,  Michael Langsam

发明人： Mark Leonard O'Neill ,  Lloyd Mahlon Robeson ,  William Franklin Burgoyne, Jr. ,  Michael Langsam

IPC分类号： B29C3508

CPC分类号： H01L21/02118 ,  C08J9/28 ,  C08J2201/0502 ,  C08J2201/0542 ,  H01B3/306 ,  H01B3/42 ,  H01B3/427 ,  H01B3/442 ,  H01L21/02203 ,  H01L21/02282 ,  H01L21/312 ,  H01L21/31695

摘要： A process for producing a nanoporous polymer film of no greater than 10 micron thickness having low dielectric constant value, including the steps of: (a) providing a polymer in a solution with at least two solvents for the polymer in which a lowest boiling solvent and a highest boiling solvent have a difference in their respective boiling points of approximately 50° C. or greater; (b) forming a film of the polymer in solution with at least the two solvents on a substrate; (c) removing a predominant amount of the lowest boiling solvent; (d) contacting the film with a fluid which is a non-solvent for the polymer, but which is miscible with the at least two solvents to induce phase inversion in the film; (e) forming an average pore size in the film in the range of less than 30 nanometers. The present invention is also nanoporous films made by the above process.

摘要翻译： 一种用于制备具有低介电常数值的不大于10微米厚度的纳米多孔聚合物膜的方法，包括以下步骤：（a）在聚合物中提供聚合物至少两种溶剂，其中最低沸点溶剂和 最高沸点溶剂的沸点相差约为50℃以上; （b）在基材上用至少两种溶剂在溶液中形成聚合物膜; （c）除去主要量的最低沸点溶剂; （d）使膜与用于聚合物的非溶剂的流体接触，但与至少两种溶剂可混溶以在膜中诱导相转化; （e）在小于30纳米的范围内形成膜中的平均孔径。本发明还是通过上述方法制备的纳米多孔膜。

公开(公告)号：US07332223B2

公开(公告)日：2008-02-19

申请号：US11394906

申请日：2006-03-31

申请人： Gregory A. Sotzing ,  Francis Joseph Waller ,  Lloyd Mahlon Robeson

发明人： Gregory A. Sotzing ,  Francis Joseph Waller ,  Lloyd Mahlon Robeson

IPC分类号： B32B27/06 ,  C08G75/00

CPC分类号： C08G61/123 ,  C08G61/126 ,  H01G11/48 ,  H01G11/56 ,  Y02E60/13 ,  Y10T428/31533

摘要： This invention presents polymers and copolymers comprising repeating units of thieno[3,4-b]thiophene. Water-borne dispersions of such polymers and copolymers can be cast by conventional methods to provide uniform, thin films which possess utility in numerous electroactive applications including electrochromic displays, optically transparent electrodes and antistatic coatings. The compositions of this invention can be doped with conventional p-dopants or n-dopants. The invention also presents an aqueous process for preparing such compositions of matter.

摘要翻译： 本发明提供了包含噻吩并[3,4-b]噻吩重复单元的聚合物和共聚物。 这种聚合物和共聚物的水分散体可以通过常规方法浇铸以提供均匀的薄膜，其在许多电活性应用中具有实用性，包括电致变色显示器，光学透明电极和抗静电涂层。 本发明的组合物可掺杂常规的p-掺杂剂或n-掺杂剂。 本发明还提供了用于制备这种物质组合物的水性方法。

公开(公告)号：US06656998B1

公开(公告)日：2003-12-02

申请号：US09562345

申请日：2000-05-01

申请人： Lloyd Mahlon Robeson ,  Lori Anderson Vratsanos ,  Susan Ann Miller

发明人： Lloyd Mahlon Robeson ,  Lori Anderson Vratsanos ,  Susan Ann Miller

IPC分类号： C08L3104

CPC分类号： C09D131/04 ,  C08L31/04 ,  C08L2205/22 ,  C08L2666/04

摘要： Water-borne paints having an ASTM 60° gloss value of at least 10 are formulated with a latex of a copolymer of vinyl acetate and ethylene or alkyl acrylate having a dry glass transition temperature (Tg) below 20° C. and a latex of a polymer of vinyl acetate having a dry Tg above room temperature but a Tg when wet below 23° C. so that it is film-forming from the latex at room temperature. These paints are suitable for service as satin, semi-gloss or high gloss coatings but preferably are used as semi-gloss paints. The addition of the higher Tg polymer of vinyl acetate to the lower Tg copolymer provides a paint free with low to no volatile organic content but exhibiting improved blocking resistance without significant reduction in gloss.

摘要翻译： 具有ASTM 60°光泽值至少为10的水性涂料用乙酸乙烯酯和乙烯的共聚物或干玻璃化转变温度（Tg）低于20℃的丙烯酸烷基酯的胶乳和一种 具有高于室温的干燥Tg的乙酸乙烯酯的聚合物，而当湿度低于23℃时为Tg，使得其在室温下由胶乳成膜。 这些涂料适合作为缎面，半光泽或高光泽涂料使用，但优选用作半光泽涂料。 将乙酸乙烯酯的较高Tg聚合物加入到较低Tg共聚物中，提供无油的无涂料，具有低至无挥发性有机物含量，但显示出改进的抗粘连性，而光泽度没有显着降低。