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    Pentafluorosulfanyl-substituted thienothiophene monomers and conducting polymers
    6.
    发明授权
    Pentafluorosulfanyl-substituted thienothiophene monomers and conducting polymers 有权
    五氟硫烷基取代的噻吩并噻吩单体和导电聚合物

    公开(公告)号：US07060846B2

    公开(公告)日：2006-06-13

    申请号：US11229516

    申请日：2005-09-20

    申请人： Steffen Zahn ,  Andrew Francis Nordquist ,  Kristen Elaine Minnich ,  Guari Sankar Lal ,  William Franklin Burgoyne, Jr. ,  Axel Klauck-Jacobs

    发明人： Steffen Zahn ,  Andrew Francis Nordquist ,  Kristen Elaine Minnich ,  Guari Sankar Lal ,  William Franklin Burgoyne, Jr. ,  Axel Klauck-Jacobs

    IPC分类号： C07D333/04

    CPC分类号： C07D495/04 ,  C07D333/28 ,  C08G61/126 ,  H01G11/48 ,  Y02E60/13

    摘要： Thienothiophene monomers having an SF5 group and conducting oligomers and polymers formed by the polymerization of such monomers and their use as hole injection materials, charge transport materials, or as semiconductors. The compound may be of the formula: where X and X′ are independently H, halogen atoms (e.g., F, Cl, Br, and I), MgCl, MgBr, Mgl, Sn(R′)3, where R′ comprises C1-6 alkyl or —OC1-6 alkyl, boronic acid, boronic ester, —CH═CHR″ (where R″ comprises H or C1-6 alkyl), —OC1-6 alkyl, —COOC1-6 alkyl, —S—COR′″ and —COR′″ (where R′″ comprises H or C1-6 alkyl), —C≡CH, or polymerizable aromatic rings (such as phenyl, naphthalene, pyrrole, dithiophene, thienothiophene, thiophene and so forth).

    摘要翻译： 具有SF 5 N基团的噻吩并噻吩单体和通过这些单体的聚合形成的导电低聚物和聚合物及其作为空穴注入材料，电荷传输材料或半导体的用途。 化合物可以具有下式：其中X和X'独立地为H，卤素原子（例如F，Cl，Br和I），MgCl，MgBr，Mg1，Sn（R'）3 >，其中R'包含C 1-6烷基或-OC 1-6 - 烷基，硼酸，硼酸酯，-CH-CHR“（其中R” 包括H或C 1-6烷基），-OC 1-6烷基，-COOC 1-6烷基，-S-COR' '和-COR'''（其中R“'包括H或C 1-6烷基），-C≡CH或可聚合的芳环（例如苯基，萘，吡咯，二噻吩 噻吩并噻吩，噻吩等）。

    Polymeric compositions comprising per(phenylethynyl) arene derivatives
    7.
    发明授权
    Polymeric compositions comprising per(phenylethynyl) arene derivatives 有权
    包含每（苯基乙炔基）芳烃衍生物的聚合物组合物

    公开(公告)号：US08502401B2

    公开(公告)日：2013-08-06

    申请号：US13058688

    申请日：2009-08-10

    申请人： William Franklin Burgoyne, Jr. ,  Mark David Conner ,  Andrew Francis Nordquist ,  William Steven Collins

    发明人： William Franklin Burgoyne, Jr. ,  Mark David Conner ,  Andrew Francis Nordquist ,  William Steven Collins

    IPC分类号： H01L23/29

    CPC分类号： C08G65/48 ,  C08G2261/3422 ,  C08L65/00 ,  C08L71/00 ,  C08L79/08 ,  H01L2924/0002 ,  C08L2666/22 ,  H01L2924/00

    摘要： A polymeric composition comprising a first polymer chosen from a poly(arylene ether) polymer including polymer repeat units of the following structure: —(O—Ar1—O—Ar2—O—)m—(—O—Ar3—O—Ar4—O)n- where Ar1, Ar2, Ar3, and Ar4 are identical or different aryl radicals, m is 0 to 1, n is 1 m; a polysulfone, a polyimide, a poly(etherketone), a polyurea, a polyurethane, and combinations thereof and a second polymer comprising a per(phenylethynyl) arene polymer derivative. Cured films containing the polymer can exhibit at least one of the following properties: Tg from 160° C. to 180° C., a dielectric constant below 2.7 with frequency independence, and a maximum moisture absorption of less than 0.17 wt %. Accordingly, the polymer is especially useful, for example, in interlayer dielectrics and in die-attach adhesives.

    摘要翻译： 一种聚合物组合物，其包含选自包含以下结构的聚合物重复单元的聚（亚芳基醚）聚合物的第一聚合物： - （O-Ar1-O-Ar2-O-）m - （ - O-Ar3-O-Ar4- 其中Ar 1，Ar 2，Ar 3和Ar 4为相同或不同的芳基，m为0至1，n为1; 聚砜，聚酰亚胺，聚（醚酮），聚脲，聚氨酯及其组合，以及包含全（苯基乙炔基）芳烃聚合物衍生物的第二聚合物。 含有该聚合物的固化膜可呈现以下特性中的至少一种：Tg为160℃至180℃，介电常数低于2.7，频率独立，最大吸湿率小于0.17重量％。 因此，聚合物特别适用于例如层间电介质和芯片附着粘合剂中。

    Substituted thienothiophene monomers and conducting polymers
    9.
    发明授权
    Substituted thienothiophene monomers and conducting polymers 失效
    取代的噻吩并噻吩单体和导电聚合物

    公开(公告)号：US07118692B2

    公开(公告)日：2006-10-10

    申请号：US10958068

    申请日：2004-10-04

    申请人： Andrew Francis Nordquist ,  William Franklin Burgoyne, Jr. ,  Steffen Zahn ,  Francis Joseph Waller

    发明人： Andrew Francis Nordquist ,  William Franklin Burgoyne, Jr. ,  Steffen Zahn ,  Francis Joseph Waller

    IPC分类号： H01B1/12

    CPC分类号： H01B1/127 ,  H01G11/48 ,  H01G11/56 ,  Y02E60/13

    摘要： Thienothiophenes compositions comprising a C3-8 secondary or tertiary alkyl group are disclosed. The thienothiophenes may be represented by the formula: where R is C3-8 secondary or tertiary alkyl, e.g., isopropyl, tert-butyl, tert-pentyl, isopentyl, and 2-ethylhexyl, X and X′ are independently selected from the group consisting of H, halogen atoms (e.g., F, Cl, Br, and I), MgCl, MgBr, Mgl, Sn(R′)3, (where R′ is C1-6 alkyl or —OC1-6 alkyl), boronic acid, boronic ester, —CH═CHR″ (where R″ is H or C1-6 alkyl), —OC1-6 alkyl, —COOC1-6 alkyl, —S—COR′″, —COR′″ (where R′″ is H or C1-6 alkyl), —C≡CH, and polymerizable aromatic rings such as phenyl, naphthalene, pyrrole, dithiophene, thienothiophene, thiophene and so forth.

    摘要翻译： 公开了包含C 3-8仲仲或叔烷基的噻吩并噻吩类组合物。 噻吩并噻吩可以由下式表示：其中R是C 3-8仲仲或叔烷基，例如异丙基，叔丁基，叔戊基，异戊基和2-乙基己基，X和X 独立地选自H，卤素原子（例如F，Cl，Br和I），MgCl，MgBr，Mg1，Sn（R'）3（其中R' 是C 1-6烷基或-OC 1-6烷基），硼酸，硼酸酯，-CH-CHR“（其中R”是H或C C 1-6烷基），-OC 1-6烷基，-COOC 1-6烷基，-S-COR“ - ， - COR''（其中R“'是H或C 1-6烷基），-C≡CH，以及可聚合的芳环如苯基，萘，吡咯，二噻吩，噻吩并噻吩，噻吩和 等等。

    Pentafluorosulfanyl-substituted thienothiophene monomers and conducting polymers
    10.
    发明授权
    Pentafluorosulfanyl-substituted thienothiophene monomers and conducting polymers 失效
    五氟硫烷基取代的噻吩并噻吩单体和导电聚合物

    公开(公告)号：US07094365B2

    公开(公告)日：2006-08-22

    申请号：US10958054

    申请日：2004-10-04

    申请人： Steffen Zahn ,  Andrew Francis Nordquist ,  Kristen Elaine Minnich ,  Gauri Sankar Lal ,  William Franklin Burgoyne, Jr. ,  Axel Klauck-Jacobs

    发明人： Steffen Zahn ,  Andrew Francis Nordquist ,  Kristen Elaine Minnich ,  Gauri Sankar Lal ,  William Franklin Burgoyne, Jr. ,  Axel Klauck-Jacobs

    IPC分类号： H01B1/12 ,  C07D333/00

    CPC分类号： C08G61/126 ,  H01B1/127

    摘要： Thienothiophene monomers having an SF5 group and conducting oligomers and polymers formed by the polymerization of such monomers and their use as hole injection materials, charge transport materials, or as semiconductors. The compound may be of the formula: where X and X′ are independently H, halogen atoms (e.g., F, Cl, Br, and I), MgCl, MgBr, MgI, Sn(R′)3, where R′ is C1-6 alkyl or —OC1-6 alkyl, boronic acid, boronic ester, —CH═CHR″ (where R″ is H or C1-6 alkyl), —OC1-6 alkyl, —COOC1-6 alkyl, —S—COR′″ and —COR′″ (where R′″ is H or C1-6 alkyl), —C≡CH, or polymerizable aromatic rings (such as phenyl, naphthalene, pyrrole, dithiophene, thienothiophene, thiophene and so forth.

    摘要翻译： 具有SF 5 N基团的噻吩并噻吩单体和通过这些单体的聚合形成的导电低聚物和聚合物及其作为空穴注入材料，电荷传输材料或半导体的用途。 化合物可以具有下式：其中X和X'独立地为H，卤素原子（例如F，Cl，Br和I），MgCl，MgBr，MgI，Sn（R'）3 >，其中R'是C 1-6烷基或-OC 1-6 - 烷基，硼酸，硼酸酯，-CH-CHR“（其中R” 是H或C 1-6烷基），-OC 1-6烷基，-COOC 1-6烷基，-S-COR' '和-COR''（其中R“'是H或C 1-6烷基），-C≡CH或可聚合的芳环（例如苯基，萘，吡咯，二噻吩 噻吩并噻吩，噻吩等。