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    Catalytic reactions involving alkenes
    1.
    发明授权
    Catalytic reactions involving alkenes 有权
    涉及烯烃的催化反应

    公开(公告)号：US08314246B2

    公开(公告)日：2012-11-20

    申请号：US11991340

    申请日：2006-08-30

    申请人： Timothy F. Jamison ,  Sze-Sze Ng

    发明人： Timothy F. Jamison ,  Sze-Sze Ng

    IPC分类号： C07D231/00

    CPC分类号： C07F7/1892

    摘要： The present invention relates to new compositions and reactions to produce allylic alcohols or precursors of allylic alcohols (e.g., silyl ethers of allylic alcohols). Methods of the invention may comprise combining an alkene and an aldehyde in the presence of a transition metal catalyst (e.g., a nickel catalyst) to form an allylic alcohol or precursor of an allylic alcohol. Reaction products of the present invention may be valuable as intermediates and/or products in pharmaceutical and polymer research. Also, methods of the invention may be useful as fragment coupling reactions in complex molecule synthesis. Moreover, methods of the invention may include the use of reagents which, under reaction conditions known in the art, may have been unreactive, i.e., may not have been able to form the reaction product. The reagents used in the present invention may be relatively lower in cost than in other methods. Also, methods of the invention may reduce the number of synthetic and purification steps required to produce the reaction products, as well as reducing time, cost, and waste production.

    摘要翻译： 本发明涉及新的组合物和产生烯丙基醇或烯丙基醇前体（例如烯丙基醇的甲硅烷基醚）的反应。 本发明的方法可以包括在过渡金属催化剂（例如镍催化剂）存在下组合烯烃和醛以形成烯丙醇或烯丙基醇的前体。 本发明的反应产物可作为药物和聚合物研究中的中间体和/或产品是有价值的。 此外，本发明的方法可用作复合分子合成中的片段偶联反应。 此外，本发明的方法可以包括使用试剂，其在本领域已知的反应条件下可能已经不反应，即可能不能形成反应产物。 本发明中使用的试剂的成本可以低于其它方法。 此外，本发明的方法可以减少生产反应产物所需的合成和纯化步骤的数量，以及减少时间，成本和废物产生。

    Catalytic reactions involving alkenes
    5.
    发明申请
    Catalytic reactions involving alkenes 有权
    涉及烯烃的催化反应

    公开(公告)号：US20090216025A1

    公开(公告)日：2009-08-27

    申请号：US11991340

    申请日：2006-08-30

    申请人： Timothy F Jamison ,  Sze-Sze Ng

    发明人： Timothy F Jamison ,  Sze-Sze Ng

    IPC分类号： C07F7/18 ,  B01J31/12 ,  B01J27/185

    CPC分类号： C07F7/1892

    摘要： The present invention relates to new compositions and reactions to produce allylic alcohols or precursors of allylic alcohols (e.g., silyl ethers of allylic alcohols). Methods of the invention may comprise combining an alkene and an aldehyde in the presence of a transition metal catalyst (e.g., a nickel catalyst) to form an allylic alcohol or precursor of an allylic alcohol. Reaction products of the present invention may be valuable as intermediates and/or products in pharmaceutical and polymer research. Also, methods of the invention may be useful as fragment coupling reactions in complex molecule synthesis. Moreover, methods of the invention may include the use of reagents which, under reaction conditions known in the art, may have been unreactive, i.e., may not have been able to form the reaction product. The reagents used in the present invention may be relatively lower in cost than in other methods. Also, methods of the invention may reduce the number of synthetic and purification steps required to produce the reaction products, as well as reducing time, cost, and waste production.

    摘要翻译： 本发明涉及新的组合物和产生烯丙基醇或烯丙基醇前体（例如烯丙基醇的甲硅烷基醚）的反应。 本发明的方法可以包括在过渡金属催化剂（例如镍催化剂）存在下组合烯烃和醛以形成烯丙醇或烯丙基醇的前体。 本发明的反应产物可作为药物和聚合物研究中的中间体和/或产品是有价值的。 此外，本发明的方法可用作复合分子合成中的片段偶联反应。 此外，本发明的方法可以包括使用试剂，其在本领域已知的反应条件下可能已经不反应，即可能不能形成反应产物。 本发明中使用的试剂的成本可以低于其它方法。 此外，本发明的方法可以减少生产反应产物所需的合成和纯化步骤的数量，以及减少时间，成本和废物产生。