Aqueous resin composition having gas barrier properties and laminated film using the same
    2.
    发明申请
    Aqueous resin composition having gas barrier properties and laminated film using the same 有权
    具有阻气性的水性树脂组合物和使用其的层压膜

    公开(公告)号:US20070031679A1

    公开(公告)日:2007-02-08

    申请号:US10575783

    申请日:2004-10-07

    IPC分类号: C08G18/00 B32B27/40

    摘要: An aqueous resin composition with gas barrier properties contains (i) polyurethane resin having aurethane group and a urea group in a total concentration of 25 to 60% by weight and having a acid value of 5 to 100 mgKOH/g, (ii) a swelling inorganic layered compound (e.g., a water-swelling mica, and a montmorillonite), and (iii) a polyamine compound having an amine value of 100 to 1900 mgKOH/g. The polyurethane resin (i) is obtained by a reaction of (A) an aromatic, araliphatic or alicyclic polyisocyanate, (B) a polyhydroxyalkanecarboxylic acid, and at least one component selected from (C) a C2-8alkylene glycol and (D) a chain-extension agent (e.g., diamine, hydrazine and a hydrazine derivative), and neutralized with a neutralizing agent. The proportion of the acid group of the polyurethane resin (i) relative to the basic nitrogen atom of the polyamine compound (iii) is 10/1 to 1/5 as the equivalent ratio. A laminated film with high gas barrier properties is obtainable by coating a base film with the aqueous resin composition. The present invention provides an aqueous resin composition with excellent gas barrier properties, and a laminated film using the same.

    摘要翻译: 具有阻气性的水性树脂组合物含有(i)总重量为25〜60重量%,酸值为5〜100mgKOH / g的氨基甲酸酯基和脲基的聚氨酯树脂,(ii) 无机层状化合物(例如水溶性云母,蒙脱石),(iii)胺值为100〜1900mgKOH / g的多胺化合物。 聚氨酯树脂(i)通过(A)芳族,芳脂族或脂环族多异氰酸酯,(B)聚羟基链烷羧酸和至少一种选自(C)C 2-8 - 亚烷基二醇和(D)扩链剂(例如二胺,肼和肼衍生物),并用中和剂中和。 聚氨酯树脂(i)的酸基相对于多胺化合物(iii)的碱性氮原子的比例为当量比为10/1〜1/5。 通过用水性树脂组合物涂布基膜可获得具有高阻气性的层压膜。 本发明提供阻气性优异的水性树脂组合物和使用其的层压膜。

    Gas barrier film
    3.
    发明申请
    Gas barrier film 审中-公开
    阻气膜

    公开(公告)号:US20050084686A1

    公开(公告)日:2005-04-21

    申请号:US10962576

    申请日:2004-10-13

    申请人: Takuzo Imaizumi

    发明人: Takuzo Imaizumi

    摘要: A gas barrier film exhibiting a superior gas barrier property and simultaneously provided with an excellent coating property, a polyurethane resin obtained by adding a polyisocyanate compound containing at least one of an aromatic, aromatic aliphatic, and alicyclic polyisocyanate in an amount of at least 30 wt % of the total polyisocyanate compound, a polyhydroxyalkane carboxylic acid, as necessary a polyol compound containing a C2 to C8 polyol ingredient in an amount of at least 90 wt % of the total polyol compound, a chain extender selected from the group comprised of at least one of ammonia, an ammonia derivative, diamine, hydrazine, and a hydrazine derivative, and a neutralization agent and having a total of a urethane group concentration and urea group concentration of 25 to 60 wt % and an acid value of 5 to 100 mgKOH·g−1, a swellable inorganic layer compound, and a polyamine compound having an amine value of 100 to 1900 mgKOH·g−1 formed on one side or both sides of a thermoplastic resin base.

    摘要翻译: 具有优异的阻气性并同时具有优异涂布性能的阻气膜,通过将含有至少30重量%的至少一种芳族,芳族脂族和脂环族多异氰酸酯的多异氰酸酯化合物, 总多异氰酸酯化合物的%,多羟基烷烃羧酸,根据需要含有C 2〜C 8多元醇成分的多元醇化合物,其量为至少90重量% 总多元醇化合物,选自氨,氨衍生物,二胺,肼和肼衍生物中的至少一种的增链剂和中和剂,其总氨基甲酸酯基浓度和尿素基浓度 25〜60重量%,酸值为5〜100mg / kg,可溶胀无机层化合物,胺值为100〜1900mgKOH·g的多胺化合物 > -1 形成 在热塑性树脂基材的一面或两面上。