公开(公告)号：US20070254216A1

公开(公告)日：2007-11-01

申请号：US11571349

申请日：2005-03-24

申请人： Susumu Hara ,  Tetsuji Zama

发明人： Susumu Hara ,  Tetsuji Zama

IPC分类号： H01M4/70 ,  H01M4/02

CPC分类号： H01M14/00 ,  F03G7/005 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/1399 ,  H01M4/608 ,  H01M4/663 ,  H02N11/006

摘要： The present invention relates to an electrode, wherein a substrate comprises a porous carbon material and an electroconductive polymer layer formed by an electrolytic polymerization method is provided substantially on the substrate; the electrode, wherein the porous carbon material comprises at least one porous carbon material selected from the group consisting of a carbon paper, a carbon fiber, a porous carbon sheet and an activated carbon sheet; and an actuator having the above electrode as a counter electrode.

摘要翻译： 本发明涉及一种电极，其中基底包括多孔碳材料和通过电解聚合方法形成的导电聚合物层，其基本上设置在基底上; 所述电极，其中所述多孔碳材料包括选自由碳纸，碳纤维，多孔碳片和活性炭片组成的组中的至少一种多孔碳材料; 以及具有上述电极作为对电极的致动器。

公开(公告)号：US07943240B2

公开(公告)日：2011-05-17

申请号：US12131916

申请日：2008-06-02

申请人： Tetsuji Zama ,  Susumu Hara ,  Shingo Sewa

发明人： Tetsuji Zama ,  Susumu Hara ,  Shingo Sewa

IPC分类号： B32B9/04

CPC分类号： F16F15/005 ,  Y10T29/417 ,  Y10T428/31504 ,  Y10T428/31551 ,  Y10T428/32 ,  Y10T428/325

摘要： In order to obtain actuator elements capable of being displaced such as expansion and contract or bending for practical use even when used as actuator elements with larger size, stacked layers or bundles in which conductive polymer-containing layers or fiber-like tubes are provided with conductive polymer composite structures which include conductive substrates and conductive polymers, said conductive substrates have deformation property, and conductivity of said conductive substrates is not less than 1.0×103 S/cm are used.

摘要翻译： 为了获得能够被移动的致动器元件，例如膨胀和收缩或弯曲以用于实际使用，即使当用作具有较大尺寸的致动器元件，堆叠层或束，其中导电聚合物包含层或纤维状管设置有导电 包含导电性基板和导电性聚合物的高分子复合结构体，所述导电性基板具有变形特性，导电性基板的导电率为1.0×10 3 S / cm以上。

公开(公告)号：US07999449B2

公开(公告)日：2011-08-16

申请号：US11571349

申请日：2005-03-24

申请人： Susumu Hara ,  Tetsuji Zama

发明人： Susumu Hara ,  Tetsuji Zama

IPC分类号： H01M4/02

CPC分类号： H01M14/00 ,  F03G7/005 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/1399 ,  H01M4/608 ,  H01M4/663 ,  H02N11/006

摘要： The present invention relates to an electrode, wherein a substrate comprises a porous carbon material and an electroconductive polymer layer formed by an electrolytic polymerization method is provided substantially on the substrate; the electrode, wherein the porous carbon material comprises at least one porous carbon material selected from the group consisting of a carbon paper, a carbon fiber, a porous carbon sheet and an activated carbon sheet; and an actuator having the above electrode as a counter electrode.

摘要翻译： 本发明涉及一种电极，其中基底包括多孔碳材料和通过电解聚合方法形成的导电聚合物层，其基本上设置在基底上; 所述电极，其中所述多孔碳材料包括选自由碳纸，碳纤维，多孔碳片和活性炭片组成的组中的至少一种多孔碳材料; 以及具有上述电极作为对电极的致动器。

公开(公告)号：US20070119716A1

公开(公告)日：2007-05-31

申请号：US10597738

申请日：2005-02-04

申请人： Susumu Hara ,  Tetsuji Zama

发明人： Susumu Hara ,  Tetsuji Zama

IPC分类号： C25B3/00 ,  H01M4/60

CPC分类号： H01M4/8605 ,  C08G61/124 ,  C25B3/10 ,  C25D1/18 ,  H01B1/127 ,  H01G11/56 ,  H01M4/8668 ,  Y02E60/13

摘要： A filmy object containing an electrically conductive polymer, characterized in that (1) the electrically conductive polymer is one obtained by the electrolytic polymerization method and (2) upon immersion in a good solvent, the filmy object expands to come to have a film surface area larger by 30% or more than the film surface area before the immersion.

摘要翻译： 包含导电聚合物的薄膜物体，其特征在于：（1）导电聚合物是通过电解聚合法得到的导电聚合物和（2）浸入良溶剂中时，膜物体膨胀以形成膜表面积 比浸渍前的膜表面积大30％以上。

公开(公告)号：US20060275660A1

公开(公告)日：2006-12-07

申请号：US10536940

申请日：2003-12-01

申请人： Tetsuji Zama ,  Susumu Hara ,  Shingo Sewa

发明人： Tetsuji Zama ,  Susumu Hara ,  Shingo Sewa

IPC分类号： H01M4/60 ,  C25B3/10

CPC分类号： H01G9/042 ,  C08G61/124 ,  C08G73/0611 ,  C09D5/4476 ,  C25D13/04 ,  H01B1/127 ,  H01G9/028 ,  H01G9/038 ,  H01G9/058 ,  H01G9/155 ,  H01G11/26 ,  H01G11/56 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/1399 ,  H01M4/602 ,  Y02E60/13

摘要： In polypyrrole films obtained by a process for producing polypyrrole films comprising the steps of forming polypyrrole layers on working electrodes by electrochemical polymerization methods using pyrroles and/or pyrrole derivatives, followed by stripping off said polypyrrole layers, wherein said electrochemical polymerization methods use electrolytes including organic compounds comprising at least one bond or one functional group of ether bond, ester bond, carbonate bond, hydroxyl group, nitro group, sulfone group, and nitryl group and/or halogenated hydrocarbon as lo solvents and wherein said electrolytes include anions including trifluoromethanesulfonate ion and/or plural of fluorine atoms which bond to central atom and said working electrodes are metal electrodes, conductivity can be stably sustainable in the presence of oxygen and are excellent in mechanical strength.

摘要翻译： 在通过聚吡咯薄膜制造方法获得的聚吡咯薄膜中，包括以下步骤：通过使用吡咯和/或吡咯衍生物的电化学聚合方法在工作电极上形成聚吡咯层，然后剥离所述聚吡咯层，其中所述电化学聚合方法使用包括有机 包含醚键的至少一个键或一个官能团，酯键，碳酸酯键，羟基，硝基，砜基和硝基和/或卤代烃作为溶剂，其中所述电解质包括阴离子，包括三氟甲磺酸根离子和 /或多个与中心原子结合的氟原子和所述工作电极是金属电极，导电性可以在氧的存在下稳定地持续，并且机械强度优异。

公开(公告)号：US20090004476A1

公开(公告)日：2009-01-01

申请号：US12131916

申请日：2008-06-02

申请人： Tetsuji Zama ,  Sushumu Hara ,  Shingo Sewa

发明人： Tetsuji Zama ,  Sushumu Hara ,  Shingo Sewa

IPC分类号： B32B9/04

CPC分类号： F16F15/005 ,  Y10T29/417 ,  Y10T428/31504 ,  Y10T428/31551 ,  Y10T428/32 ,  Y10T428/325

摘要： In order to obtain actuator elements capable of being displaced such as expansion and contract or bending for practical use even when used as actuator elements with larger size, stacked layers or bundles in which conductive polymer-containing layers or fiber-like tubes are provided with conductive polymer composite structures which include conductive substrates and conductive polymers, said conductive substrates have deformation property, and conductivity of said conductive substrates is not less than 1.0×103 S/cm are used.

摘要翻译： 为了获得能够被移动的致动器元件，例如膨胀和收缩或弯曲以用于实际使用，即使当用作具有较大尺寸的致动器元件，堆叠层或束，其中导电聚合物包含层或纤维状管设置有导电 包括导电基底和导电聚合物的聚合物复合结构，所述导电基片具有变形特性，并且所述导电基片的导电率不小于1.0×10 3 S / cm。

公开(公告)号：US20060124470A1

公开(公告)日：2006-06-15

申请号：US10533915

申请日：2003-11-05

申请人： Tetsuji Zama ,  Susumu Hara ,  Shingo Sewa

发明人： Tetsuji Zama ,  Susumu Hara ,  Shingo Sewa

IPC分类号： H01G9/00 ,  C25D11/00

CPC分类号： F16F15/005 ,  Y10T428/31504 ,  Y10T428/31551 ,  Y10T428/32 ,  Y10T428/325

摘要： In order to obtain actuator elements capable of being displaced such as expansion and contract or bending for practical use even when used as actuator elements with larger size, stacked layers or bundles in which conductive polymer-containing layers or fiber-like tubes are provided with conductive polymer composite structures which include conductive substrates and conductive polymers, said conductive substrates have deformation property, and conductivity of said conductive substrates is not less than 1.0×103 S/cm are used.

摘要翻译： 为了获得能够被移动的致动器元件，例如膨胀和收缩或弯曲以用于实际使用，即使当用作具有较大尺寸的致动器元件，堆叠层或束，其中导电聚合物包含层或纤维状管设置有导电 包括导电基底和导电聚合物的聚合物复合结构，所述导电基底具有变形特性，并且所述导电基底的导电率不小于1.0×3 3 / S / cm。

公开(公告)号：US20060076540A1

公开(公告)日：2006-04-13

申请号：US10523985

申请日：2003-08-08

申请人： Tetsuji Zama ,  Susumu Hara ,  Shingo Sewa

发明人： Tetsuji Zama ,  Susumu Hara ,  Shingo Sewa

IPC分类号： H01B1/12

CPC分类号： C08G61/124 ,  A61F2002/5066

摘要： A process for producing conductive polymers with excellent electrochemical strain per redox cycle is provided. A process for producing conductive polymers by an electrochemical polymerization method, wherein said conductive polymers have deformation property by electrochemical redox, said electrochemical polymerization method is a polymerization method using electrolyte including organic compounds as solvents, and wherein said organic compounds include (1) chemical bond species selected at least one from a group composed of the chemical bond consisting of ether bond, ester bond, carbon-halogen bond, and carbonate bond and/or (2) functional groups selected at least one from a group composed of functional groups consisting of hydroxyl group, nitro group, sulfone group, and nitryl group in a molecule, and said electrolyte includes anions which include trifluoromethanesulfonate ion and/or plural of fluorine atoms which bond to central atom is used.

摘要翻译： 提供了一种用于每个氧化还原循环产生具有优异的电化学应变的导电聚合物的方法。 一种通过电化学聚合法制备导电聚合物的方法，其中所述导电聚合物通过电化学氧化还原具有变形性能，所述电化学聚合方法是使用包含有机化合物作为溶剂的电解质的聚合方法，其中所述有机化合物包括（1）化学键 选自由由醚键，酯键，碳 - 卤键和碳酸酯键组成的组中的至少一个的物质和/或（2）选自至少一个由官能团组成的组的官能团 羟基，硝基，砜基和硝基，所述电解质包括使用与中心原子结合的三氟甲磺酸根离子和/或多个氟原子的阴离子。