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    PIGMENTS OF SIMULTANEOUSLY SUBSTITUTED PYROCHLORE AND RELATED STRUCTURES
    1.
    发明申请
    PIGMENTS OF SIMULTANEOUSLY SUBSTITUTED PYROCHLORE AND RELATED STRUCTURES 有权
    同时取代的PYROCHLORE和相关结构的颜料

    公开(公告)号：US20140261085A1

    公开(公告)日：2014-09-18

    申请号：US14211729

    申请日：2014-03-14

    Applicant: The Shepherd Color Company

    Inventor： Simon K. Boocock ,  Andrew E. Smith ,  Miroslav Trojan

    IPC: C09D7/12

    CPC classification number: C09D7/61 ,  C01G33/006 ,  C01G41/006 ,  C01G45/006 ,  C01G45/12 ,  C01G49/0054 ,  C01G51/006 ,  C01G51/40 ,  C01G51/70 ,  C01G53/006 ,  C01G53/40 ,  C01G53/70 ,  C01P2002/36 ,  C01P2002/52

    Abstract: A compound or a pigment comprising a compound where there is simultaneous substitution of more or more elements onto both the A and B sites of a pyrochlore lattice or a lattice related to a pyrochlore. The pigment comprises a compound with the formula of AyA′y′BxB′x′Zp. Elements A and A′ have a valence of 1, 2, or 3; and are selected from the elements of groups 1, 2, 12, 13, 14, 15, and the first row of transition metals, excluding H, Pb, Cd, Hg, N, As, and Tl. Elements B and B′ have a valence of 3, 4, 5, or 6; and are selected from the elements of the first, second, or third row of transition metals, groups 13, 14, and 15, excluding V, C, Pb, and Tl. Element Z is selected from O, F, N, a chalcogen, S, Se, hydroxide ion, and mixtures thereof.

    Abstract translation: 包含化合物的化合物或颜料，其中同时将更多或更多元素取代到烧绿石晶格的A和B位点或与烧绿石相关的晶格。 该颜料包含具有下式的化合物：AyA'y'BxB'x'Zp。 元素A和A'的价数为1,2或3; 并且选自组1,2,12,13,14,15的元素和除H，Pb，Cd，Hg，N，As和T 1之外的第一排过渡金属。 元素B和B'的化合价为3,4,5或6; 并且选自除了V，C，Pb和T1之外的第一，第二或第三排过渡金属组13,14和15的元素。 元素Z选自O，F，N，硫族元素，S，Se，氢氧根离子及其混合物。

    CHROMIUM-FREE NEAR-INFRARED REFLECTING DELAFOSSITE PIGMENTS
    3.
    发明申请
    CHROMIUM-FREE NEAR-INFRARED REFLECTING DELAFOSSITE PIGMENTS 审中-公开
    无铬红外反射偏光颜料

    公开(公告)号：US20160319097A1

    公开(公告)日：2016-11-03

    申请号：US15134834

    申请日：2016-04-21

    Applicant: The Shepherd Color Company

    Inventor： Matthew C. Comstock

    IPC: C08K3/00

    CPC classification number: C08K3/013 ,  C01G3/00 ,  C01G15/00 ,  C01G49/009 ,  C01P2002/52 ,  C01P2004/61 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C01P2006/80 ,  C09C1/22 ,  C09C1/40 ,  C09D5/004

    Abstract: The current technology is directed to an iron-substituted copper aluminum delafossite pigment, as well as a gallate version of the same. In particular, the materials may be defined as iron-substituted copper aluminum delafossite, CuFexAl1-xO2 and the gallate, CuFexGa1-xO2 where X=0.01 to 1.00, for example, CuFe0.15Al0.85O2, and CuFe0.15Ga0.85O2. The pigments are dark-brown to black, absorb most light in the visible spectrum, but have low absorbance and high reflectance in the near-infrared regions, specifically light from about 700 nm-2500 nm.

    Abstract translation: 目前的技术是针对铁取代的铜铝色拉福石颜料，以及没食子酸酯版本。 特别地，这些材料可以定义为铁取代的铜铝铁矿床，CuFexAl1-xO2和没食子酸盐，其中X = 0.01至1.00的CuFexGa1-xO2，例如CuFe0.15Al0.85O2和CuFe0.15Ga0.85O2。 颜料是深棕色至黑色，吸收可见光谱中的大部分光，但在近红外区域具有低吸光度和高反射率，特别是约700nm-2500nm的光。

    Pigments based on LiSbO3 and LiNbO3 related structures
    6.
    发明授权
    Pigments based on LiSbO3 and LiNbO3 related structures 有权

    公开(公告)号：US10202510B2

    公开(公告)日：2019-02-12

    申请号：US14929949

    申请日：2015-11-02

    Applicant: The Shepherd Color Company

    Inventor： William M. Yuhasz

    IPC: C09C1/00 ,  C09C1/36 ,  C01G30/02 ,  C01G33/00 ,  C01G35/00 ,  C01G51/00 ,  C04B28/02 ,  C04B14/30 ,  C01G30/00 ,  C08K3/24 ,  C08K9/02 ,  C04B103/54

    Abstract: The present invention involves pigments derived from compounds with the LiSbO3-type or LiNbO3-type structures. These compounds possess the following formulations M1M5Z3, M1M2M4M5Z6, M1M32M5Z6, M1M2M3M6Z6, M12M4M6Z6, M1M5M6Z6, or a combination thereof. The cation M1 represents an element with a valence of +1 or a mixture thereof, the cation M2 represents an element with a valence of +2 or a mixture thereof, the cation M3 represents an element with a valence of +3 or a mixture thereof, the cation M4 represents an element with a valence of +4 or a mixture thereof, the cation M5 represents an element with a valence of +5 or a mixture thereof, and the cation M6 represents an element with a valence of +6 or a mixture thereof. The cation M is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, or Te. The anion Z is selected from N, O, S, Se, Cl, F, hydroxide ion or a mixture thereof. Along with the elements mentioned above vacancies may also reside on the M or Z sites of the above formulations such that the structural type is retained. The above formula may also include M dopant additions below 20 atomic %, where the dopant is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, Bi, Te, or mixtures thereof.

    PIGMENTS BASED ON LiSbO3 AND LiNbO3 RELATED STRUCTURES
    8.
    发明申请
    PIGMENTS BASED ON LiSbO3 AND LiNbO3 RELATED STRUCTURES 审中-公开

    公开(公告)号：US20190203053A1

    公开(公告)日：2019-07-04

    申请号：US16225574

    申请日：2018-12-19

    Applicant: The Shepherd Color Company

    Inventor： William M. Yuhasz

    IPC: C09C1/00 ,  C01G51/00 ,  C09C3/04 ,  C09C1/36 ,  C09C1/62

    CPC classification number: C09C1/0096 ,  C01G51/42 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2002/76 ,  C01P2002/77 ,  C01P2002/84 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C01P2006/66 ,  C09C1/3607 ,  C09C1/627 ,  C09C3/041 ,  C09D7/61

    Abstract: The present invention involves pigments derived from compounds with the LiSbO3-type or LiNbO3-type structures. These compounds possess the following formulations M1M5Z3, M1M2M4M5Z6, M1M32M5Z6, M1M2M3M6Z6, M12M4M6Z6, M1M5M6Z6, or a combination thereof. The cation M1 represents an element with a valence of +1 or a mixture thereof, the cation M2 represents an element with a valence of +2 or a mixture thereof, the cation M3 represents an element with a valence of +3 or a mixture thereof, the cation M4 represents an element with a valence of +4 or a mixture thereof, the cation M5 represents an element with a valence of +5 or a mixture thereof, and the cation M6 represents an element with a valence of +6 or a mixture thereof. The cation M is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, or Te. The anion Z is selected from N, O, S, Se, Cl, F, hydroxide ion or a mixture thereof. Along with the elements mentioned above vacancies may also reside on the M or Z sites of the above formulations such that the structural type is retained. The above formula may also include M dopant additions below 20 atomic %, where the dopant is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, Bi, Te, or mixtures thereof.

    PIGMENTS BASED ON LiSbO3 AND LiNbO3 RELATED STRUCTURES
    10.
    发明申请
    PIGMENTS BASED ON LiSbO3 AND LiNbO3 RELATED STRUCTURES 审中-公开
    基于LiSbO3和LiNbO3的颜料相关结构

    公开(公告)号：US20160122548A1

    公开(公告)日：2016-05-05

    申请号：US14929949

    申请日：2015-11-02

    Applicant: The Shepherd Color Company

    Inventor： William M. Yuhasz

    IPC: C09C1/00 ,  C09C1/36

    CPC classification number: C09C1/0096 ,  C01G30/002 ,  C01G30/026 ,  C01G33/006 ,  C01G35/006 ,  C01G51/006 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2002/76 ,  C01P2002/77 ,  C01P2002/80 ,  C01P2002/84 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/62 ,  C01P2006/63 ,  C01P2006/64 ,  C01P2006/65 ,  C01P2006/66 ,  C04B14/30 ,  C04B28/02 ,  C04B2103/54 ,  C08K3/24 ,  C08K9/02 ,  C09C1/00 ,  C09C1/36

    Abstract: The present invention involves pigments derived from compounds with the LiSbO3-type or LiNbO3-type structures. These compounds possess the following formulations M1M5Z3, M1M2M4M5Z6, M1M32M5Z6, M1M2M3M6Z6, M12M4M6Z6, M1M5M6Z6, or a combination thereof. The cation M1 represents an element with a valence of +1 or a mixture thereof, the cation M2 represents an element with a valence of +2 or a mixture thereof, the cation M3 represents an element with a valence of +3 or a mixture thereof, the cation M4 represents an element with a valence of +4 or a mixture thereof, the cation M5 represents an element with a valence of +5 or a mixture thereof, and the cation M6 represents an element with a valence of +6 or a mixture thereof. The cation M is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, or Te. The anion Z is selected from N, O, S, Se, Cl, F, hydroxide ion or a mixture thereof. Along with the elements mentioned above vacancies may also reside on the M or Z sites of the above formulations such that the structural type is retained. The above formula may also include M dopant additions below 20 atomic %, where the dopant is selected from H, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Ru, Co, Ni, Cu, Ag, Zn, B, Al, Ga, In, Si, Ge, Sn, P, Sb, Bi, Te, or mixtures thereof.

    Abstract translation: 本发明涉及衍生自具有LiSbO 3型或LiNbO 3型结构的化合物的颜料。 这些化合物具有以下配方M1M5Z3，M1M2M4M5Z6，M1M32M5Z6，M1M2M3M6Z6，M12M4M6Z6，M1M5M6Z6或其组合。 阳离子M1表示价数为+1的元素或其混合物，阳离子M2表示价数为+2的元素或其混合物，阳离子M3表示价数为+3的元素或其混合物 阳离子M4表示价数为+4的元素或其混合物，阳离子M5表示价数为+5的元素或其混合物，阳离子M6表示价数为+6的元素或 的混合物。 阳离子M选自H，Li，Na，K，Rb，Cs，Mg，Ca，Sr，Ba，Sc，Y，La，Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy， Er，Tm，Yb，Lu，Ti，Zr，Hf，V，Nb，Ta，Cr，Mo，W，Mn，Fe，Ru，Co，Ni，Cu，Ag，Zn，B，Al， Si，Ge，Sn，P，Sb或Te。 阴离子Z选自N，O，S，Se，Cl，F，氢氧根离子或其混合物。 与上述元素一起，空位也可以存在于上述配方的M或Z位点上，从而保留了结构类型。 上述公式还可以包括低于20原子％的M掺杂剂添加剂，其中掺杂剂选自H，Li，Na，K，Rb，Cs，Mg，Ca，Sr，Ba，Sc，Y，La，Ce，Pr， Nd，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu，Ti，Zr，Hf，V，Nb，Ta，Cr，Mo，W，Mn，Fe，Ru，Co，Ni， Cu，Ag，Zn，B，Al，Ga，In，Si，Ge，Sn，P，Sb，Bi，Te或其混合物。

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