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1.发明授权Solid oxide electrolyte fuel cell having dimpled surfaces of a power generation film 失效具有发电膜的凹凸表面的固体氧化物电解质燃料电池
公开(公告)号：US5518829A
公开(公告)日：1996-05-21
申请号：US390485
申请日：1995-02-17
CPC分类号： C25B9/00 , H01M8/1231 , H01M8/2425
摘要： The invention relates to a solid oxide electrolyte fuel cell (SOFC) which can be used as a cell for water electrolysis, CO.sub.2 electrolysis and other electrolyses, as well as for power generation. In a SOFC in which both surfaces of a power generation film comprising three layers of a fuel electrode, a solid electrolyte, and an oxygen electrode are formed with a number of dimples, the thickness of a yttria-stabilized zirconia film that constitutes the solid electrolyte is 5 to 100 .mu.m, and the thickness of an oxygen electrode material that constitutes the oxygen electrode which is provided on one side of the yttria-stabilized zirconia film is 200 to 2,000 .mu.m. As a result, the power generation performance can be greatly improved and a sufficiently strong oxygen electrode material prevents a thin yttria-stabilized zirconia film from being damaged in manual operations.
摘要翻译： 本发明涉及一种固体氧化物电解质燃料电池（SOFC），其可用作水电解，二氧化碳电解和其他电解池以及发电。 在其中形成具有多个凹坑的三层燃料电极，固体电解质和氧电极的发电膜的两个表面的SOFC中，构成固体电解质的氧化钇稳定的氧化锆膜的厚度 为氧化钇稳定的氧化锆膜的一面，构成氧电极的氧电极材料的厚度为200〜2000μm。 结果，可以大大提高发电性能，并且足够强的氧电极材料防止在手动操作中薄氧化钇稳定的氧化锆膜被损坏。
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公开(公告)号：US5198312A
公开(公告)日：1993-03-30
申请号：US669019
申请日：1991-03-13
申请人： Mitsuhiro Irino , Tokuki Satake , Hiroshi Sakai , Masayuki Funatsu , Hisao Haneda , Masaru Ishibashi , Koichi Takenobu , Kiyoshi Watanabe , Kazumi Ogura , Shigeru Ohkura
发明人： Mitsuhiro Irino , Tokuki Satake , Hiroshi Sakai , Masayuki Funatsu , Hisao Haneda , Masaru Ishibashi , Koichi Takenobu , Kiyoshi Watanabe , Kazumi Ogura , Shigeru Ohkura
CPC分类号： H01M8/04014 , H01M8/1231 , H01M8/2425 , H01M8/04022 , H01M8/247 , H01M8/249
摘要： A power generation system with flat fuel cells of solid electrolyte construction permits the building up of a large capacity system. There are a train of pile units of flat fuel cells of solid electrolyte disposed in a horizontally extending fuel gas duct. The gas fuel duct supplies to the train of pile units of flat fuel cells fuel gas. Each of said pile units of flat fuel cells has a horizontal flat flow path for the fuel gas disposed above each fuel-side porous electrode sheet of the fuel cell opening freely at two path ends on the opposing side faces of the pile unit. There is a horizontal flat flow path for the oxidant gas disposed beneath each oxygen-side porous electrode sheet separated from the fuel gas flow paths and each connected at two path ends to either a supply line or to an exhaust line for the oxidant gas. There is an after-burning region disposed downstream of said train of pile units of flat fuel cells, for burning at least a part of the spent fuel gas which has passed through the fuel cell using at least a part of the spent oxidant gas which has passed through the fuel cell, for generating a heat of combustion for use for preheating at least one of the feed gases to be supplied to the fuel cell.
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公开(公告)号：US06316138B1
公开(公告)日：2001-11-13
申请号：US08273455
申请日：1994-07-11
IPC分类号： H01M810
CPC分类号： H01M8/0297 , H01M8/0202 , H01M8/2425
摘要： An improved structure of a solid oxide electrolyte fuel cell (SOFC) is disclosed. A generating layer in the SOFC consists of three layers of a fuel electrode, an oxide layer and an oxygen electrode, and is shaped into a dimpled structure having recessed portions on its both surfaces. Protruded portions on the side of the fuel electrode are electrically bonded with an interconnector layer via a first conductive adhesive, while protruded portions on the side of the oxygen electrode of another generating layer are electrically bonded with the same interconnector layer via a second conductive adhesive. A plurality of generating layers and a plurality of interconnector layers are alternately stacked and they are electrically bonded in the above-described manner. Preferably the first conductive adhesive is made of material common to the fuel electrode and the second conductive adhesive is made of material common to the oxygen electrode. Owing to the improved structure, occurrence of lateral flows of electrons in the interconnector layers having a large resistance can be suppressed, hence an electrical resistance can be reduced, and also amounts of materials of the oxygen electrode and the fuel electrode can be made small.
摘要翻译： 公开了一种改进的固体氧化物电解质燃料电池（SOFC）的结构。 SOFC中的发生层由三层燃料电极，氧化物层和氧电极构成，并且成形为在其两个表面上具有凹陷部分的凹凸结构。 燃料电极侧的突出部分通过第一导电粘合剂与互连器层电连接，而另一发生层的氧电极侧的突出部分经由第二导电粘合剂与相同的互连器层电连接。 交替层叠多个发生层和多个互连层，并以上述方式电连接。 优选地，第一导电粘合剂由燃料电极共用的材料制成，第二导电粘合剂由氧电极共有的材料制成。 由于结构改善，可以抑制电阻较大的互连器层中的电子横向流动的发生，因此可以降低电阻，并且可以使氧电极和燃料电极的材料量变小。
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公开(公告)号：US5480737A
公开(公告)日：1996-01-02
申请号：US337509
申请日：1994-11-08
CPC分类号： H01M8/2425 , C25B9/00 , H01M8/1231
摘要： A power generation layer includes three layers of a fuel electrode, a solid oxide electrolyte and an oxygen electrode. Both faces of the power generation layer are formed with a number of dimples that are shaped and arranged so as to satisfy (half dimple height)=3.2.times.(dimple diameter)-(half dimple pitch).+-.(dimple diameter).
摘要翻译： 发电层包括三层燃料电极，固体氧化物电解质和氧电极。 发电层的两面形成有多个凹坑，其形状和布置为满足（半凹陷高度）= 3.2×（凹坑直径） - （半凹坑间距）+/-（凹坑直径）。
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公开(公告)号：US5501914A
公开(公告)日：1996-03-26
申请号：US296134
申请日：1994-08-26
CPC分类号： H01M8/2425 , H01M8/0271 , Y02P70/56
摘要： A solid oxide electrolyte fuel cell comprises a power generation film consisting of a solid oxide electrolyte film dimpled over substantially the whole area on both sides thereof, an oxygen electrode formed on one side thereof, and a fuel electrode formed on the other side of thereof, and comprises a pair of interconnectors located on both sides of the power generation film. Furthermore, this invention adopts a seal structure for sealing each side of the power generation film to each of the corresponding interconnectors. The peripheral area of the power generation film is provided with a seal face with the interconnector and is formed to lie in essentially the same plane as the apices of the dimpled pattern formed on the power generation film, and the provided seal section has approximately the same thermal expansion coefficient as the solid oxide electrolyte film which forms the power generation film.
摘要翻译： 固体氧化物电解质燃料电池包括发电膜，其由在其两侧的基本上整个区域上凹凸的固体氧化物电解质膜，在其一侧形成的氧电极和形成在其另一侧上的燃料电极组成， 并且包括位于发电膜两侧的一对互连器。 此外，本发明采用密封结构，用于将发电膜的每一侧密封到每个相应的互连器。 发电膜的周边区域设置有具有互连器的密封面，并且形成为位于与形成在发电膜上的凹凸图案的顶点基本相同的平面中，并且所提供的密封部分具有大致相同的 作为形成发电膜的固体氧化物电解质膜的热膨胀系数。
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公开(公告)号：US5065833A
公开(公告)日：1991-11-19
申请号：US556253
申请日：1990-07-19
申请人： Toshio Matsuoka , Akio Higashida , Tokuki Satake
发明人： Toshio Matsuoka , Akio Higashida , Tokuki Satake
摘要： An improved ground-surface-effect winged craft has a main body in the shape of an airfoil, side plates extending nearly vertically at the opposite lateral sides of the main body for intercepting air flowing outwards from the underside of the main body, side plate floats provided at the side plates, a float provided at a central lower portion of the main body, an operator's seat provided on the float, vertical and horizontal tails provided at a rear portion of the main body, and a propelling device for lifting and propelling the airframe of the craft by making use of both a power augment ramwing effect with the horizontal tail and a ground-surface-effect generated between the main body and a flat surface such as a water surface or a ground surface.
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公开(公告)号：US4873156A
公开(公告)日：1989-10-10
申请号：US102652
申请日：1987-09-30
CPC分类号： H01M8/243 , H01M8/1231 , Y02P70/56
摘要： A cylindrical solid electrolytic fuel cell which includes an oxygen electrode constituting the innermost layer of the fuel cell and having a thickness of 1 mm or more, a solid electrolyte covering the outer peripheral surface of the oxygen electrode, and a fuel electrode covering the outer peripheral surface of the solid electrolyte, is disclosed.
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