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公开(公告)号:US20100311924A1
公开(公告)日:2010-12-09
申请号:US12734727
申请日:2008-11-26
CPC分类号: C08F10/06 , C08F10/02 , C08F110/06 , C08F210/06 , C08F4/6555 , C08F4/651 , C08F4/02 , C08F4/6546 , C08F2500/12 , C08F210/16 , C08F2/34
摘要: Catalyst in form of solid particles, wherein the particles—have a specific surface area of less than 20 m2/g, comprise a transition metal compound which is selected from one of the groups 4 to 10 of the periodic table (IUPAC) or a compound of actinide or lanthanide, comprise a metal compound which is selected from one of the groups 1 to 3 of the periodic table (IUPAC), and—comprise solid material, wherein the solid material • does not comprise catalytically active sites, • has a specific surface area below 500 m2/g, and • has a mean particle size below 100.
摘要翻译: 固体颗粒形式的催化剂,其中颗粒具有小于20m 2 / g的比表面积,包含选自元素周期表(IUPAC)的第4至10族之一的过渡金属化合物或化合物 锕系元素或镧系元素包含选自周期表(IUPAC)中1至3族之一的金属化合物,并且包括固体材料,其中固体材料不包含催化活性位点, 表面积小于500m2 / g,平均粒径小于100。
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公开(公告)号:US5677069A
公开(公告)日:1997-10-14
申请号:US433517
申请日:1995-05-12
IPC分类号: B32B7/06 , B32B27/10 , B32B27/28 , B32B27/32 , C08J5/18 , C08L23/08 , C08L33/04 , C08L33/06 , C08L51/00 , C08L51/06 , B32B27/30
CPC分类号: C08J5/18 , B32B7/06 , C08L23/0869 , C08J2323/08 , C08J2351/00 , C08L51/06 , Y10T428/31855 , Y10T428/31909 , Y10T428/31935
摘要: The invention relates to sealable and peelable polymer composition which comprises 5-35 weight-% styrene modified ethylene copolymer and 95-65 weight-% ethylene butyl acrylate copolymer. Ethylene copolymer is preferably ethylene butylacrylate copolymer (E/BA) or ethylene vinyl acetate copolymer (E/VA).
摘要翻译: PCT No.PCT / FI93 / 00446 Sec。 371日期:1995年5月12日 102(e)日期1995年5月12日PCT提交1993年11月3日PCT公布。 公开号WO94 / 11434 日期1994年5月26日本发明涉及可密封和可剥离的聚合物组合物,其包含5-35重量%苯乙烯改性乙烯共聚物和95-65重量%乙烯丙烯酸丁酯共聚物。 乙烯共聚物优选为丙烯酸丁酯共聚物(E / BA)或乙烯 - 乙酸乙烯酯共聚物(E / VA)。
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公开(公告)号:US5312872A
公开(公告)日:1994-05-17
申请号:US103886
申请日:1993-08-06
申请人: Torvald Vestberg , Ismo Lehtiniemi
发明人: Torvald Vestberg , Ismo Lehtiniemi
IPC分类号: C08F255/00 , C08F2/18 , C08F255/02 , B32B27/30 , C08J3/02
CPC分类号: C08F255/02
摘要: A method for preparing a polyolefine-vinyl composite, in which method about 10-200 weight fractions of vinyl monomer and about 0.01-4.0 weight fractions of a free radical polymerization initiator, based on 100 weight fractions of vinyl monomer, are impregnated in 100 weight fractions of polyolefine particles by slowly mixing these at a temperature of about 20.degree.-100.degree. C. while continuously or discontinuously adding about 1-60% by weight of water, based on the total weight of the vinyl monomer and the polyolefine, during the maintenance of the particle structure of the polyolefine, is disclosed. A water suspension is prepared by adding water and stabilizing agents to the above-mentioned mixture after a completed impregnation. The total quantity of water is about 80-1000 weight fractions, based on 100 weight fractions of polyolefine+vinyl monomer. The temperature of the water suspension is then increased for polymerizing the vinyl monomer.
摘要翻译: 一种制备聚烯烃 - 乙烯基复合材料的方法,其中基于100重量份乙烯基单体约10-200重量份的乙烯基单体和约0.01-4.0重量份的自由基聚合引发剂以100重量份 通过在约20℃-100℃的温度下缓慢混合它们,同时连续地或不连续地加入约1-60重量%的水,基于乙烯基单体和聚烯烃的总重量,聚烯烃微粒的分数 公开了维持聚烯烃的颗粒结构。 在完全浸渍之后,通过向上述混合物中加入水和稳定剂来制备水悬浮液。 基于100重量份的聚烯烃+乙烯基单体,水的总量为约80-1000重量份。 然后增加水悬浮液的温度以使乙烯基单体聚合。
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公开(公告)号:US10253115B2
公开(公告)日:2019-04-09
申请号:US14240696
申请日:2012-08-29
申请人: Peter Denifl , Pirjo Jaaskelainen , Timo Leinonen , Bo Malm , Anders E. Nymark , Torvald Vestberg
发明人: Peter Denifl , Pirjo Jaaskelainen , Timo Leinonen , Bo Malm , Anders E. Nymark , Torvald Vestberg
摘要: Process for producing of a capacitor film comprising the steps of (a) polymerizing propylene in the presence of a catalyst comprising a solid catalyst system obtaining a polypropylene, (b) subjecting said polypropylene to a film forming process obtaining a capacitor film, wherein during the polymerization step (a) said catalyst comprising the solid catalyst system fragments into nanosized catalyst fragments being distributed in said polypropylene, said solid catalyst system comprises a transition metal, a metal which is selected from one of the groups 1 to 3 of the periodic table (IUPAC), and an internal electron donor.
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公开(公告)号:US09079988B2
公开(公告)日:2015-07-14
申请号:US12998307
申请日:2009-10-06
申请人: Michiel Bergstra , John Severn , Torvald Vestberg , Pauli Leskinen , Bo Malm , Olli Tuominen , Pirjo Jääskeläinen
发明人: Michiel Bergstra , John Severn , Torvald Vestberg , Pauli Leskinen , Bo Malm , Olli Tuominen , Pirjo Jääskeläinen
IPC分类号: C08F2/38 , C08F2/00 , C08F4/64 , C08F210/06 , C08F210/16
CPC分类号: C08F210/06 , C08F210/16 , C08F2400/02 , C08F2/00 , C08F2/38 , C08F2/001 , C08F2500/12 , C08F2500/17 , C08F2500/19 , C08F2500/04
摘要: The present invention relates to a process for the preparation of a propylene copolymer P1 having ethylene-derived comonomer units, which comprises the following steps: (i) introducing propylene, ethylene, and hydrogen into a polymerisation reactor R1, wherein the ethylene is fed to the polymerisation reactor R1 in a periodically varying amount, (ii) preparing the propylene copolymer in the polymerisation reactor R1 in the presence of a catalyst.
摘要翻译: 本发明涉及一种制备具有乙烯衍生的共聚单体单元的丙烯共聚物P1的方法,其包括以下步骤:(i)将丙烯,乙烯和氢气引入聚合反应器R1中,其中将乙烯进料至 聚合反应器R1以周期性变化的量,(ii)在催化剂存在下在聚合反应器R1中制备丙烯共聚物。
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公开(公告)号:US20110034656A1
公开(公告)日:2011-02-10
申请号:US12906563
申请日:2010-10-18
申请人: Torvald Vestberg , Peter Denifl , Timo Leinonen
发明人: Torvald Vestberg , Peter Denifl , Timo Leinonen
IPC分类号: C08F10/14
CPC分类号: C08F10/00 , C08F110/06 , C08L23/02 , C08L23/04 , C08L23/10 , C08L2205/02 , C08L2205/025 , C08L2666/06 , C08F2500/12
摘要: The invention is directed an alpha-olefin homo- or copolymer composition comprising at least one (i) alpha-olefin homo- or copolymer component, wherein the alpha-olefin homo- or copolymer composition comprises a decreased amount of C6-C15-oligomers.
摘要翻译: 本发明涉及包含至少一种(i)α-烯烃均聚物或共聚物组分的α-烯烃均聚物或共聚物组合物,其中α-烯烃均聚物或共聚物组合物包含少量的C 6 -C 15低聚物。
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公开(公告)号:US20100256318A1
公开(公告)日:2010-10-07
申请号:US12734730
申请日:2008-11-26
IPC分类号: C08F210/06
CPC分类号: C08F210/06 , C08F2/001 , C08F210/16 , C08F2500/12
摘要: The present invention relates to a propylene random copolymer, comprising comonomers selected from the group consisting of ethylene, C4 to C20 alpha-olefins, and any combination thereof, wherein the propylene random copolymer (a) has a comonomer content of at least 3.5 wt.-%, based on the weight of the propylene random copolymer, (b) has a randomness of at least 30%, and (c) is prepared in the presence of a catalyst system comprising solid catalyst particles, wherein the solid catalyst particles (c1) have a specific surface area of less than 20 m2/g, (c2) comprise a transition metal compound which is selected from one of the groups 4 to 10 of the periodic table or a compound of actinide or lanthanide, (c3) comprise a metal compound which is selected from one of the groups 1 to 3 of the periodic table, and (c4) comprise inclusions not having catalytically active sites.
摘要翻译: 本发明涉及丙烯无规共聚物,其包含选自乙烯,C 4至C 20α-烯烃以及它们的任何组合的共聚单体,其中丙烯无规共聚物(a)的共聚单体含量为至少3.5wt。 - %,基于丙烯无规共聚物的重量,(b)具有至少30%的随机性,和(c)在包含固体催化剂颗粒的催化剂体系的存在下制备,其中固体催化剂颗粒(c1 )具有小于20m 2 / g的比表面积,(c2)包含选自周期表第4至10族之一的过渡金属化合物或锕系元素或镧系元素的化合物,(c3)包含 金属化合物,其选自元素周期表第1至3族之一,(c4)包含不具有催化活性位点的夹杂物。
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公开(公告)号:US07531607B2
公开(公告)日:2009-05-12
申请号:US10582781
申请日:2004-12-17
申请人: Torvald Vestberg
发明人: Torvald Vestberg
IPC分类号: C08F4/649 , C08F110/06 , C08F210/06
CPC分类号: C08F10/00 , C08F10/06 , C08F110/06 , C08F2400/02 , C08F4/6465 , C08F2/00 , C08F2/38 , C08F2/40 , C08F2/001 , C08F2500/12 , C08F2500/15
摘要: A process for producing at least two different propylene polymer grades, in which process the isotacticity of the polymer is changed while keeping the melt flow rate of the polymer at a predetermined level during a transition of production from a first polymer grade to a second. The process is carried out in a polymerization arrangement comprising at least one polymerization reactor, where propylene is polymerized, optionally with comonomers, under polymerization conditions in the presence of hydrogen as a molecular weight controlling agent and a Ziegler-Natta catalyst system. The catalyst system comprises a catalyst component and an external donor. During a transition of production from the first polymer grade to the second, the external donor is changed, but the hydrogen feed is kept at a predetermined level.
摘要翻译: 一种生产至少两种不同丙烯聚合物级别的方法,其中改变聚合物的全同立构规整度,同时保持聚合物的熔体流动速率在从第一聚合物级到第二级的生产过渡期间处于预定水平。 该方法在包含至少一个聚合反应器的聚合装置中进行,其中丙烯聚合,任选地与共聚单体聚合,在氢气作为分子量控制剂和齐格勒 - 纳塔催化剂体系的存在下在聚合条件下进行。 催化剂体系包括催化剂组分和外部供体。 在从第一聚合物级到第二级的生产过渡期间,改变外供体,但氢进料保持在预定水平。
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公开(公告)号:US20080033122A1
公开(公告)日:2008-02-07
申请号:US11597590
申请日:2005-05-18
申请人: Peter Denifl , Timo Leinonen , Torvald Vestberg
发明人: Peter Denifl , Timo Leinonen , Torvald Vestberg
CPC分类号: C08F210/06 , C08F255/00 , C08F255/02 , C08L23/10 , C08L23/16 , C08L51/06 , C08F2/001 , C08L2666/06 , C08L2666/02 , C08F210/16
摘要: The present invention relates to novel processes for producing heterophasic alpha-olefin compositions, and more specifically to copolymer compositions of propylene produced in a multi-stage process using specified catalysts. The polymers obtained from the process have uniform quality and properties which make them suitable for a wide range of applications.
摘要翻译: 本发明涉及用于生产多相α-烯烃组合物的新方法,更具体地涉及使用特定催化剂的多阶段方法中生产的丙烯的共聚物组合物。 从该方法获得的聚合物具有均匀的质量和性质,使得它们适用于广泛的应用。
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公开(公告)号:US07038000B2
公开(公告)日:2006-05-02
申请号:US10476626
申请日:2002-05-03
IPC分类号: C08F110/06
CPC分类号: C08F210/06 , C08F4/65912 , C08F4/65916 , Y10S526/943 , C08F2/14 , C08F4/65927 , C08F210/14 , C08F2500/12 , C08F210/08 , C08F2500/03 , C08F2500/20
摘要: There is provided a process for the copolymerisation of propylene with at least one C4-20 α-olefin or C4-20 diene in a reaction medium in the presence of a catalyst system at a temperature of greater that 80° C. or at a temperature and pressure above the critical temperature and pressure of the reaction medium. Under such conditions, comonmer incorporation is higher than under standard conditions.
摘要翻译: 提供了在反应介质中存在下丙烯与至少一种C 4-14-20α-烯烃或C 4-20二烯共聚的方法 催化剂体系在大于80℃的温度下或在高于反应介质的临界温度和压力的温度和压力下进行。 在这种情况下,共同体注册高于标准条件。
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