公开(公告)号：US09070951B2

公开(公告)日：2015-06-30

申请号：US13496971

申请日：2010-09-17

申请人： Meiten Koh ,  Akiyoshi Yamauchi ,  Akinori Tani ,  Hideo Sakata ,  Hitomi Nakazawa ,  Toshiki Ichisaka ,  Hiroyuki Arima ,  Tomoyo Sanagi

发明人： Meiten Koh ,  Akiyoshi Yamauchi ,  Akinori Tani ,  Hideo Sakata ,  Hitomi Nakazawa ,  Toshiki Ichisaka ,  Hiroyuki Arima ,  Tomoyo Sanagi

IPC分类号： H01M4/58 ,  H01M6/16 ,  H01M10/0569 ,  H01M10/052 ,  H01M6/14

CPC分类号： H01M10/0569 ,  H01M6/14 ,  H01M6/16 ,  H01M6/162 ,  H01M6/166 ,  H01M10/052 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02T10/7011

摘要： The present invention provides a solvent for a nonaqueous electrolyte solution enabling a lithium secondary battery to exhibit an excellent discharge capacity, load characteristics, and cycle characteristics even under high voltages, as well as a nonaqueous electrolyte solution that uses this solvent and a lithium secondary battery. This solvent for a nonaqueous electrolyte solution is a solvent for a nonaqueous electrolyte solution for a lithium secondary battery, wherein the solvent for a nonaqueous electrolyte solution contains a fluorine-free cyclic carbonate (I), a fluorine-free chain carbonate (II), and a 1,1-di(fluorinated alkyl)ethylene carbonate (III), and wherein with a sum of (I), (II), and (III) being 100 volume %, the fluorine-free cyclic carbonate (I) is 10 to 50 volume %, the fluorine-free chain carbonate (II) is 49.9 to 89.9 volume %, and the 1,1-di(fluorinated alkyl)ethylene carbonate (III) is from at least 0.1 volume % to not more than 30 volume %.

摘要翻译： 本发明提供一种非水电解液的溶剂，其能够使锂二次电池即使在高电压下也显示优异的放电容量，负载特性和循环特性，以及使用该溶剂的非水电解质溶液和锂二次电池 。 该非水电解液用溶剂是锂二次电池用非水电解液的溶剂，其中，非水电解液的溶剂含有无氟环状碳酸酯（I），无碳链碳酸酯（II）， 和（I），（II）和（III）之和为100体积％的无水环状碳酸酯（I）为1〜2（氟化烷基）碳酸亚乙酯（III） 10〜50体积％，无碳链碳酸酯（II）为49.9〜89.9体积％，1,1-二（氟化烷基）碳酸亚乙酯（III）为0.1体积％以上30以下 体积％。

公开(公告)号：US08071709B2

公开(公告)日：2011-12-06

申请号：US12282664

申请日：2007-03-14

申请人： Mitsuru Kishine ,  Hirofumi Nishibayashi ,  Toshiki Ichisaka ,  Kazuo Kobayashi ,  Ryuji Tachibana ,  Tadashi Okawa ,  Katsumi Kihara

发明人： Mitsuru Kishine ,  Hirofumi Nishibayashi ,  Toshiki Ichisaka ,  Kazuo Kobayashi ,  Ryuji Tachibana ,  Tadashi Okawa ,  Katsumi Kihara

IPC分类号： C08G77/24

CPC分类号： C09K3/1018 ,  C08G77/24 ,  C08L27/16 ,  C08L83/04 ,  C08L2205/22 ,  C08L2666/14 ,  C08L83/00

摘要： The present invention provides a novel fluorine-containing rubber composite material having both of excellent fuel impermeability and excellent cold resistance, a fuel impermeable sealing material comprising the composite material and a process for preparing the composite material. The fluorine-containing rubber composite material comprises crosslinked particles of fluorine-containing silicone rubber dispersed in a fluorine-containing rubber. It is preferable that the fluorine-containing rubber comprises a vinylidene fluoride/tetrafluoroethylene/perfluoro vinyl ether copolymer, and the composite material has cold resistance of not more than −35° C. and fuel permeability of not more than 500 g·mm/m2·day. The fuel impermeable sealing material comprises the composite material. The process for preparing the composite material comprises a step for co-coagulation of a fluorine-containing rubber emulsion and an emulsion of crosslinked fluorine-containing silicone rubber.

摘要翻译： 本发明提供一种具有优异的燃料不渗透性和优异的耐寒性的新型含氟橡胶复合材料，包含该复合材料的燃料不可渗透的密封材料以及该复合材料的制备方法。 含氟橡胶复合材料包含分散在含氟橡胶中的含氟硅橡胶的交联颗粒。 含氟橡胶优选包含偏二氟乙烯/四氟乙烯/全氟乙烯基醚共聚物，复合材料的耐寒性不大于-35℃，燃料渗透率不大于500g·mm / m 2 ·天。 燃料不可渗透的密封材料包括复合材料。 制备复合材料的方法包括使含氟橡胶乳液和交联的含氟硅橡胶的乳液共混的步骤。

公开(公告)号：US20110290363A1

公开(公告)日：2011-12-01

申请号：US13205554

申请日：2011-08-08

申请人： Tomihiko YANAGIGUCHI ,  Toshiki ICHISAKA ,  Haruhisa MASUDA ,  Mitsuhiro OTANI

发明人： Tomihiko YANAGIGUCHI ,  Toshiki ICHISAKA ,  Haruhisa MASUDA ,  Mitsuhiro OTANI

IPC分类号： F16L11/00

CPC分类号： C08L27/16 ,  C08K5/136 ,  C08L27/18 ,  C08L53/00 ,  C08L2205/02 ,  C08L2205/22 ,  C08L2666/02 ,  C09J153/00 ,  Y10T428/1352 ,  Y10T428/1386 ,  Y10T428/1397 ,  Y10T428/3154 ,  C08L2666/04 ,  C08L2666/24

摘要： A fuel hose including a laminated article having: a layer including a thermoplastic polymer composition which includes a fluororesin (A) including a fluorine-containing ethylenic polymer (a) and a crosslinked fluororubber (B) including a fluororubber (b) that has been at least partially crosslinked. The fluorine-containing ethylenic polymer (a), the at least partially crosslinked fluororubber (b) and a weight ratio of the fluororesin (A) to the crosslinked fluororubber (B) are as defined herein. A fuel permeation coefficient and a tensile modulus of elasticity of a molded article including the thermoplastic polymer composition is not more than 20 g·mm/m2·day and is not more than 400 MPa. The fuel hose further includes a layer including at least one crosslinked rubber.

摘要翻译： 1.一种燃料软管，其具有层叠体，所述层叠体具有：包含热塑性聚合物组合物的层，所述热塑性聚合物组合物包含含有含氟乙烯性聚合物（a）的氟树脂（A）和包含氟橡胶（b）的交联氟橡胶（B） 最少部分交联。 含氟乙烯性聚合物（a），至少部分交联的氟橡胶（b）和氟树脂（A）与交联氟橡胶（B）的重量比如本文所定义。 包含该热塑性聚合物组合物的模制品的燃料透过系数和拉伸弹性模量不大于20g·mm / m 2·天，不大于400MPa。 燃料软管还包括包含至少一种交联橡胶的层。

公开(公告)号：US09373848B2

公开(公告)日：2016-06-21

申请号：US13816356

申请日：2011-09-16

申请人： Meiten Koh ,  Hideo Sakata ,  Tomoyo Sanagi ,  Hitomi Nakazawa ,  Hiroyuki Arima ,  Toshiki Ichisaka ,  Kenzou Takahashi

发明人： Meiten Koh ,  Hideo Sakata ,  Tomoyo Sanagi ,  Hitomi Nakazawa ,  Hiroyuki Arima ,  Toshiki Ichisaka ,  Kenzou Takahashi

IPC分类号： H01M4/02 ,  H01M4/66 ,  H01G11/30 ,  H01G11/48 ,  H01M10/052 ,  H01G11/26 ,  H01B1/24

CPC分类号： H01M4/667 ,  H01B1/24 ,  H01G11/26 ,  H01G11/30 ,  H01G11/48 ,  H01M4/661 ,  H01M4/663 ,  H01M4/666 ,  H01M4/668 ,  H01M10/052 ,  Y02E60/122 ,  Y02E60/13

摘要： The present invention provides a conductive protective layer-forming paste for current collector laminates which can be used even for high voltage designs to protect current collectors from corroding without loss of cell characteristics, and a current collector laminate, an electrode laminate, and nonaqueous secondary cells (e.g. a lithium secondary cell, an electric double layer capacitor) that include a conductive protective layer formed therefrom. The paste for forming conductive protective layers for current collector protection includes: polytetrafluoroethylene; and a conductive filler (b). The current collector laminate includes: a conductive protective layer (A); and a current collector (B), the conductive protective layer (A) being formed by coating the paste for forming conductive protective layers onto the current collector (B).

摘要翻译： 本发明提供一种用于集电体层压体的导电保护层形成用糊剂，其甚至可以用于高电压设计，以保护集电体免受腐蚀而不损失电池特性，集电器层压体，电极层压体和非水二次电池 （例如锂二次电池，双电层电容器），其包括由其形成的导电保护层。 用于形成用于集电器保护的导电保护层的浆料包括：聚四氟乙烯; 和导电填料（b）。 集电体层叠体包括：导电保护层（A）; 和集电体（B），所述导电保护层（A）通过在所述集电体（B）上涂布形成导电保护层的糊料而形成。

公开(公告)号：US20130143117A1

公开(公告)日：2013-06-06

申请号：US13816356

申请日：2011-09-16

申请人： Meiten Koh ,  Hideo Sakata ,  Tomoyo Sanagi ,  Hitomi Nakazawa ,  Hiroyuki Arima ,  Toshiki Ichisaka ,  Kenzou Takahashi

发明人： Meiten Koh ,  Hideo Sakata ,  Tomoyo Sanagi ,  Hitomi Nakazawa ,  Hiroyuki Arima ,  Toshiki Ichisaka ,  Kenzou Takahashi

IPC分类号： H01M4/66 ,  H01G11/26

CPC分类号： H01M4/667 ,  H01B1/24 ,  H01G11/26 ,  H01G11/30 ,  H01G11/48 ,  H01M4/661 ,  H01M4/663 ,  H01M4/666 ,  H01M4/668 ,  H01M10/052 ,  Y02E60/122 ,  Y02E60/13

摘要： The present invention provides a conductive protective layer-forming paste for current collector laminates which can be used even for high voltage designs to protect current collectors from corroding without loss of cell characteristics, and a current collector laminate, an electrode laminate, and nonaqueous secondary cells (e.g. a lithium secondary cell, an electric double layer capacitor) that include a conductive protective layer formed therefrom. The paste for forming conductive protective layers for current collector protection includes: polytetrafluoroethylene; and a conductive filler (b). The current collector laminate includes: a conductive protective layer (A); and a current collector (B), the conductive protective layer (A) being formed by coating the paste for forming conductive protective layers onto the current collector (B).

摘要翻译： 本发明提供一种用于集电体层压体的导电保护层形成用糊剂，其甚至可以用于高电压设计，以保护集电体免受腐蚀而不损失电池特性，集电器层压体，电极层压体和非水二次电池 （例如锂二次电池，双电层电容器），其包括由其形成的导电保护层。 用于形成用于集电器保护的导电保护层的浆料包括：聚四氟乙烯; 和导电填料（b）。 集电体层叠体包括：导电保护层（A）; 和集电体（B），所述导电保护层（A）通过在所述集电体（B）上涂布形成导电保护层的糊料而形成。

公开(公告)号：US20120183867A1

公开(公告)日：2012-07-19

申请号：US13496971

申请日：2010-09-17

申请人： Meiten Koh ,  Akiyoshi Yamauchi ,  Akinori Tani ,  Hideo Sakata ,  Hitomi Nakazawa ,  Toshiki Ichisaka ,  Hiroyuki Arima ,  Tomoyo Sanagi

发明人： Meiten Koh ,  Akiyoshi Yamauchi ,  Akinori Tani ,  Hideo Sakata ,  Hitomi Nakazawa ,  Toshiki Ichisaka ,  Hiroyuki Arima ,  Tomoyo Sanagi

IPC分类号： H01M10/0569

CPC分类号： H01M10/0569 ,  H01M6/14 ,  H01M6/16 ,  H01M6/162 ,  H01M6/166 ,  H01M10/052 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02T10/7011

摘要： The present invention provides a solvent for a nonaqueous electrolyte solution enabling a lithium secondary battery to exhibit an excellent discharge capacity, load characteristics, and cycle characteristics even under high voltages, as well as a nonaqueous electrolyte solution that uses this solvent and a lithium secondary battery. This solvent for a nonaqueous electrolyte solution is a solvent for a nonaqueous electrolyte solution for a lithium secondary battery, wherein the solvent for a nonaqueous electrolyte solution contains a fluorine-free cyclic carbonate (I), a fluorine-free chain carbonate (II), and a 1,1-di(fluorinated alkyl)ethylene carbonate (III), and wherein with a sum of (I), (II), and (III) being 100 volume %, the fluorine-free cyclic carbonate (I) is 10 to 50 volume %, the fluorine-free chain carbonate (II) is 49.9 to 89.9 volume %, and the 1,1-di(fluorinated alkyl)ethylene carbonate (III) is from at least 0.1 volume % to not more than 30 volume %.

摘要翻译： 本发明提供一种非水电解液的溶剂，其能够使锂二次电池即使在高电压下也显示优异的放电容量，负载特性和循环特性，以及使用该溶剂的非水电解质溶液和锂二次电池 。 该非水电解液用溶剂是锂二次电池用非水电解液的溶剂，其中，非水电解液的溶剂含有无氟环状碳酸酯（I），无氟碳酸链（II）， 和（I），（II）和（III）之和为100体积％的无水环状碳酸酯（I）为1〜2（氟化烷基）碳酸亚乙酯（III） 10〜50体积％，无碳链碳酸酯（II）为49.9〜89.9体积％，1,1-二（氟化烷基）碳酸亚乙酯（III）为0.1体积％以上30以下 体积％。

公开(公告)号：US20090076224A1

公开(公告)日：2009-03-19

申请号：US12282664

申请日：2007-03-14

申请人： Mitsuru Kishine ,  Hirofumi Nishibayashi ,  Toshiki Ichisaka ,  Kazuo Kobayashi ,  Ryuji Tachibana ,  Tadashi Okawa ,  Katsumi Kihara

发明人： Mitsuru Kishine ,  Hirofumi Nishibayashi ,  Toshiki Ichisaka ,  Kazuo Kobayashi ,  Ryuji Tachibana ,  Tadashi Okawa ,  Katsumi Kihara

IPC分类号： C08L27/12

CPC分类号： C09K3/1018 ,  C08G77/24 ,  C08L27/16 ,  C08L83/04 ,  C08L2205/22 ,  C08L2666/14 ,  C08L83/00

摘要： The present invention provides a novel fluorine-containing rubber composite material having both of excellent fuel impermeability and excellent cold resistance, a fuel impermeable sealing material comprising the composite material and a process for preparing the composite material. The fluorine-containing rubber composite material comprises crosslinked particles of fluorine-containing silicone rubber dispersed in a fluorine-containing rubber. It is preferable that the fluorine-containing rubber comprises a vinylidene fluoride/tetrafluoroethylene/perfluoro vinyl ether copolymer, and the composite material has cold resistance of not more than −35° C. and fuel permeability of not more than 500 g·mm/m2·day. The fuel impermeable sealing material comprises the composite material. The process for preparing the composite material comprises a step for co-coagulation of a fluorine-containing rubber emulsion and an emulsion of crosslinked fluorine-containing silicone rubber.

摘要翻译： 本发明提供一种具有优异的燃料不渗透性和优异的耐寒性的新型含氟橡胶复合材料，包含该复合材料的燃料不可渗透的密封材料以及该复合材料的制备方法。 含氟橡胶复合材料包含分散在含氟橡胶中的含氟硅橡胶的交联颗粒。 优选含氟橡胶包含偏二氟乙烯/四氟乙烯/全氟乙烯基醚共聚物，该复合材料的耐寒性不大于-35℃，燃料渗透率不超过500g·mm / m2 。天。 燃料不可渗透的密封材料包括复合材料。 制备复合材料的方法包括使含氟橡胶乳液和交联的含氟硅橡胶的乳液共混的步骤。

公开(公告)号：US20120301794A1

公开(公告)日：2012-11-29

申请号：US13577119

申请日：2011-02-07

申请人： Meiten Koh ,  Hideo Sakata ,  Tomoyo Sanagi ,  Hitomi Nakazawa ,  Hiroyuki Arima ,  Toshiki Ichisaka

发明人： Meiten Koh ,  Hideo Sakata ,  Tomoyo Sanagi ,  Hitomi Nakazawa ,  Hiroyuki Arima ,  Toshiki Ichisaka

IPC分类号： H01M10/0565 ,  H01M10/0561

CPC分类号： H01M10/0565 ,  H01B1/122 ,  H01M2300/0085 ,  H01M2300/0091

摘要： The present invention provides a composite gel electrolyte film for a secondary battery which has improved ion conductivity and excellent ignition resistance and is insusceptible to discoloration. The present invention is a composite gel electrolyte film for a secondary battery comprising: a gel electrolyte for a secondary battery formed of an electrolyte retention film impregnated with a nonaqueous electrolyte; and a porous film formed of at least one resin selected from the group consisting of polyethylene, polypropylene, and polyimide, the electrolyte retention film containing a vinylidene fluoride copolymer resin that includes a vinylidene fluoride unit and a tetrafluoroethylene unit at a molar ratio of 55/45 to 95/5 and further includes 0 to 10 mol % of a hexafluoropropylene unit, the total of the vinylidene fluoride unit, the tetrafluoroethylene unit, and the hexafluoropropylene unit being 100 mol %.

摘要翻译： 本发明提供一种二次电池用复合凝胶电解质膜，其具有改善的离子传导性和优异的耐点火性，并且不易变色。 本发明是一种二次电池用复合凝胶电解质膜，其特征在于，包括：由浸渍有非水电解质的电解质保留膜形成的二次电池用凝胶电解质; 以及由选自聚乙烯，聚丙烯和聚酰亚胺的至少一种树脂形成的多孔膜，所述电解质保留膜含有偏二氟乙烯单元和四氟乙烯单元的偏二氟乙烯共聚物树脂，摩尔比为55 / 45〜95/5，进一步含有0〜10摩尔％的六氟丙烯单元，1,1-二氟乙烯单元，四氟乙烯单元和六氟丙烯单元的合计为100摩尔％。

公开(公告)号：US20110086983A1

公开(公告)日：2011-04-14

申请号：US12965746

申请日：2010-12-10

申请人： Tomihiko YANAGIGUCHI ,  Toshiki ICHISAKA ,  Haruhisa MASUDA ,  Mitsuhiro OTANI

发明人： Tomihiko YANAGIGUCHI ,  Toshiki ICHISAKA ,  Haruhisa MASUDA ,  Mitsuhiro OTANI

IPC分类号： C08L27/20

CPC分类号： C08L27/16 ,  C08K5/136 ,  C08L27/18 ,  C08L53/00 ,  C08L2205/02 ,  C08L2205/22 ,  C08L2666/02 ,  C09J153/00 ,  Y10T428/1352 ,  Y10T428/1386 ,  Y10T428/1397 ,  Y10T428/3154 ,  C08L2666/04 ,  C08L2666/24

摘要： The object of the present invention is to provide a thermoplastic polymer composition which is flexible and capable of melt-molding and has excellent heat resistance, chemical resistance and oil resistance. Another object of the present invention is to provide a molded article, a laminated article, a hose for industrial use, a tube for industrial use, a fuel hose and a fuel tube comprising the thermoplastic polymer composition. Further object of the present invention is to provide a process for preparing a thermoplastic polymer composition. The thermoplastic polymer composition comprises a fluororesin (A) comprising a fluorine-containing ethylenic polymer (a) and a crosslinked fluororubber (B) in which at least a part of at least one kind of fluororubber (b) is crosslinked, and a weight ratio of the fluororesin (A) to the crosslinked fluororubber (B) is 85/15 to 40/60, a fuel permeation coefficient of a molded article obtained from the composition is not more than 40 g·mm/m2·day and a tensile modulus of elasticity of the molded article is not more than 400 MPa.

摘要翻译： 本发明的目的是提供一种柔性且能够熔融模塑并且具有优异的耐热性，耐化学性和耐油性的热塑性聚合物组合物。 本发明的另一个目的是提供一种模制品，层压制品，工业用软管，工业用管，燃料软管和包含热塑性聚合物组合物的燃料管。 本发明的另一个目的是提供一种制备热塑性聚合物组合物的方法。 热塑性聚合物组合物包含含有含氟乙烯性聚合物（a）的氟树脂（A）和至少一种氟橡胶（b）的至少一部分交联的交联氟橡胶（B），重量比 的氟树脂（A）与交联氟橡胶（B）的摩尔比为85/15〜40/60，由组合物得到的成型品的燃料透过系数为40g·mm / m 2·天以下，拉伸弹性模量 成型体的弹性不大于400MPa。

公开(公告)号：US20120231196A1

公开(公告)日：2012-09-13

申请号：US13480381

申请日：2012-05-24

申请人： Toshiki ICHISAKA ,  Michiko DOI ,  Haruhisa MASUDA ,  Katsuhide OHTANI ,  Tomihiko YANAGIGUCHI ,  Tsuyoshi ONO ,  Tomohiro KINO ,  Tadahiro YABU

发明人： Toshiki ICHISAKA ,  Michiko DOI ,  Haruhisa MASUDA ,  Katsuhide OHTANI ,  Tomihiko YANAGIGUCHI ,  Tsuyoshi ONO ,  Tomohiro KINO ,  Tadahiro YABU

IPC分类号： B32B27/08 ,  B32B37/18 ,  B32B1/08

CPC分类号： F16L11/04 ,  B32B1/08 ,  B32B25/08 ,  B32B25/14 ,  B32B27/18 ,  B32B27/304 ,  B32B27/322 ,  B32B27/38 ,  B32B2250/24 ,  B32B2270/00 ,  B32B2307/546 ,  B32B2307/7265 ,  B32B2597/00 ,  B32B2605/08 ,  F16L2011/047 ,  Y10T428/1386 ,  Y10T428/1393 ,  Y10T428/3154

摘要： The present invention provides a laminated article having improved adhesion of the fluorine-containing resin layer to the elastomer layer. The laminated article comprises a fluorine-containing resin layer (a) formed using a fluorine-containing resin having a carbonyl group, an olefin group or an amino group at an end of a polymer trunk chain or an end of a polymer side chain, and an elastomer layer (b) formed using an elastomer composition.

摘要翻译： 本发明提供一种具有改善的含氟树脂层与弹性体层的粘附性的层压制品。 层压制品包括使用在聚合物主链或聚合物侧链末端具有羰基，烯基或氨基的含氟树脂形成的含氟树脂层（a），以及 使用弹性体组合物形成的弹性体层（b）。