Pulvurent rubber comprising carbon black filler, process for their preparation and application
    4.
    发明授权
    Pulvurent rubber comprising carbon black filler, process for their preparation and application 失效
    包含炭黑填料的普罗文橡胶,其制备和应用的方法

    公开(公告)号:US06825262B2

    公开(公告)日:2004-11-30

    申请号:US10183435

    申请日:2002-06-28

    IPC分类号: C08K900

    CPC分类号: C08J3/215 C08J2321/00

    摘要: The invention relates to a process for preparing fine-particle free-flowing rubber powders, composed of carbon black fillers and a rubber, prepared by solution polymerization. The process operates on the basis of a two-phase system involving transfer of the organic rubber phase in a non-aggressive manner into the inorganic filler suspension, without addition of chemicals. A rubber/carbon black composite is formed. The process comprises measures to avoid clumping of product in the aqueous phase. After mechanical water removal and thermal drying, the product obtained flows freely and is a storage-stable powder or pellet and are markedly superior to the standard both in their processing and in their rubber-technology property profile.

    摘要翻译: 本发明涉及通过溶液聚合制备的由炭黑填料和橡胶组成的微粒自由流动橡胶粉末的方法。 该方法基于包括以无侵蚀的方式将有机橡胶相以无侵蚀的方式转移到无机填料悬浮液中的两相系统而不添加化学物质。 形成橡胶/炭黑复合材料。 该方法包括避免产物在水相中结块的措施。 机械除水和热干燥后,获得的产品自由流动,是一种储存稳定的粉末或丸粒,在其加工和橡胶技术性能特征方面均明显优于标准。

    Mixture of organosilanepolysulphanes and a process for the production of rubber compounds containing these mixtures
    7.
    发明授权
    Mixture of organosilanepolysulphanes and a process for the production of rubber compounds containing these mixtures 失效
    有机硅聚磺硫烷的混合物和用于生产含有这些混合物的橡胶化合物的方法

    公开(公告)号:US06194594B1

    公开(公告)日:2001-02-27

    申请号:US08889136

    申请日:1997-07-07

    IPC分类号: C08F718

    摘要: This invention relates to mixtures of organosilane-polysulphanes of the general formula (RO)3Si(CH2)xS—Sz—S(CH2)xSi(OR)3  (I) in which R means alkyl, linear or branched, having 1-8 C atoms, in particular 1-3 C atoms x means an integer from 1-8 z means 0 to 6, wherein sum of the proportions of polysulphanes in which z=0 and z=1 amounts to ≧80% by weight, providing that the proportion of compounds in which z=0 remains below 80% and the proportion of organosilanepolysulphanes in which z means an integer from 2 to 6 does not exceed a proportion of 20 wt. % in the mixtures, and to the rubber compounds produced using these mixtures, in particular for tire treads.

    摘要翻译: 本发明涉及一般形式的有机硅烷 - 多硫化物的混合物,R表示直链或支链烷基,具有1-8个C原子,特别是1-3个C原子的烷基,这意味着1-8z的整数表示0至6, z = 0和z = 1的多硫化物的比例相当于> = 80重量%,条件是其中z = 0的化合物的比例保持在80%以下,有机硅烷聚磺烷的比例,其中z表示2的整数 至6不超过20重量%的比例。 和使用这些混合物生产的橡胶化合物,特别是用于轮胎胎面。

    Precipitated silicas
    9.
    发明授权

    公开(公告)号:US06977065B1

    公开(公告)日:2005-12-20

    申请号:US08870591

    申请日:1997-06-06

    IPC分类号: C01B33/193 C08K3/36 C01B33/12

    摘要: A precipitated silica with the following physicochemical properties: BET surface area35 m2/g to 350 m2/g BET/CTAB surface area ratio0.8 to 1.1 Pore volume, PV1.6 ml/g to 3.4 ml/g Silanol group density3 ml/(1.5 g) to 9.5 ml/(1.5 g) (V2 = NaOH consumption) Average aggregate size250 nm to 1500 nm CTAB surface area30 m2/g to 350 m2/g DBP value150 ml/100 g to 300 ml/100 g V2/V1 by Hg porosimetry0.19 to 0.46 DBP/CTAB1.2 to 3.5 is produced by reacting alkali silicate with mineral acids at temperatures of 60° C. to 95° C. while maintaining a pH of 7.5 to 10.5 and continuously stirring, continuing the reaction to a solids concentration in the precipitation suspension of 90 g/l to 120 g/l, adjusting the pH value to a value of less than or equal to 5, filtering out, washing, drying and optionally grinding or granulating the precipitated silica. The precipitated silica is used as a filler in vulcanizable rubber compounds and vulcanizates.

    Rubber powder compositions and process for the production thereof
    10.
    发明授权
    Rubber powder compositions and process for the production thereof 有权
    橡胶粉组合物及其制备方法

    公开(公告)号:US06433064B1

    公开(公告)日:2002-08-13

    申请号:US09459975

    申请日:1999-12-14

    IPC分类号: C08K334

    摘要: Finely divided, pulverulent rubbers containing filler which contain further processing and vulcanization auxiliaries necessary for the production of vulcanizable rubber mixtures, which rubbers are pourable even after exposure to mechanical action, and to a process for the production thereof. The rubber powder is obtained within two precipitation steps. These rubber powders are used for the production of vulcanizable rubber mixtures. The fillers used, which comprise not only precipitated silicas but also carbon blacks known in the rubber industry, are optionally surface modified with organosilicon compounds.

    摘要翻译: 包含进一步加工的填料的粉碎橡胶以及即使在暴露于机械作用之后橡胶也可倾倒的可硫化橡胶混合物所需的硫化助剂及其生产方法。 在两个沉淀步骤中获得橡胶粉末。 这些橡胶粉末用于生产可硫化的橡胶混合物。 所使用的填料不仅包括沉淀二氧化硅,而且包括在橡胶工业中已知的炭黑,任选用有机硅化合物表面改性。